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1. 发明申请

US20130248770A1 METAL PASSIVATION OF HEAT-EXCHANGER EXPOSED TO SYNTHESIS GAS 失效
标题翻译：接触合成气体的换热器的金属钝化
公开(公告)号：US20130248770A1
公开(公告)日：2013-09-26
申请号：US13821882
申请日：2011-08-19
申请人： Peter Edward James Abbott , Martin Fowles
发明人： Peter Edward James Abbott , Martin Fowles
IPC分类号： C01B3/02
CPC分类号： C01B3/02 , B01J8/067 , B01J19/02 , B01J2219/0236 , B01J2219/024 , F28F19/02
摘要： A process for passivation of surfaces of heat exchange apparatus exposed to a synthesis gas containing carbon monoxide, includes the steps of: adding arsine to the synthesis gas to provide a total As concentration in the synthesis gas in range 0.001 to 10 ppmv, (ii) exposing the mixture of hot synthesis gas and arsine to the shell-side surfaces of said heat exchange apparatus to reduce the interaction between the carbon monoxide present in said gas and metals in said surfaces, (iii) recovering a cooled synthesis gas from the shell-side of said apparatus, and (iv) passing the cooled synthesis gas, optionally after further cooling, through a sorbent bed to remove arsenic compounds from the synthesis gas.
摘要翻译：一种暴露于含有一氧化碳的合成气体的热交换装置的表面的钝化方法包括以下步骤：向合成气中加入胂以提供合成气中的总As浓度范围为0.001至10ppmv，（ii）将热合成气和胂的混合物暴露于所述热交换装置的壳侧表面，以减少所述气体中存在的一氧化碳和所述表面中的金属之间的相互作用，（iii）从壳层中回收冷却的合成气，（iv）任选地在进一步冷却之后将冷却的合成气通过吸附剂床以从合成气中除去砷化合物。

2. 发明授权

US08470202B2 Metal passivation 有权
标题翻译：金属钝化
公开(公告)号：US08470202B2
公开(公告)日：2013-06-25
申请号：US12091258
申请日：2006-10-10
申请人： Peter Edward James Abbott , Martin Fowles
发明人： Peter Edward James Abbott , Martin Fowles
IPC分类号： C01B3/26 , C23C22/03
CPC分类号： B01J8/0496 , B01J19/002 , B01J2219/02 , C01B3/38 , C01B2203/0227 , C01B2203/0261 , C01B2203/0495 , C07C29/1518 , C07C41/01 , C10G2/32 , C23F11/02 , C07C31/04 , C07C43/043
摘要： A method for passivating low-alloy steel surfaces in apparatus operating in the temperature range 350 to 580° C. and exposed to a carbon monoxide containing gas mixture comprises adding a passivating compound containing at least one phosphorus (P) atom to the gas mixture. The gas mixture is preferably a reformed gas and also described is a process for producing a synthesis gas wherein, prior to cooling a reformed gas mixture to a temperature between 350 and 580° C. in apparatus having low-alloy steel surfaces downstream of one or more reforming steps, a passivating compound containing at least one phosphorus (P) atom is combined with the gas mixture.
摘要翻译：在350至580℃的温度范围内操作并暴露于含一氧化碳的气体混合物的设备中钝化低合金钢表面的方法包括向气体混合物中加入含有至少一个磷（P）原子的钝化化合物。气体混合物优选是重整气体，并且还描述了一种生产合成气的方法，其中在将重整气体混合物冷却至350-580℃之间的温度之前，在具有低合金钢表面的装置中，更多的重整步骤，含有至少一个磷（P）原子的钝化化合物与气体混合物组合。

