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1. 发明授权

US4234696A 2-Chloroethyl phosphonate compositions 失效
标题翻译： 2-氯乙基膦酸酯组合物
公开(公告)号：US4234696A
公开(公告)日：1980-11-18
申请号：US27581
申请日：1979-04-06
申请人： Gail H. Birum , Richard F. Jansen
发明人： Gail H. Birum , Richard F. Jansen
IPC分类号： C08J9/00 , C08K5/5337 , C08G18/14
CPC分类号： C08J9/0038 , C08K5/5337 , C08J2375/04
摘要： The present invention relates to 2-chloroethylphosphonate mixtures which are effective flame retardants for organic polymeric materials and have especially beneficial effects on rise and tack-free times in the production of rigid polyurethane foams.
摘要翻译：本发明涉及作为有机聚合物材料的有效阻燃剂的2-氯乙基膦酸酯混合物，并且在生产刚性聚氨酯泡沫体中对上升和无粘着时间具有特别有利的影响。

2. 发明授权

US4713489A Preparation of N-substituted arylsulfonamides 失效
标题翻译： N-取代芳基磺酰胺的制备
公开(公告)号：US4713489A
公开(公告)日：1987-12-15
申请号：US820876
申请日：1986-01-16
申请人： Gail H. Birum , Richard F. Jansen
发明人： Gail H. Birum , Richard F. Jansen
IPC分类号： C07C311/15 , C07C143/79
CPC分类号： C07C311/15
摘要： N-substituted arylsulfonamides which comprises the steps of (a) reacting an aryl hydrocarbon with chlorosulfonic acid to form a crude chlorosulfonation reaction product, (b) adding said crude reaction product to a mixture comprising an aliphatic amine, an alkali or alkaline earth metal hydroxide and water to form an amidation reaction mixture, (c) maintaining the temperature of the amidation reaction mixture at between about 50.degree. C. and 100.degree. C. and the pH at above about 7 with stirring for a period of time of up to about 2 hours, and optionally (d) separating the resulting N-substituted arylsulfonamide from the amidation reaction product.
摘要翻译： N-取代的芳基磺酰胺，其包括以下步骤：（a）使芳基烃与氯磺酸反应以形成粗氯磺化反应产物，（b）将所述粗反应产物加入到包含脂族胺，碱金属或碱土金属氢氧化物和水以形成酰胺化反应混合物，（c）将酰胺化反应混合物的温度保持在约50℃至100℃，pH高于约7，同时搅拌一段时间至多约 2小时，任选地（d）从酰胺化反应产物中分离得到的N-取代的芳基磺酰胺。

3. 发明授权

US4179482A 2-Chloroethyl phosphonate compositions 失效
标题翻译： 2-氯乙基膦酸酯组合物
公开(公告)号：US4179482A
公开(公告)日：1979-12-18
申请号：US945668
申请日：1978-09-25
申请人： Gail H. Birum , Richard F. Jansen
发明人： Gail H. Birum , Richard F. Jansen
IPC分类号： C07F9/32 , C07F9/40 , C08J9/00 , C08K5/5337
CPC分类号： C08J9/0038 , C07F9/3211 , C07F9/4075 , C08K5/5337 , C08J2375/04
摘要： The present invention relates to 2-chloroethylphosphonate mixtures which are effective flame retardants for organic polymeric materials and have especially beneficial effects on rise and tack-free times in the production of rigid polyurethane foams.
摘要翻译：本发明涉及作为有机聚合物材料的有效阻燃剂的2-氯乙基膦酸酯混合物，并且在生产刚性聚氨酯泡沫体中对上升和无粘性时间具有特别有利的影响。

4. 发明授权

US4081463A Production of 2-carboxyethyl(phenyl)phosphinic acid 失效
标题翻译： 2-羧基乙基（苯基）次膦酸的制备
公开(公告)号：US4081463A
公开(公告)日：1978-03-28
申请号：US755363
申请日：1976-12-27
申请人： Gail H. Birum , Richard F. Jansen
发明人： Gail H. Birum , Richard F. Jansen
IPC分类号： C08K5/53 , C07F9/30 , C07F9/6574 , C08K5/00 , C08K5/5313 , C08L67/00
CPC分类号： C08K5/5313 , C07F9/301 , C08K5/53
摘要： 2-Carboxyethyl(phenyl)phosphinic acid is prepared in two stages by first reacting dichloro(phenyl)phosphine with acrylic acid employed at a molar excess of 25% to 45% to form a mixture of three intermediates, namely 3-(chlorophenylphosphinyl)propionyl chloride, the cyclic anhydride of 2-carboxyethyl(phenyl)phosphinic acid and the mixed anhydride of acrylic acid with 3-chlorocarbonylethyl(phenyl)phosphinic acid. The second stage of the process is the hydrolysis of the mixture of three intermediates set forth above to obtain the desired product. The product is useful as a flame retardant material when used with organic polymers such as polyesters.
摘要翻译：通过首先使二氯（苯基）膦与摩尔过量为25％至45％的丙烯酸反应形成2-三羧酸（苯基）次膦酸的三种中间体，即3-（氯苯基氧膦基）丙酰基氯化物，2-羧基乙基（苯基）次膦酸的环状酸酐和丙烯酸与3-氯代羰基乙基（苯基）次膦酸的混合酸酐。该方法的第二阶段是水解上述三种中间体的混合物以获得所需的产物。当与有机聚合物如聚酯一起使用时，该产品可用作阻燃材料。

