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    • 3. 发明授权
    • Materials and systems for advanced substrate cleaning
    • 用于高级基材清洗的材料和系统
    • US08314055B2
    • 2012-11-20
    • US12503486
    • 2009-07-15
    • David S. L. MuiJi ZhuArjun Mendiratta
    • David S. L. MuiJi ZhuArjun Mendiratta
    • C11D7/32
    • B08B7/0014C11D3/3746C11D7/5004C11D11/0047H01L21/02063H01L21/02071H01L21/6704H01L21/67051
    • The embodiments of the present invention provide improved materials, apparatus, and methods for cleaning wafer surfaces, especially surfaces of patterned wafers (or substrates). The cleaning materials, apparatus, and methods discussed have advantages in cleaning patterned substrates with fine features without substantially damaging the features. The cleaning material includes polymers of one or more polymeric compounds. The cleaning materials can be used in a wide range of viscosity and pH to clean different types of surfaces. The cleaning materials are in liquid phase, and deform around device features to capture the contaminants on the substrate. The polymers entrap the contaminants preventing their return to the substrate surface. The cleaning apparatus is designed to dispense and rinse cleaning materials with a range of viscosities.
    • 本发明的实施例提供用于清洁晶片表面,特别是图案化晶片(或基板)的表面的改进的材料,装置和方法。 所讨论的清洁材料,设备和方法具有在清洁具有精细特征的图案化基底而没有实质上损害特征的优点。 清洁材料包括一种或多种聚合物的聚合物。 清洁材料可以在宽范围的粘度和pH范围内使用以清洁不同类型的表面。 清洁材料处于液相,并围绕设备特征变形以捕获衬底上的污染物。 聚合物捕获污染物,防止其返回到基底表面。 清洁设备设计成可以分配和冲洗具有一定粘度范围的清洁材料。
    • 4. 发明申请
    • Method of Post Etch Polymer Residue Removal
    • 后蚀刻聚合物残渣去除方法
    • US20120115332A1
    • 2012-05-10
    • US13354322
    • 2012-01-19
    • Seokmin YunMark WilcoxsonJi ZhuKevin ChuangHsiao Wei ChangDavid Lou
    • Seokmin YunMark WilcoxsonJi ZhuKevin ChuangHsiao Wei ChangDavid Lou
    • H01L21/3065
    • H01L21/02063H01L21/6708
    • A method for processing a substrate includes etching a surface of the substrate using an etching chemistry in a plasma chamber, the etching configured to define one or more features on the surface of the substrate. The features have some etch polymer residues as a result of the etching. The etching is terminated. A dry flash chemistry is applied into the plasma chamber. The plasma chamber is powered for a period of time between about 5 seconds and about 10 seconds to perform a dry flash etch. During the dry flash etch, the chamber is set to a low pressure of between about 5 mTorr and about 40 mTorr. The dry flash etch acts to weaken adhesion of the etch polymer residues to the features. The substrate is moved from plasma chamber and into a wet clean chamber for cleaning which removes the etch polymer residues during fluid cleaning.
    • 一种用于处理衬底的方法包括:在等离子体室中使用蚀刻化学法蚀刻衬底的表面,蚀刻被配置为在衬底的表面上限定一个或多个特征。 这些特征由于蚀刻而具有一些蚀刻聚合物残留物。 蚀刻终止。 将干闪光化学物质施加到等离子体室中。 等离子体室在约5秒至约10秒之间的时间内供电以进行干闪光蚀刻。 在干闪光蚀刻期间,室设定在约5mTorr至约40mTorr之间的低压。 干闪光蚀刻用于削弱蚀刻聚合物残留物对特征的粘附。 衬底从等离子体室移动到用于清洁的湿式清洁室中,其在流体清洁期间除去蚀刻聚合物残余物。
    • 9. 发明申请
    • COMPOSITION OF A CLEANING MATERIAL FOR PARTICLE REMOVAL
    • 用于颗粒去除的清洁材料的组成
    • US20100120647A1
    • 2010-05-13
    • US12267345
    • 2008-11-07
    • Ji ZhuArjun MendirattaDavid Mui
    • Ji ZhuArjun MendirattaDavid Mui
    • C11D3/37
    • C11D7/5004C11D3/222C11D3/3765C11D3/3773C11D3/3776
    • The embodiments of the present invention provide improved materials for cleaning patterned substrates with fine features. The cleaning materials have advantages in cleaning patterned substrates with fine features without substantially damaging the features. The cleaning materials are fluid, either in liquid phase, or in liquid/gas phase, and deform around device features; therefore, the cleaning materials do not substantially damage the device features or reduce damage all together. To assist removing of particles from the wafer (or substrate) surfaces, the polymeric compound of the polymers can contain a polar functional group, which can establish polar-polar molecular interaction and hydrogen bonds with hydrolyzed particles on the wafer surface. The polymers of a polymeric compound(s) with a large molecular weight form long polymer chains and network. The long polymer chains and/or polymer network show superior capabilities of capturing and entrapping contaminants, in comparison to conventional cleaning materials. The polymeric compound(s) of the polymers may also include a functional group that carries charge in the cleaning solution. The charge of the functional group of the polymers improves the particle removal efficiency.
    • 本发明的实施例提供用于清洁具有精细特征的图案化衬底的改进材料。 清洁材料在清洁具有精细特征的图案化基材上具有优点,而基本上不损坏特征。 清洁材料是流体,液相或液相/气相,并围绕装置特征变形; 因此,清洁材料基本上不会损坏设备特征或将损坏降低在一起。 为了帮助从晶片(或衬底)表面去除颗粒,聚合物的聚合物可以含有极性官能团,其可以与晶片表面上的水解颗粒建立极性极性的分子相互作用和氢键。 具有大分子量的高分子化合物的聚合物形成长的聚合物链和网络。 与传统清洁材料相比,长的聚合物链和/或聚合物网络显示出捕获和捕获污染物的优异性能。 聚合物的聚合物还可以包括在清洁溶液中携带电荷的官能团。 聚合物官能团的电荷提高了颗粒去除效率。