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    • 1. 发明申请
    • Production of photoluminescent silicon nanoparticles having surfaces that are essentially free of residual oxygen
    • 生产具有基本上没有残余氧的表面的光致发光硅纳米颗粒
    • US20070196297A1
    • 2007-08-23
    • US11406940
    • 2006-04-19
    • Eli RuckensteinMark SwihartFengjun Hua
    • Eli RuckensteinMark SwihartFengjun Hua
    • A61K8/19H01J1/62
    • C30B29/06C01B33/02C30B29/60Y10S977/774Y10S977/814Y10T428/24273
    • The present invention relates to a method for preparing photoluminescent silicon nanoparticles having uniformly hydrogen-terminated surfaces that are essentially free of residual oxygen. The present invention also relates to a method of preparing a blue-emitting photoluminescent silicon nanoparticle. The present invention further relates to a composition that includes a photoluminescent silicon nanoparticle having a surface that is uniformly hydrogen-terminated and essentially free of residual oxygen. The present invention also relates to a composition including a photoluminescent silicon nanoparticle having a surface that is uniformly coated with an organic layer and essentially free of residual oxygen. The present invention additionally relates to a composition including a photoluminescent silicon nanoparticle stably dispersed in an organic solvent and having a surface that is uniformly coated with an organic layer and essentially free of residual oxygen.
    • 本发明涉及一种制备基本上没有残余氧的具有均匀氢封端表面的光致发光硅纳米颗粒的方法。 本发明还涉及一种制备蓝色发光光致发光硅纳米颗粒的方法。 本发明还涉及包含光致发光硅纳米颗粒的组合物,所述光致发光硅纳米颗粒具有均匀氢终止且基本上没有残余氧的表面。 本发明还涉及包含光致发光硅纳米颗粒的组合物,其具有均匀地涂覆有机层并且基本上没有残余氧的表面。 本发明还涉及一种组合物,其包含稳定分散在有机溶剂中并具有均匀涂覆有机层并且基本上没有残余氧的表面的光致发光硅纳米颗粒。
    • 2. 发明授权
    • Breakable crosslinkers an use for preparation of polymers using same
    • 可破坏的交联剂和用于制备使用其的聚合物
    • US06323360B1
    • 2001-11-27
    • US09712324
    • 2000-11-14
    • Eli RuckensteinHongmin Zhang
    • Eli RuckensteinHongmin Zhang
    • C08F2210
    • C08F290/14C07C69/734C08F20/12C08F220/14C08F297/023C08F297/026
    • The present invention discloses the synthesis of a novel crosslinker having the following structure: R1 is C(R8) (R9) wherein (R8) is H, or an alkyl group having 1-5 carbon atoms, and (R9) is H, or an alkyl group having 1-5 carbon atoms. R2 is H, or an alkyl group having 1-5 carbon atoms. R3 is H or an alkyl group having 1-5 carbon atoms. R4 is an alkyl group having 1-5 carbon atoms. R5 is H or an alkyl group having 1-5 carbon atoms. R6 is H or an alkyl group having 1-5 carbon atoms. R7 is C(R10) (R11) wherein (R10) is H, or an alkyl group having 1-5 carbon atoms, and (R11) is H, or an alkyl group having 1-5 carbon atoms. The crosslinker is stable in a basic environment, but decomposable in an acidic environment.
