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1. 发明授权

US08968642B2 Cermet body and a method of making a cermet body 有权
标题翻译：金属陶瓷体和制造金属陶瓷体的方法
公开(公告)号：US08968642B2
公开(公告)日：2015-03-03
申请号：US13325086
申请日：2011-12-14
申请人： Malin Mårtensson , Gerold Weinl
发明人： Malin Mårtensson , Gerold Weinl
IPC分类号： B22F3/10 , C22C1/05 , C22C29/10 , C22C29/02
CPC分类号： C22C1/051 , C22C29/10
摘要： A TiC-based cermet body includes TiC and WC so that the atomic ratio Ti/W is between 2 to 5, and cobalt as the binder phase is present in an amount of between 5 to 25 vol %. Further, the cermet body has at least one element from group V of the periodic table, Mx, so that the atomic ratio Ti/Mx is between 4 to 20 and the atomic ratio W/Mx is between 1 to 6. The cermet body also has Cr in an amount such that the atomic Cr/Co ratio is from 0.025 to 0.14. The cermet body includes both undissolved TiC cores with a rim of (Ti,W,Mx)C alloy as well as (Ti,W,Mx)C grains which have been formed during sintering. A method of making a cermet body is also disclosed.
摘要翻译： TiC基金属陶瓷体包括TiC和WC，原子比Ti / W为2〜5，作为粘结相的钴的存在量为5〜25体积％。此外，金属陶瓷体具有至少一种来自元素周期表V的元素Mx，使得原子比Ti / Mx为4〜20，原子比W / Mx为1〜6。金属陶瓷体也具有使原子Cr / Co比为0.025〜0.14的量的Cr。金属陶瓷体包括具有（Ti，W，Mx）C合金边缘的未溶解的TiC芯以及在烧结期间形成的（Ti，W，Mx）C晶粒。还公开了制造金属陶瓷体的方法。

2. 发明申请

US20120156083A1 CERMET BODY AND A METHOD OF MAKING A CERMET BODY 有权
标题翻译： CERMET身体和制造CERMET身体的方法
公开(公告)号：US20120156083A1
公开(公告)日：2012-06-21
申请号：US13325086
申请日：2011-12-14
申请人： Malin Mårtensson , Gerold Weinl
发明人： Malin Mårtensson , Gerold Weinl
IPC分类号： B22F3/10 , C22C29/02
CPC分类号： C22C1/051 , C22C29/10
摘要： A TiC-based cermet body includes TiC and WC so that the atomic ratio Ti/W is between 2 to 5, and cobalt as the binder phase is present in an amount of between 5 to 25 vol %. Further, the cermet body has at least one element from group V of the periodic table, Mx, so that the atomic ratio Ti/Mx is between 4 to 20 and the atomic ratio W/Mx is between 1 to 6. The cermet body also has Cr in an amount such that the atomic Cr/Co ratio is from 0.025 to 0.14. The cermet body includes both undissolved TiC cores with a rim of (Ti,W,Mx)C alloy as well as (Ti,W,Mx)C grains which have been formed during sintering. A method of making a cermet body is also disclosed.
摘要翻译： TiC基金属陶瓷体包括TiC和WC，原子比Ti / W为2〜5，作为粘结相的钴的存在量为5〜25体积％。此外，金属陶瓷体具有至少一种来自元素周期表V的元素Mx，使得原子比Ti / Mx为4〜20，原子比W / Mx为1〜6。金属陶瓷体也具有使原子Cr / Co比为0.025〜0.14的量的Cr。金属陶瓷体包括具有（Ti，W，Mx）C合金边缘的未溶解的TiC芯以及在烧结期间形成的（Ti，W，Mx）C晶粒。还公开了制造金属陶瓷体的方法。