3. 发明授权

US07727509B2 Metal passivation in a heat exchange reformer 有权
标题翻译：热交换重整器中的金属钝化
公开(公告)号：US07727509B2
公开(公告)日：2010-06-01
申请号：US10499227
申请日：2002-12-16
申请人： Peter Edward James Abbott , Bernard John Crewdson , Martin Fowles
发明人： Peter Edward James Abbott , Bernard John Crewdson , Martin Fowles
IPC分类号： C01B3/24
CPC分类号： B01J19/002 , B01J8/0496 , B01J8/067 , B01J19/02 , B01J2208/00168 , B01J2208/00212 , B01J2208/00707 , B01J2219/00006 , B01J2219/00272 , B01J2219/0204 , B01J2219/0236 , C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0244 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/1052 , C01B2203/1064 , C01B2203/1235 , C01B2203/127 , C01B2203/141 , C23F11/02 , Y02P20/128
摘要： A method for reducing the interaction between carbon monoxide present in a heat exchange medium and metals on the shell side of heat exchange reformer apparatus used for reforming of hydrocarbons by treatment of the shell-side of said apparatus with an effective amount of at least one passivation compound containing at least one element selected from phosphorus, tin, antimony, arsenic, lead, bismuth, copper, germanium, silver or gold is described. Where volatile compounds are formed by the passivation compound, the method further comprises compound recovery to prevent contamination and deactivation of subsequent process steps. The method reduces side reactions, provides improved reformer tube lifetime and allows tubes to be treated in-situ without the need for process shutdown.
摘要翻译：一种用于通过用有效量的至少一种钝化处理所述装置的壳侧来减少在热交换介质中存在的一氧化碳与用于重整烃的热交换重整装置的壳侧上的金属之间的相互作用的方法描述了含有选自磷，锡，锑，砷，铅，铋，铜，锗，银或金中的至少一种元素的化合物。当通过钝化化合物形成挥发性化合物时，该方法还包括化合物回收以防止后续工艺步骤的污染和失活。该方法减少了副反应，提供了改进的重整器管寿命，并允许管原位处理，而不需要过程关闭。

4. 发明授权

US07445702B2 Desulphurisation 失效
标题翻译：脱硫
公开(公告)号：US07445702B2
公开(公告)日：2008-11-04
申请号：US10532616
申请日：2003-10-30
申请人： Peter Edward James Abbott
发明人： Peter Edward James Abbott
IPC分类号： C10G45/00 , C10G27/04 , C10G45/04 , C10G29/00 , B01D3/34
CPC分类号： C10G27/04
摘要： Propane and/or butanes are separated from a hydrocarbon feedstock contaminated with alkyl mercaptans by fractional distillation at such a pressure that the separated overheads stream containing said propane and/or butanes is at a temperature in the range 50 to 100° C. Sufficient oxygen is introduced into the hydrocarbon feedstock to oxidise the mercaptans therein and the resultant mixture is subjected to the fractional distillation in a column including at least one bed of a catalyst capable, under the prevailing conditions, of oxidising the mercaptans to higher boiling point sulphur compounds. These higher boiling point sulphur compounds are separated as part of the liquid phase from the distillation.
摘要翻译：将丙烷和/或丁烷与被烷基硫醇污染的原料烃分开，使得分离的含有丙烷和/或丁烷的塔顶馏出物流的温度为50-100℃。足够的氧是引入烃原料以氧化其中的硫醇，并将所得混合物在包括至少一种催化剂床的塔中进行分馏，所述催化剂床在主要条件下能够将硫醇氧化成高沸点硫化合物。这些较高沸点的硫化合物作为液相的一部分从蒸馏中分离出来。