    • 本发明公开了具有以下结构的新型交联剂的合成:R1是C(R8)(R9)其中(R8)是H或具有1-5个碳原子的烷基,(R9)是H,或 具有1-5个碳原子的烷基。 R2是H或具有1-5个碳原子的烷基。 R3是H或具有1-5个碳原子的烷基。 R4是具有1-5个碳原子的烷基。 R5是H或具有1-5个碳原子的烷基。 R6是H或具有1-5个碳原子的烷基。 R 7是C(R 10)(R 11),其中(R 10)是H或具有1-5个碳原子的烷基,(R 11)是H或具有1-5个碳原子的烷基。 交联剂在碱性环境中稳定,但在酸性环境中可分解。
    • 4. 发明授权
    • Graft, graft-block, block-graft, and star-shaped copolymers and methods of making them
    • 接枝,接枝嵌段,嵌段接枝和星形共聚物及其制备方法
    • US06384146B1
    • 2002-05-07
    • US09542762
    • 2000-04-04
    • Eli RuckensteinHongmin Zhang
    • Eli RuckensteinHongmin Zhang
    • C08F25502
    • C08F265/06C08F255/02C08F287/00C08F291/00C08F297/00C08F297/02C08F297/023C08F297/026C08F297/04
    • The present invention relates to a continuous method of preparing a block-graft or star-shaped copolymer. This method involves providing a living polymer, mixing the living polymer with a first monomer under conditions effective to produce a block copolymer, wherein the first monomer includes a polymerization site and a polymerization initiation site, and mixing the block copolymer with a second monomer under conditions effective to produce a block-graft or star-shaped copolymer. The present invention also relates to a continuous method of preparing a graft or graft-block copolymer. This method involves mixing a first monomer and a second monomer under conditions effective to produce a copolymer of the first and second monomers, wherein the second monomer comprises a polymerization site and a polymerization initiation site, mixing the copolymer with a third monomer under conditions effective to produce a graft copolymer, and mixing the graft copolymer with a fourth monomer under conditions effective to produce a graft-block copolymer. The present invention also relates to graft, graft-block, block-graft, and star-shaped copolymers produced by the methods of the present invention.
    • 本发明涉及制备嵌段接枝或星形共聚物的连续方法。 该方法包括提供活性聚合物,在有效产生嵌段共聚物的条件下将活性聚合物与第一单体混合,其中第一单体包括聚合位点和聚合引发位点,并将嵌段共聚物与第二单体在条件 有效地制备嵌段接枝或星形共聚物。 本发明还涉及制备接枝或接枝嵌段共聚物的连续方法。 该方法包括在有效产生第一和第二单体的共聚物的条件下混合第一单体和第二单体,其中第二单体包含聚合位点和聚合引发位点,将共聚物与第三单体混合, 产生接枝共聚物,并在有效产生接枝嵌段共聚物的条件下将接枝共聚物与第四单体混合。 本发明还涉及通过本发明的方法制备的接枝,接枝嵌段,嵌段接枝和星形共聚物。
    • 7. 发明授权
    • Production of photoluminescent silicon nanoparticles having surfaces that are essentially free of residual oxygen
    • 生产具有基本上没有残余氧的表面的光致发光硅纳米颗粒
    • US08029698B2
    • 2011-10-04
    • US11406940
    • 2006-04-19
    • Eli RuckensteinMark T. SwihartFengjun Hua
    • Eli RuckensteinMark T. SwihartFengjun Hua
    • C09K11/08C09K11/66B32B3/10H01L21/20H01L21/36
    • C30B29/06C01B33/02C30B29/60Y10S977/774Y10S977/814Y10T428/24273
    • The present invention relates to a method for preparing photoluminescent silicon nanoparticles having uniformly hydrogen-terminated surfaces that are essentially free of residual oxygen. The present invention also relates to a method of preparing a blue-emitting photoluminescent silicon nanoparticle. The present invention further relates to a composition that includes a photoluminescent silicon nanoparticle having a surface that is uniformly hydrogen-terminated and essentially free of residual oxygen. The present invention also relates to a composition including a photoluminescent silicon nanoparticle having a surface that is uniformly coated with an organic layer and essentially free of residual oxygen. The present invention additionally relates to a composition including a photoluminescent silicon nanoparticle stably dispersed in an organic solvent and having a surface that is uniformly coated with an organic layer and essentially free of residual oxygen.
    • 本发明涉及一种制备基本上没有残余氧的具有均匀氢封端表面的光致发光硅纳米颗粒的方法。 本发明还涉及一种制备蓝色发光光致发光硅纳米颗粒的方法。 本发明还涉及包含光致发光硅纳米颗粒的组合物,所述光致发光硅纳米颗粒具有均匀氢终止且基本上没有残余氧的表面。 本发明还涉及包含光致发光硅纳米颗粒的组合物,其具有均匀地涂覆有机层并且基本上没有残余氧的表面。 本发明还涉及一种组合物,其包含稳定分散在有机溶剂中并具有均匀涂覆有机层并且基本上没有残余氧的表面的光致发光硅纳米颗粒。