3. 发明授权

US06290902B1 Method for producing Ti (C,N)—(Ti,Ta,W) (C,N)—Co alloys for cutting tool applications 有权
标题翻译：生产用于切削刀具应用的Ti（C，N） - （Ti，Ta，W）（C，N）-Co合金的方法
公开(公告)号：US06290902B1
公开(公告)日：2001-09-18
申请号：US09563347
申请日：2000-05-03
申请人： Marco Zwinkels , Ulf Rolander , Gerold Weinl , Anders Piirhonen
发明人： Marco Zwinkels , Ulf Rolander , Gerold Weinl , Anders Piirhonen
IPC分类号： B22F300
CPC分类号： C22C29/04 , B22F2005/001 , B22F2998/10 , B22F2999/00 , C22C1/051 , B22F3/101 , B22F3/1035 , B22F3/1028 , B22F2201/11 , B22F2201/02 , B22F2201/04
摘要： The present invention relates to a method for manufacturing a sintered body of carbonitride alloy with titanium as the main component and cobalt as the binder phase and which does not have any compositional gradients or center porosity concentration after sintering. This is achieved by processing the material in a specific manner to obtain a lower melting point of the liquid phase in the interior of the body than in the surface while balancing the gas atmosphere outside the body with the alloy composition during all stages of the liquid phase sintering.
摘要翻译：本发明涉及一种以钛为主要成分的碳氮化合金和作为粘结相的钴的烧结体的制造方法，其烧结后不具有任何组成梯度或中心孔隙率的浓度。这是通过以特定的方式处理材料来实现的，以获得在体内的液相比在表面内部更低的熔点，同时在液相的所有阶段期间与合金组成物平衡体外的气体气氛烧结。

4. 发明授权

US6004371A Titanium-based carbonitride alloy with controllable wear resistance and toughness 失效
标题翻译：钛基碳氮化合物，耐磨性和韧性可控
公开(公告)号：US6004371A
公开(公告)日：1999-12-21
申请号：US875139
申请日：1998-02-02
申请人： Ulf Rolander , Gerold Weinl , Per Lindahl , Hans-Olof Andren
发明人： Ulf Rolander , Gerold Weinl , Per Lindahl , Hans-Olof Andren
IPC分类号： C22C29/02 , C22C1/05 , C22C29/04 , C23C30/00
CPC分类号： C22C29/04 , C23C30/005 , B22F2005/001 , B22F2998/00
摘要： The present invention relates to a sintered body of titanium-based carbonitride alloy comprising hard constituents containing at least tungsten in addition to titanium in a binder phase based on cobalt. There are four distinctly different microstructural components, namely: A) cores which are remnants of and have a metal composition determined by the raw material powder; B) tungsten-rich cores formed during the sintering; C) outer rims with intermediate tungsten content formed during the sintering; and D) a binder phase of a solid solution of at least titanium and tungsten in cobalt. Toughness and wear resistance are varied by adding WC, (Ti,W)C, and/or (Ti,W)(C,N) in varying amounts as raw materials.
摘要翻译： PCT No.PCT / SE96 / 00052 Sec。 371日期1998年2月2日 102（e）1998年2月2日PCT 1996年1月19日PCT PCT。 WO96 / 22403 PCT出版物日期：1996年7月25日本发明涉及一种钛基碳氮化物合金烧结体，其包含除基于钴的粘结相中的钛以外含有至少钨的硬质成分。有四种明显不同的显微组织成分，即：A）由原料粉末确定的残留物并具有金属组成的芯; B）在烧结期间形成的富钨芯; C）在烧结期间形成具有中等钨含量的外缘; 和D）至少钛和钨在钴中的固溶体的粘结相。通过以不同的量添加WC，（Ti，W）C和/或（Ti，W）（C，N）作为原料来改变韧性和耐磨性。

5. 发明授权

US5694639A Titanium based carbonitride alloy with binder phase enrichment 失效
标题翻译：钛基碳氮化物合金，具有粘结相富集
公开(公告)号：US5694639A
公开(公告)日：1997-12-02
申请号：US593905
申请日：1996-01-30
申请人： Rolf Gregor Oskarsson , Gerold Weinl
发明人： Rolf Gregor Oskarsson , Gerold Weinl
IPC分类号： C04B35/56 , B22F3/10 , C04B35/64 , C22C1/05 , C22C29/04 , B22F3/00
CPC分类号： C22C29/04 , B22F3/101 , B22F2998/00 , Y10T428/12021 , Y10T428/12056 , Y10T428/12993
摘要： A sintered body of titanium based carbonitride alloy containing hard constituents based on, in addition to titanium, one or more of the metals Zr, Hf, V, Nb, Ta, Cr, No or W in 5-30% binder phase based on Co and/or Ni is disclosed. The body has a binder phase enriched surface zone with a higher binder phase content than in the inner portion of the body in combination with an enrichment of simple hard constituents, i.e., the share of grains with core-rim structure is lower in the surface zone than in the inner of the body. A method of manufacturing the sintered carbonitride alloy is also provided which comprises forming a powder mixture containing binder phase containing Co and/or Ni and hard constituents of carbides and nitrides with titanium as a main component, the mixture having composition which is substoichiometric regarding an interstitial balance and sintering the mixture to completely transform the substoichiometric phases to stoichiometric by heating a) in vacuum to 1100-1200 C., b) in vacuum at about 1200 C. for about 30 minutes, c) in deoxidizing H.sub.2 -atmosphere for 15-30 minutes at about 1200 C., d) in N.sub.2 -atmosphere during heating to sintering temperature 1400-1600 C., and e) cooling to room temperature in vacuum or inert gas.
摘要翻译：一种钛基碳氮化物合金烧结体，其特征在于除了钛之外还含有一种或多种基于Co的5-30％粘结相中的一种或多种金属Zr，Hf，V，Nb，Ta，Cr，No或W 和/或Ni。与身体的内部部分相比，身体具有较高的粘结相含量的粘结相富集的表面区域，并与简单的硬质成分的富集相结合，即表面区域中具有核心 - 边缘结构的颗粒份额较低比在身体的内部。还提供了一种制造碳化氮烧结合金的方法，该方法包括形成含有Co和/或Ni的粘结相的粉末混合物以及以钛为主要成分的碳化物和氮化物的硬成分，该混合物具有关于间隙的亚化学计量的组成平衡并烧结混合物以通过在真空中加热a）在1100-1200℃，b）在约1200℃的真空中，将亚化学计量相完全转化为化学计量相约30分钟，c）在将H 2气氛中脱氧15- 在约1200℃下30分钟，d）在加热至烧结温度1400-1600℃期间的N 2气氛中，e）在真空或惰性气体中冷却至室温。

