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    • 2. 发明授权
    • Sintered hardmetals
    • 烧结硬质合金
    • US4451292A
    • 1984-05-29
    • US305625
    • 1981-09-17
    • Fred W. HallHans-Joachim Retelsdorf
    • Fred W. HallHans-Joachim Retelsdorf
    • C22C1/05C22C29/02C22C29/06B22F3/12C22C1/04C22C14/00
    • C22C29/02C22C29/06
    • Spinodally-decomposing mixed crystals of zirconium and titanium carbides, possibly including carbonitrides and optionally including one or more carbides of metals of Group Vb of the Periodic Table of the Elements, are used in making sintered hardmetals based on tungsten carbide. One or more iron group metals or alloys, preferably cobalt or a nickel alloy, is or are used as a binder. The sintered hardmetals are made by a 2-stage process, mixed crystal material comprising zirconium and titanium carbides being formed in the first stage and being combined with the binder and tungsten carbide in the second stage. Process variations which encourage spinodal decomposition of the mixed crystal material are also disclosed.
    • PCT No.PCT / GB81 / 00036 Sec。 371日期:1981年9月17日 102(e)日期1981年9月17日PCT提交1981年3月4日PCT公布。 第WO81 / 02588号公报 日期:1984年9月17日。元素分解锆和碳化钛的混晶,可能包括碳氮化物,任选地包括元素周期表第Vb族金属的一种或多种碳化物,用于制造基于钨的烧结硬质合金 碳化物。 一种或多种铁族金属或合金,优选钴或镍合金,被用作或用作粘合剂。 烧结硬质合金是通过二阶段工艺制成的,在第一阶段中形成包括锆和碳化钛的混合晶体材料,并在第二阶段与粘合剂和碳化钨组合。 还公开了鼓励混晶材料的旋节分解的工艺变化。
    • 3. 发明授权
    • Sintered hard metals
    • 烧结硬金属
    • US4417922A
    • 1983-11-29
    • US285189
    • 1981-07-20
    • Fred W. HallHans-Joachim Retelsdorf
    • Fred W. HallHans-Joachim Retelsdorf
    • C22C1/05C22C29/04C22C29/06C22C29/00C22C1/10
    • C22C29/06C22C29/04
    • Mixed crystals of zirconium and hafnium carbides, possibly including the carbonitrides, are used in place of tantalum carbide in sintered hard metals. The new products contain one or more hard metals of Groups IV to VI of the Periodic Table of the Elements other than the mixed crystals, in particular, titanium and tungsten carbides, possibly with carbides of vanadium, niobium, molybdenum or chromium, and one or more iron group metals or alloys, preferably cobalt, is or are used as a binder. The sintered hard metals are made essentially by a 2-stage process, mixed crystal material comprising zirconium and hafnium carbides being formed in the first stage and being combined with the binder in the second stage, the one or more other hard metals of Groups IV to VI being incorporated in one or both stages. Any tendency to microporosity, shown particularly by products having a nitrogen content, is avoided by hot isostatic pressing.
    • PCT No.PCT / GB80 / 00195 Sec。 371日期1981年7月20日 102(e)日期1981年7月20日PCT提交1980年11月10日PCT公布。 公开号WO81 / 0142200 日期:1981年5月28日。使用锆和碳化铪混合的晶体,可能包括碳氮化物,代替烧结硬质金属中的碳化钽。 新产品含有一种或多种元素周期表第Ⅳ至Ⅵ族的硬金属,不同于混晶,特别是钛和碳化钨,可能含有钒,铌,钼或铬的碳化物,以及一种或多种 更多的铁族金属或合金,优选钴,被用作或用作粘合剂。 烧结的硬质金属主要由2阶段工艺制成,包含锆和碳化铪的混合晶体材料在第一阶段中形成并与第二阶段中的粘合剂组合,其中一种或多种其它硬质金属组IV至 VI被并入一个或两个阶段。 通过热等静压来避免任何具有氮含量的产品的微孔倾向。
    • 8. 发明授权
    • Sinterable mass for producing workpieces of alloy steel
    • 用于生产合金钢工件的烧结块
    • US4263046A
    • 1981-04-21
    • US945900
    • 1978-09-26
    • Rudolf FichteHans-Joachim RetelsdorfRichard JervisGunter Radel
    • Rudolf FichteHans-Joachim RetelsdorfRichard JervisGunter Radel
    • C22C33/02G06G7/163B22F1/00
    • G06G7/163C22C33/0207
    • A workpiece of alloy steel is produced by sintering under a nonoxidizing atmosphere a mass of malleable-iron powder admixed with a comminuted complex ferroalloy. The latter, obtained from a molten mixture of several simple high-carbon ferroalloys saturated with graphite, is a blend of at least three nonferrous metals and iron in carbide form, including a complex carbide of formula M.sub.7 C.sub.3 containing iron and manganese with the possible addition of chromium and another carbide of formula M'.sub.2 C/M'C containing molybdenum with the possible addition of vanadium and/or niobium. The carbidically bound carbon amounts to at least 4%, by weight, of the ferroalloy composition and may constitute between 10% and 60% of the carbon of the sinterable powder mixture to which elemental carbon may be added as graphite. As the mass of iron and ferroalloy particles compacted under high pressure is sintered at temperatures between about 1150.degree. and 1300.degree. C., the carbides lose their identity as their metals diffuse into the soft iron along with the carbon.
    • 通过在非氧化气氛下烧结与粉碎的复合铁合金混合的大量可锻铸铁粉来制造合金钢的工件。 由几种用石墨饱和的简单高碳铁合金的熔融混合物获得的后者是至少三种有色金属和碳化物形式的铁的混合物,包括含有铁和锰的式M7C3的复合碳化物,可能加入 铬和含有钼的式M'2C / M'C的另一种碳化物,可能加入钒和/或铌。 碳结合碳占铁合金组合物的至少4重量%,并且可以构成作为石墨添加元素碳的可烧结粉末混合物的碳的10%至60%。 当在高压下压实的铁和铁合金颗粒的质量在约1150℃和1300℃之间的温度下烧结时,碳化物随着其与金属一起扩散到软铁中而失去它们的相同性。