5. 发明授权

US06174927B1 Exothermic catalytic chemical process 失效
标题翻译：放热催化化学工艺
公开(公告)号：US06174927B1
公开(公告)日：2001-01-16
申请号：US09142092
申请日：1999-04-06
申请人： Peter Edward James Abbott
发明人： Peter Edward James Abbott
IPC分类号： C07C2700
CPC分类号： B01J8/0285 , B01J8/001 , B01J2208/00044 , B01J2208/00132 , B01J2219/00198 , B01J2219/00202 , B01J2219/00213 , B01J2219/00238 , C07C29/1512 , C07C29/154 , C07C31/04
摘要： An exothermic catalytic process, particularly methanol synthesis, wherein reactants are passed through a fixed bed of a catalyst and heat evolved by the reaction is transferred to at least part of the reactants fed to the catalyst bed by heat exchange means to which said part of the reactants are fed, characterized by operation of the process under conditions whereby increasing the temperature at which said reactants are fed to the catalyst bed has the effect of increasing the temperature to which said reactants are heated in said heat exchange means, and vice versa, and controlling said process by monitoring the temperature of said reactants leaving said heat exchange means and/or entering said bed, decreasing the temperature at which the reactants are fed to said heat exchange means in response to any increase in said monitored temperature from a desired level, and increasing the temperature at which the reactants are fed to said heat exchange means in response to any decrease in said monitored temperature from said desired level.
摘要翻译：放热催化方法，特别是甲醇合成，其中反应物通过催化剂的固定床和通过反应放出的热量被转移到通过热交换装置供给到催化剂床的反应物的至少一部分，反应物进料，其特征在于在使所述反应物进料到催化剂床的温度升高的条件下操作该方法具有增加所述反应物在所述热交换装置中被加热的温度的作用，反之亦然，以及通过监测离开所述热交换装置和/或进入所述床的所述反应物的温度来控制所述方法，降低反应物响应于所述监测温度从期望水平的任何增加而被供给到所述热交换装置的温度，并且响应于sai的任何减少而增加反应物被供给到所述热交换装置的温度从所述期望的水平监测温度。

6. 发明授权

US5711049A Wiper blade assembly 失效
标题翻译：雨刷组件
公开(公告)号：US5711049A
公开(公告)日：1998-01-27
申请号：US589639
申请日：1996-01-22
申请人： Barry James Abbott , Valerie Margaret Abbott , Stephen James Clarke , Dino Donchi
发明人： Barry James Abbott , Valerie Margaret Abbott , Stephen James Clarke , Dino Donchi
IPC分类号： B60S1/38 , B60S1/04
CPC分类号： B60S1/38 , B60S2001/3818 , B60S2001/3822 , B60S2001/3836
摘要： A backing strip for a windscreen wiper blade assembly, and a clip for securing the backing strip to the assembly are disclosed. The backing strip and clip may be used in a wiper refill replacing existing windscreen wiper blades or may be provided as original equipment. The backing strip comprises rails (20) and (22) which can be engaged with claws (12) of the wiper assembly. The backing strip has two channels (34) and (36) for receiving a wiper element (40) and either rails (20) or (22) can be engaged with the claws depending on the size of the claws. The wiper element (40) is arranged in an appropriate one of the channels (34, 36) depending on which of the rails (20, 22) are engaged with the claws. The backing strip may include a third pair of rails (102) for enabling the backing strip to be used with claws of three different sizes. A clip (50) is disclosed for retaining the backing strip to the assembly and comprises first and second pairs of legs (54) and (56) which are spaced apart different distances corresponding to the rails (20) and (22), the legs (54) and (56) have prongs (58) which engage behind the claws (12) to limit longitudinal movement of the backing strip relative to the claws (12).
摘要翻译：公开了一种用于挡风玻璃刮水器组件的背衬条和用于将背衬条固定到组件的夹子。背衬带和夹子可以用于更换现有风挡玻璃刮水器的擦拭器补充件中，或者可以作为原始设备提供。背衬条包括可与刮水器组件的爪（12）接合的轨道（20）和（22）。背衬条具有用于接收刮水元件（40）的两个通道（34）和（36），并且根据爪的尺寸，轨道（20）或（22）可以与爪接合。根据哪个轨道（20,22）与爪接合，刮水器元件（40）布置在适当的一个通道（34,36）中。背衬带可以包括第三对导轨（102），用于使背衬条能够与三种不同尺寸的爪一起使用。公开了一种夹子（50），用于将背衬带固定到组件上，并且包括第一和第二对腿部（54）和（56），其彼此间隔开与轨道（20）和（22）相对应的不同距离，（54）和（56）具有接合爪（12）后面的尖头（58），以限制背衬条相对于爪（12）的纵向移动。

