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    • 1. 发明授权
    • Silver halide photographic material and method for processing the same
    • 卤化银照相材料及其加工方法
    • US5618660A
    • 1997-04-08
    • US401295
    • 1995-03-09
    • Itsuo FujiwaraTadashi Ito
    • Itsuo FujiwaraTadashi Ito
    • G03C1/035G03C1/09G03C1/12G03C1/14G03C1/20G03C1/22G03C1/26G03C1/28G03C5/16G03C5/29
    • G03C1/09G03C1/127G03C1/20G03C1/22G03C1/26G03C1/28G03C5/164
    • A silver halide photographic material having good spectral-sensitivity to laser rays, and which forms a high-sensitivity and high-contrast image by short-time exposure with high-intensity light. When processed with a reduced amount of replenisher, there is little fluctuation of photographic properties of the processed photographic material. The present invention relates to a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer comprising a silver halide emulsion containing silver halide grains having a silver chloride content of 50 mol % or less, wherein the silver halide emulsion is spectrally sensitized with a spectral sensitizing dye selected from the group consisting of compounds represented by formulae (I), (II) and (III) and the silver halide emulsion is chemically sensitized with a selenium compound and a gold compound: ##STR1## where the substituent groups for formulae (I) to (III) are defined in the specification.
    • 对激光光线具有良好的光谱灵敏度的卤化银照相材料,通过高强度光的短时间曝光形成高灵敏度和高对比度的图像。 当用减少量的补充液处理时,加工的照相材料的照相性能的波动很小。 本发明涉及一种卤化银照相材料,其中含有至少一种含有卤化银乳剂的卤化银乳剂的至少一种感光卤化银乳剂层的载体,该卤化银乳剂含有氯化银含量为50摩尔%以下,其中卤化银 用选自由式(I),(II)和(III)表示的化合物的光谱增感染料进行光谱增感,并且卤化银乳剂用硒化合物和金化合物进行化学增感: (I)其中式(I)至(III)的取代基在本说明书中定义的图像(II)(III)。
    • 6. 发明授权
    • Processing of photographic silver halide photosensitive material and
fixer used therein
    • 照相卤化银感光材料及其中使用的定影剂的加工
    • US5298382A
    • 1994-03-29
    • US22105
    • 1993-02-25
    • Takashi ToyodaItsuo Fujiwara
    • Takashi ToyodaItsuo Fujiwara
    • G03C1/035G03C1/047G03C1/12G03C5/08G03C5/16G03C5/38G03C1/73
    • G03C1/047G03C5/164G03C5/38G03C2001/0471Y10S430/164
    • Photographic silver halide photosensitive material is processed, after exposure, by treating it with a working fixer solution. The photosensitive material comprises at least one layer of silver halide emulsion on a support and contains at least 10% by weight, based on gelatins, of a gelatin having an isoelectric point of at least 5.0 on the emulsion layer side. The working fixer solution is prepared by furnishing a fixer concentrate of at least pH 5 containing a thiosulfate as a fixing agent, 0.05-0.8 mol/liter of a sulfite and up to 0.01 mol/liter of a water-soluble aluminum salt, and diluting the fixer concentrate with water, thereby forming the working fixer solution containing a minimized amount of ammonium thiosulfate and 0.5-2.5 mol/liter of sodium thiosulfate. The method provides improved rapid processing with increased degrees of fixation and drying while preventing the generation of sulfurous acid and ammonia gases.
    • 摄影卤化银感光材料在曝光后通过用定影剂溶液处理。 感光材料在载体上包含至少一层卤化银乳剂,并且基于明胶含有至少10重量%的在乳剂层侧具有至少5.0的等电点的明胶。 通过提供含有硫代硫酸盐作为固定剂,0.05-0.8mol /升亚硫酸盐和至多0.01mol /升水溶性铝盐的至少pH 5的固定剂浓缩物来制备工作定影剂溶液,并稀释 固定剂用水浓缩,从而形成含最少量的硫代硫酸铵和0.5-2.5mol / l硫代硫酸钠的加工定影剂溶液。 该方法提供了改进的快速加工,具有增加的固定和干燥程度,同时防止产生亚硫酸和氨气。
    • 7. 发明授权
    • Photothermographic material
    • 光热成像材料
    • US07416838B2
    • 2008-08-26
    • US11708359
    • 2007-02-21
    • Itsuo Fujiwara
    • Itsuo Fujiwara
    • G03C1/498G03C1/76
    • G03C1/49872G03C1/32G03C1/49854G03C1/49863G03C2200/36
    • The present invention provides a photothermographic material having, on one side of a support, an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and at least one non-photosensitive layer which is disposed on the same side of the support as the image forming layer and farther from the support than the image forming layer, wherein the non-photosensitive layer includes at least a copolymer latex of an acrylate or methacrylate having a fluorine atom and a monomer component having a hydrophobic group, and the surface of the side having the image forming layer includes convex portions having a height of 1.5 μm or higher in an amount of from 20 to 2000 per 1 mm2. A photothermographic material which exhibits excellent film physical properties and high image quality is provided.