5. 发明授权

US3980618A Cyclic organophosphorus amides 失效
标题翻译：环状有机磷酰胺
公开(公告)号：US3980618A
公开(公告)日：1976-09-14
申请号：US582963
申请日：1975-06-02
申请人： Gail H. Birum
发明人： Gail H. Birum
IPC分类号： C07F9/30 , C07F9/38 , C07F9/6584 , C09K21/12 , C07F9/24 , C07F9/44
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3808 , C07F9/6584
摘要： The present invention relates to new compounds containing urea and organophosphorus amide moieties in cyclic structures as shown in the following equation: ##EQU1## where R is aryl or chloroalkyl of 2 to 10 carbon atoms,R' is aryl of 6 to 10 carbon atoms,R" is hydrogen, alkyl, alkenyl, furanyl or aryl of 1 to 15 carbon atoms and substituted aryl forms where the substituent is fluorine, chlorine, bromine, cyano, hydroxyl, alkyloxy, alkylthio or mixtures of such substituents, andY is O or S.The cyclic organophosphorus amides have biological activity and are also useful as fire retardants and as lead scavengers in gasoline.
摘要翻译：本发明涉及循环结构中含有脲和有机磷酰胺部分的新化合物，如下式所示：Y PARALLEL-ROH CH3NHCNHCH3 +（RO）2PR'+ R''CHO - > O PARALLEL R'-P-CHR 其中R为2至10个碳原子的芳基或氯代烷基，R'为6至10个碳原子的芳基，R“为氢，烷基，烯基，呋喃基或芳基，为1至15个碳原子和取代的芳基，其中取代基是氟，氯，溴，氰基，羟基，烷氧基，烷硫基或这些取代基的混合物，Y是O或S.

6. 发明授权

US4108949A 6-Hydroxy (alkoxy) phenylthiomethylene di(organophosphorus) compounds and process for making same 失效
标题翻译： 6-羟基（烷氧基）苯基亚甲基二（有机磷）化合物及其制备方法
公开(公告)号：US4108949A
公开(公告)日：1978-08-22
申请号：US756507
申请日：1977-01-03
申请人： Gail H. Birum
发明人： Gail H. Birum
IPC分类号： C07F9/32 , C07F9/40 , C07F9/53 , C07F9/535 , C08K5/53 , C08K5/5317 , C08K5/5337 , C08K5/5397 , C07F9/50
CPC分类号： C07F9/5329 , C07F9/3235 , C07F9/4043 , C07F9/5352 , C08K5/53 , C08K5/5317 , C08K5/5337 , C08K5/5397
摘要： The invention relates to o-hydroxy(or alkyloxy)-phenythiomethylenedi(organophosphorus) compounds and to processes for making the same. The compounds have the general formula ##STR1## where L is H or R',R' is alkyl of 1 to 6 carbon atomsM is H, Cl or Br,X is Br, Cl, F, CF.sub.3, NO.sub.2, CN, CO.sub.2 R', SO.sub.2 R', or ##STR2## and R is phenyl, alkyl of 1 to 3 carbon atoms, or OR'.The compounds of the invention have utility as corrosion inhibitors, oil additives and flame retardants.
摘要翻译：本发明涉及邻羟基（或烷氧基） - 苯基亚甲基二（有机磷）化合物及其制备方法。这些化合物具有通式其中L是H或R'，R'是1至6个碳原子的烷基，M是H，Cl或Br，X是Br，Cl，F，CF 3，NO 2，CN，CO 2 R '，SO2R'或，R是苯基，1至3个碳原子的烷基或OR'。

7. 发明授权

US4071584A Hydroxyphenylthiophosphoranylidene organophosphorus compounds 失效
标题翻译：羟基苯硫基亚正膦基有机磷化合物
公开(公告)号：US4071584A
公开(公告)日：1978-01-31
申请号：US756504
申请日：1977-01-03
申请人： Gail H. Birum
发明人： Gail H. Birum
IPC分类号： C07F9/40 , C07F9/535 , C08K5/5333 , C07F9/08 , C08K5/53
CPC分类号： C07F9/5352 , C07F9/4025 , C08K5/5333
摘要： The present invention relates to a new hydroxyphenylthiophosphoranylidene organophoshorus compounds and to a process involving an unusual phenyl migration for their preparation. The general reaction for the preparation of the products of the present invention is set forth below: ##STR1## WHERE X is halogen (F, Cl, Br), NO.sub.2, CN, CO.sub.2 R', SO.sub.2 R', CF.sub.3 or ##STR2## R is phenyl, alkyl of 1 to 3 carbon atoms, or OR', and R' is alkyl of 1 to 6 carbon atoms.The compounds of the invention are useful as flame retardants, lubricating oil additives and as corrosion inhibitors.
摘要翻译：本发明涉及一种新的羟基苯基硫代亚正膦有机磷化合物及其制备中涉及不寻常的苯基迁移的方法。制备本发明产品的一般反应如下：X是卤素（F，Cl，Br），NO 2，CN，CO 2 R'，SO 2 R'，CF 3或 R是苯基，1至3个碳原子的烷基或OR'，R'是1至6个碳原子的烷基。