6. 发明授权

US5659872A Sintered carbonitride alloy and method of producing 失效
标题翻译：烧结碳氮化合物及其制备方法
公开(公告)号：US5659872A
公开(公告)日：1997-08-19
申请号：US495840
申请日：1995-06-28
申请人： Niclas During , Gerold Weinl
发明人： Niclas During , Gerold Weinl
IPC分类号： B23B27/14 , B23P15/28 , C22C1/05 , C22C14/00 , C22C29/04 , B22F1/00
CPC分类号： C22C1/056 , C22C29/04 , B22F2998/00 , B22F2998/10
摘要： There is provided a sintered titanium-based carbonitride alloy for metal cutting containing hard constituents based on Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and/or W and 3-30% binder phase based on Co and/or Ni. The structure contains 10-50% by weight well-dispersed Ti-rich hard constituent grains essentially without core-rim structure with a mean grain size of 0.8-5 .mu.m in a conventional carbonitride alloy matrix with a mean grain size of the hard constituents of 1-2 .mu.m. The Ti-rich hard constituent grains are essentially rounded, non-angular grains with an approximately logarithmic normal grain size distribution with a standard deviation of
摘要翻译：提供了一种用于金属切割的烧结钛基碳氮化物合金，其包含基于Co和/或基于Ti，Zr，Hf，V，Nb，Ta，Cr，Mo和/或W的基于Co和/ 倪该结构在常规碳氮化物合金基质中含有10-50％重量的基本上不具有核 - 边缘结构的平均粒径为0.8-5μm的富Ti分散的硬质组分颗粒，其具有硬组分的平均晶粒尺寸 1-2亩富含Ti的硬质组分颗粒基本上是具有近似对数正态晶粒尺寸分布的圆形，非角度晶粒，标准偏差<0.23对数μm。

7. 发明申请

US20100150769A1 CERMET BODY AND A METHOD OF MAKING A CERMET BODY 有权
标题翻译： CERMET身体和制造CERMET身体的方法
公开(公告)号：US20100150769A1
公开(公告)日：2010-06-17
申请号：US12630998
申请日：2009-12-04
申请人： Gerold WEINL , Malin MÅRTENSSON
发明人： Gerold WEINL , Malin MÅRTENSSON
IPC分类号： B22F1/00 , C22C29/02 , B22F3/12
CPC分类号： C22C29/10 , B22F2005/001 , C22C1/051
摘要： The invention relates to a cermet body essentially free from nitrogen where the binder phase is Co in an amount of from about 5 to about 25 vol % Co, further comprising TiC and WC in amounts so that the atomic Ti:W ratio is from about 2.5 to about 10. The cermet body further comprising Cr in an amount such that the atomic Cr:Co ratio is from about 0.025 to about 0.14. The cermet body is free from nucleated of Ti—W—C cores. The invention also relates to a method of making a cermet body.
摘要翻译：本发明涉及一种基本上不含氮的金属陶瓷体，其中粘结相为Co，其量为约5至约25体积％Co，进一步包含TiC和WC，其量使得原子Ti：W比为约2.5 金属陶瓷体还含有使原子Cr：Co比为约0.025至约0.14的量的Cr。金属陶瓷体不含Ti-W-C核的成核体。本发明还涉及制造金属陶瓷体的方法。