    • 本发明提供一种光热敏成像材料,其在载体的一侧具有至少包含感光卤化银,非光敏有机银盐,还原剂和粘合剂的图像形成层, 感光层,其与图像形成层配置在与支撑体相同的一侧,与图像形成层相比离开支撑体更远,其中非光敏层至少包括具有氟原子的丙烯酸酯或甲基丙烯酸酯的共聚物胶乳和 具有疏水基团的单体组分,并且具有图像形成层的一侧的表面包括每1mm 2的高度为1.5-2μm的高度为1.5μm或更高的凸起部分。 提供了具有优异的膜物理性能和高图像质量的光热敏成像材料。
    • 8. 发明申请
    • Photothermographic material
    • 光热成像材料
    • US20070207417A1
    • 2007-09-06
    • US11708359
    • 2007-02-21
    • Itsuo Fujiwara
    • Itsuo Fujiwara
    • G03C1/00
    • G03C1/49872G03C1/32G03C1/49854G03C1/49863G03C2200/36
    • The present invention provides a photothermographic material having, on one side of a support, an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and at least one non-photosensitive layer which is disposed on the same side of the support as the image forming layer and farther from the support than the image forming layer, wherein the non-photosensitive layer includes at least a copolymer latex of an acrylate or methacrylate having a fluorine atom and a monomer component having a hydrophobic group, and the surface of the side having the image forming layer includes convex portions having a height of 1.5 μm or higher in an amount of from 20 to 2000 per 1 mm2. A photothermographic material which exhibits excellent film physical properties and high image quality is provided.
    • 本发明提供一种光热敏成像材料,其在载体的一侧具有至少包含感光卤化银,非光敏有机银盐,还原剂和粘合剂的图像形成层, 感光层,其与图像形成层配置在与支撑体相同的一侧,与图像形成层相比离开支撑体更远,其中非光敏层至少包括具有氟原子的丙烯酸酯或甲基丙烯酸酯的共聚物胶乳和 具有疏水基团的单体组分,并且具有图像形成层的一侧的表面包括每1mm 2的高度为1.5-2μm的高度为1.5μm或更高的凸起部分。 提供了具有优异的膜物理性能和高图像质量的光热敏照相材料。
    • 9. 发明授权
    • Heat development image forming process, thermally decoloring image recording process and process for decoloring cyanine dye
    • 热显影图像形成工艺,热脱色图像记录工艺和脱色花青染料的工艺
    • US06465163B2
    • 2002-10-15
    • US09931864
    • 2001-08-20
    • Masami SakuradaMasaki NoroItsuo FujiwaraYoshiharu Yabuki
    • Masami SakuradaMasaki NoroItsuo FujiwaraYoshiharu Yabuki
    • G03C112
    • B41M5/28G03C1/49854G03C1/832
    • A heat developable light-sensitive material comprises a support, a light-sensitive layer and a non-light-sensitive layer. The light-sensitive layer contains silver halide and a reducing agent. The non-light-sensitive layer contains a cyanine dye represented by the formula (I) or a salt thereof and a base precursor: in which R1 is hydrogen, an aliphatic group, an aromatic group, —NR21R24, —OR21 or —SR21, each of R21 and R24 independently is hydrogen, an aliphatic group or an aromatic group, or R21 and R24 are combined to form a nitrogen-containing heterocyclic ring; R2 is hydrogen, an aliphatic group or an aromatic group; R3 is an aliphatic group; L1 is a methine chain consisting of an odd number of methines; and each of Z1 and Z2 independently is an atomic group forming a five-membered or six-membered nitrogen-containing heterocyclic ring. A heat development image forming process, a thermal image recording material, a thermally decoloring image recording process and a process for decoloring a cyanine dye are also disclosed.
    • 可热显影的感光材料包括支撑体,感光层和非感光层。 感光层含有卤化银和还原剂。 非光敏层含有由式(I)表示的花青染料或其盐和碱前体:其中R 1是氢,脂族基,芳基,-NR 21 R 24,-OR 21或-SR 21, R 21和R 24各自独立地为氢,脂族基团或芳族基团,或R 21和R 24结合形成含氮杂环; R2是氢,脂族基或芳基; R3是脂族基团; L1是由奇数个次甲基组成的次甲基链; Z1和Z2各自独立地为形成五元或六元含氮杂环的原子团。 还公开了热显影图像形成方法,热图像记录材料,热脱色图像记录方法和花青染料脱色方法。