7. 发明申请

US20140357737A1 SYNTHESIS GAS AND FISCHER TROPSCH INTEGRATED PROCESS 有权
标题翻译：合成气和FISCHER TROPSCH综合工艺
公开(公告)号：US20140357737A1
公开(公告)日：2014-12-04
申请号：US14345554
申请日：2012-07-23
申请人： Peter Edward James Abbott
发明人： Peter Edward James Abbott
IPC分类号： C07C1/04
CPC分类号： C07C1/0485 , B01D53/229 , C01B3/16 , C01B3/38 , C01B2203/0233 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/0495 , C01B2203/062 , C07C29/1518 , C10G2/30 , C10K1/005 , C10K1/04 , C10K3/04 , Y02P20/125
摘要： Process for synthesizing hydrocarbons includes: reforming a hydrocarbon feedstock containing inert gases in reforming stages to generate a synthesis gas including the inert gases, steam, hydrogen and carbon monoxide; cooling the synthesis gas below the dew point to obtain a dewatered synthesis gas; synthesizing hydrocarbons from the dewatered synthesis gas by the Fischer-Tropsch reaction and separating at least part of the synthesized hydrocarbons, to give a tail gas; subjecting a mixture of at least part of the tail gas and steam to the water-gas shift reaction, to form shifted tail gas having increased hydrogen and carbon dioxide contents; subjecting the shifted tail gas to one or more membrane separation stages thereby generating an inert gas-containing gas mixture and one or more of a hydrogen-, carbon dioxide- and a hydrocarbon-containing gas mixture; and using one or more of the hydrogen-, carbon dioxide- and hydrocarbon-containing gas mixture in a reformer feed stream.
摘要翻译：合成烃的方法包括：在重整阶段重整含有惰性气体的烃原料以产生包括惰性气体，蒸汽，氢气和一氧化碳的合成气; 冷却低于露点的合成气，得到脱水合成气; 通过费 - 托反应从脱水合成气中合成烃，并分离至少部分合成的烃，得到尾气; 使至少部分尾气和蒸汽的混合物进行水煤气变换反应，形成具有增加的氢和二氧化碳含量的转移尾气; 将转移的尾气经受一个或多个膜分离阶段，从而产生含惰性气体的气体混合物和一种或多种含氢气，二氧化碳和含烃气体混合物; 并在重整器进料流中使用一种或多种含氢气，二氧化碳和含烃气体混合物。

8. 发明申请

US20140158942A1 WATER-GAS SHIFT CATALYST 审中-公开
标题翻译：水煤气转换催化剂
公开(公告)号：US20140158942A1
公开(公告)日：2014-06-12
申请号：US14123809
申请日：2012-05-22
申请人： Peter Edward James Abbott , Martin Fowles , Antonio Chica Lara , Norman Macleod , Juan Jose Gonzalez Perez , Elaine Margaret Vass
发明人： Peter Edward James Abbott , Martin Fowles , Antonio Chica Lara , Norman Macleod , Juan Jose Gonzalez Perez , Elaine Margaret Vass
IPC分类号： B01J23/887 , C01B3/16
CPC分类号： B01J23/8872 , B01J21/063 , B01J23/85 , B01J23/882 , B01J35/026 , B01J37/0009 , B01J37/024 , C01B3/16 , C01B2203/0283 , C01B2203/1041 , C01B2203/1052 , C01B2203/1082 , Y02P20/52
摘要： A catalyst precursor for preparing a catalyst suitable for use in a sour water-gas shift process is described, including; 5 to 30% by weight of a catalytically active metal oxide selected from tungsten oxide and molybdenum oxide; 1 to 10% by weight of a promoter metal oxide selected from cobalt oxide and nickel oxide; and 1 to 15% by weight of an oxide of an alkali metal selected from sodium, potassium and caesium; supported on a titania catalyst support.
摘要翻译：描述了一种用于制备适用于酸性水煤气变换过程的催化剂的催化剂前体，包括： 5至30重量％的选自氧化钨和氧化钼的催化活性金属氧化物; 1至10重量％的选自氧化钴和氧化镍的助催化剂金属氧化物; 和1至15重量％的选自钠，钾和铯的碱金属氧化物; 支持二氧化钛催化剂载体。