8. 发明授权

US07645316B2 Ti(C,N)-(Ti,Nb,W)(C,N)-Co alloy for finishing and semifinishing turning cutting tool applications 有权
标题翻译： Ti（C，N） - （Ti，Nb，W）（C，N）-Co合金，用于精加工和半成品车削刀具应用
公开(公告)号：US07645316B2
公开(公告)日：2010-01-12
申请号：US11589253
申请日：2006-10-30
申请人： Ulf Rolander , Marco Zwinkels , Gerold Weinl
发明人： Ulf Rolander , Marco Zwinkels , Gerold Weinl
IPC分类号： C22C29/04
CPC分类号： C22C1/051 , B22F3/1007 , B22F2998/00 , B22F2999/00 , C22C29/04 , B22F2207/07 , B22F1/0003 , B22F2201/02 , B22F2201/04
摘要： A titanium based carbonitride alloy contains Ti, Nb, W, C, N and Co. The alloy also contains, in addition to Ti, Co with only impurity levels of Ni and Fe, 4-7 at % Nb, 3-8 at % W and has a C/(C+N) ratio of 0.50-0.75. The Co content is 9-
摘要翻译：钛基碳氮化物合金含有Ti，Nb，W，C，N和Co。该合金除了Ti，Co之外，还含有仅具有Ni和Fe杂质含量，4-7at％Nb，3-8at％ W，C /（C + N）比为0.50-0.75。 Co含量在普通整理应用中为9- <12at％，半成品应用为12-16％。未溶解的Ti（C，N）芯的量必须保持在硬组分的26至37体积％之间，余量为含有Ti，Nb和W的一种或多种复合碳氮化物。本发明的合金特别适用于钢的半成品和铸铁。

9. 发明授权

US07588621B2 Ti(C,N)-(Ti,Nb,W)(C,N)-co alloy for milling cutting tool applications 有权
标题翻译：用于铣削刀具应用的Ti（C，N） - （Ti，Nb，W）（C，N）-co合金
公开(公告)号：US07588621B2
公开(公告)日：2009-09-15
申请号：US11892455
申请日：2007-08-23
申请人： Gerold Weinl , Ulf Rolander , Marco Zwinkels
发明人： Gerold Weinl , Ulf Rolander , Marco Zwinkels
IPC分类号： B22F3/12 , C22C14/00
CPC分类号： B22F3/1007 , B22F2005/001 , B22F2998/00 , B22F2999/00 , C22C1/051 , C22C29/04 , B22F2207/07 , B22F2201/02 , B22F2201/04 , B22F1/0003
摘要： A titanium based carbonitride alloy containing Ti, Nb, W, C, N and Co. The alloy also contains, in addition to Ti, 9-14 at % Co with only impurity levels of Ni and Fe, 1-
摘要翻译：包含Ti，Nb，W，C，N和Co的钛基碳氮化物合金除了Ti之外，该合金还含有仅具有Ni和Fe的杂质含量的9-14at％Co，1- <3at％的Nb ，3-8at％W，C /（C + N）比为0.50-0.75。未溶解的Ti（C，N）芯的量应保持在硬组分的26至37体积％之间，余量为含有Ti，Nb和W的一种或多种复合碳氮化物。该合金特别适用于钢的研磨。

10. 发明授权

US06340445B1 Ti(C,N)-(Ti,Ta,W)(C,N)-Co alloy for superfinishing cutting tool applications 有权
标题翻译：用于超精加工切削刀具应用的Ti（C，N） - （Ti，Ta，W）（C，N）-Co合金
公开(公告)号：US06340445B1
公开(公告)日：2002-01-22
申请号：US09563502
申请日：2000-05-03
申请人： Anders Piirhonen , Marco Zwinkels , Ulf Rolander , Gerold Weinl
发明人： Anders Piirhonen , Marco Zwinkels , Ulf Rolander , Gerold Weinl
IPC分类号： C22C1400
CPC分类号： C22C29/04 , B22F2005/001
摘要： A sintered body of a carbonitride alloy with titanium as main component which has improved properties particularly when used as cutting tool material in light finishing cutting operations at high cutting speed. This has been achieved by combining a carbonitride based hard phase of specific chemical composition with an extremely solution hardened Co-based binder phase.
摘要翻译：以钛为主要成分的碳氮化合金的烧结体，特别是在高切削速度的轻精加工切削加工中作为切削刀具材料时，具有改善的特性。这是通过将特定化学组成的碳氮化物基硬相与极硬溶解硬化的Co基粘合剂相结合而实现的。

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