8. 发明授权

US4036913A Phosphorus compounds 失效
标题翻译：磷化合物
公开(公告)号：US4036913A
公开(公告)日：1977-07-19
申请号：US595959
申请日：1975-07-14
申请人： Gail H. Birum
发明人： Gail H. Birum
IPC分类号： A01N57/22 , C07F9/32 , C07F9/38 , C07F9/53 , C08K5/5353 , C07F9/40
CPC分类号： C07F9/5304 , A01N57/22 , C07F9/3211 , C07F9/3808 , C08K5/5353
摘要： The present invention relates to new nitrogen-containing organophosphorus compounds having aryloxy substituents bonded to phosphorus in ester structures. ##STR1## R' is aryl of 6 to 10 carbon atoms, R" is hydrogen, alkyl, aryl or haloaryl of 1 to 15 carbon atoms, or no more than one carboethoxymethyl group, and where the halogen on the aryl group is bromine, chlorine or fluorine,R'" is alkyl, alkenyl or aryl groups of 1 to 15 carbon atoms and substituted aryl forms where the subtituent is fluorine, chlorine, bromine, nitro, cyano, hydroxyl, alkyloxy or mixtures of such substituents, andZ is CO, CS or SO.sub.2.The phosphorus compounds have utility as fire retardants and as biologically active materials.
摘要翻译：本发明涉及在酯结构中具有与磷结合的芳氧基取代基的新的含氮有机磷化合物。 R'是6至10个碳原子的芳基，R“是氢，具有1至15个碳原子的烷基，芳基或卤代芳基，或不超过一个羰乙氧基甲基，其中芳基上的卤素基团是溴，氯或氟，R“是具有1至15个碳原子的烷基，烯基或芳基和取代的芳基，其中取代基是氟，氯，溴，硝基，氰基，羟基，烷氧基或其混合物取代基，Z为CO，CS或SO 2。

9. 发明授权

US4003965A Phosphorus compounds 失效
标题翻译：磷化合物
公开(公告)号：US4003965A
公开(公告)日：1977-01-18
申请号：US589097
申请日：1975-06-23
申请人： Gail H. Birum
发明人： Gail H. Birum
IPC分类号： C07F9/38 , C09K21/12 , D06M13/288 , D06M13/432 , C07F9/40
CPC分类号： D06M13/432 , C07F9/3808 , C09K21/12 , D06M13/288
摘要： The present invention relates to new nitrogen-containing organophosphorus compounds having chloro- or bromoalkyloxy substituents bonded to phosphorus in ester structures. ##STR1## R is haloalkyl of 2 to 5 carbon atoms, and R' is alkyl or alkenyl of 1 to 15 carbon atoms.The phosphorus compounds have utility as fire retardants and as biologically active materials.
摘要翻译：本发明涉及在酯结构中具有键合到磷上的氯代或溴代烷氧基取代基的新的含氮有机磷化合物。 R图示为2〜5个碳原子的卤代烷基，R'为1〜15个碳原子的烷基或链烯基。

10. 发明授权

US4193914A Phosphorus-containing propionates 失效
标题翻译：含磷的丙酸酯
公开(公告)号：US4193914A
公开(公告)日：1980-03-18
申请号：US027562
申请日：1979-04-06
申请人： Gail H. Birum , Richard F. Jansen
发明人： Gail H. Birum , Richard F. Jansen
IPC分类号： C07F9/32 , C07F9/40 , C08J9/00 , C08K5/5313 , C08K5/53
CPC分类号： C08J9/0038 , C07F9/3211 , C07F9/4075 , C08K5/5313 , C08J2375/04
摘要： The present invention relates to 2-chloroalkyl (2-chloroalkyloxy)hydrocarbylphosphinylpropionates and a process for the preparation thereof. The invention also includes combinations of the said 2-chloroalkyl (2-chloroalkyloxy)hydrocarbylphosphinylpropionates with organic polymer substrates, such as polyurethanes and polyesters, in order to impart enhanced fire-retardancy to such otherwise flammable substrates.
摘要翻译：本发明涉及2-氯烷基（2-氯烷氧基）烃基氧膦基丙酸酯及其制备方法。本发明还包括所述2-氯烷基（2-氯烷氧基）烃基膦基丙酸酯与有机聚合物基质如聚氨酯和聚酯的组合，以便赋予这种其它可燃性底物增强的阻燃性。

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