9. 发明授权

US08747734B2 Metal passivation of heat-exchanger exposed to synthesis gas 失效
标题翻译：金属钝化热交换器暴露于合成气
公开(公告)号：US08747734B2
公开(公告)日：2014-06-10
申请号：US13821882
申请日：2011-08-19
申请人： Peter Edward James Abbott , Martin Fowles
发明人： Peter Edward James Abbott , Martin Fowles
IPC分类号： B01J19/02 , C01B3/02 , C23F11/00 , F28F19/02
CPC分类号： C01B3/02 , B01J8/067 , B01J19/02 , B01J2219/0236 , B01J2219/024 , F28F19/02
摘要： A process for passivation of surfaces of heat exchange apparatus exposed to a synthesis gas containing carbon monoxide, includes the steps of: (i) adding arsine to the synthesis gas to provide a total As concentration in the synthesis gas in range 0.001 to 10 ppmv, (ii) exposing the mixture of hot synthesis gas and arsine to the shell-side surfaces of said heat exchange apparatus to reduce the interaction between the carbon monoxide present in said gas and metals in said surfaces, (iii) recovering a cooled synthesis gas from the shell-side of said apparatus, and (iv) passing the cooled synthesis gas, optionally after further cooling, through a sorbent bed to remove arsenic compounds from the synthesis gas.
摘要翻译：一种暴露于含有一氧化碳的合成气体的热交换装置的表面的钝化处理方法，包括以下步骤：（i）向合成气中加入胂以提供合成气中的总As浓度范围为0.001至10ppmv，（ii）将热合成气和胂的混合物暴露于所述热交换装置的壳侧表面，以减少所述气体中存在的一氧化碳与所述表面中的金属之间的相互作用，（iii）从所述装置的壳侧，以及（iv）任选地在冷却后通过吸附剂床将冷却的合成气通过以从合成气中除去砷化合物。

10. 发明授权

US07238214B2 Fuel composition 有权
标题翻译：燃油组成
公开(公告)号：US07238214B2
公开(公告)日：2007-07-03
申请号：US10148813
申请日：2000-12-14
申请人： Robert Howie Barbour , David John Rickeard , Douglas James Abbott
发明人： Robert Howie Barbour , David John Rickeard , Douglas James Abbott
IPC分类号： C10L1/00
CPC分类号： C10L1/08 , C10L1/00
摘要： This invention relates to a diesel fuel composition having enhanced lubricity, said composition comprising a major amount of a diesel fuel as base fuel blended with a minor amount of a nitrogen rich fraction characterised in that the nitrogen rich fraction is derived from a source material selected from (i) a solvent extract of a solid or semi-solid natural fossil, or, (ii) a refinery process stream or blend, the sulphur to nitrogen atom ratio in the nitrogen rich fraction being less than 4. The nitrogen rich fraction has an absolute nitrogen content of at least 1000 ppm by weight and this fraction is (re)blended with the base fuel is no more than 1% by weight of the total fuel composition. Methods of separating, recovering and reblending such naturally occurring nitrogen compounds can be installed or retrofitted at existing refinery and crude oil processing facilities without any substantial increase in production costs.
摘要翻译：本发明涉及具有增强的润滑性的柴油燃料组合物，所述组合物包含主要量的柴油燃料作为与少量富氮馏分混合的基础燃料，其特征在于富氮馏分源自选自（i）固体或半固体天然化石的溶剂提取物，或（ii）炼油工艺流或共混物，富氮馏分中的硫与氮原子比小于4.富氮馏分具有绝对氮含量为至少1000重量ppm，该馏分与基础燃料混合不超过总燃料组合物的1重量％。可以在现有的炼油厂和原油加工设施上安装或改造分离，回收和重新分配这些天然存在的氮化合物的方法，而不会大大增加生产成本。

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