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1. 发明授权

US08926732B2 Imidazolium-based room-temperature ionic liquids, polymers, monomers, and membranes incorporating same 有权
标题翻译：基于咪唑鎓的室温离子液体，聚合物，单体和并入其中的膜
公开(公告)号：US08926732B2
公开(公告)日：2015-01-06
申请号：US13386780
申请日：2010-07-23
申请人： Jason E. Bara , Trevor K. Carlisle , Evan S. Hatakeyama , Douglas L. Gin , Richard D. Noble , Robert L. Kerr , Andrew L. LaFrate
发明人： Jason E. Bara , Trevor K. Carlisle , Evan S. Hatakeyama , Douglas L. Gin , Richard D. Noble , Robert L. Kerr , Andrew L. LaFrate
IPC分类号： B01D53/22 , B01D71/64 , C09K3/00 , C09K19/58 , B01D67/00 , B01D69/10 , B01D69/12 , B01D71/62 , B01J31/02 , C08G73/06 , C08K5/3445 , C08L79/04 , C09K19/34 , C09K19/38 , B01J31/06
CPC分类号： B01D53/228 , B01D67/0006 , B01D69/10 , B01D69/12 , B01D71/28 , B01D71/44 , B01D71/62 , B01D2252/30 , B01D2256/10 , B01D2256/16 , B01D2256/22 , B01D2256/245 , B01D2257/102 , B01D2257/108 , B01D2257/504 , B01D2257/7025 , B01D2323/30 , B01D2323/345 , B01D2325/16 , B01J31/0284 , B01J31/06 , C08G73/0616 , C08K5/3445 , C09K19/348 , C09K19/3823 , C09K19/582 , Y02C10/10 , Y02C20/20 , Y02P20/152 , Y02P20/156 , C08L79/04
摘要： The present invention provides gels, solutions, films, membranes, compositions, and other materials containing polymerized and/or non-polymerized room-temperature ionic liquids (RTILs). These materials are useful in catalysis, gas separation and as antistatic agents. The RTILs are preferably imidazolium-based RTILs which are optionally substituted, such as with one or more hydroxyl groups. Optionally, the materials of the present invention are composite materials comprising both polymerized and non-polymerized RTILs. The RTIL polymer is formed from polymerized RTIL cations typically synthesized as monomers and polymerized in the presence of the non-polymerized RTIL cations to provide a solid composite material. The non-polymerized RTIL cations are not covalently bound to the cationic polymer but remain as free cations within the composite material able to associate with charged subunits of the polymer. These composite materials are useful in catalysis, gas separation, and antistatic applications.
摘要翻译：本发明提供了含有聚合和/或未聚合的室温离子液体（RTIL）的凝胶，溶液，膜，膜，组合物和其它材料。这些材料可用于催化，气体分离和抗静电剂。 RTIL优选为任选取代的咪唑鎓基RTI，例如具有一个或多个羟基。任选地，本发明的材料是包含聚合和未聚合的RTIL的复合材料。 RTIL聚合物由通常作为单体合成的聚合的RTI阳离子形成，并在非聚合的RTIL阳离子存在下聚合以提供固体复合材料。未聚合的RTIL阳离子不与阳离子聚合物共价结合，而是作为能够与聚合物的带电亚基缔合的复合材料中的游离阳离子保留。这些复合材料可用于催化，气体分离和抗静电应用。

2. 发明申请

US20120186446A1 IMIDAZOLIUM-BASED ROOM-TEMPERATURE IONIC LIQUIDS, POLYMERS, MONOMERS, AND MEMBRANES INCORPORATING SAME 有权
标题翻译：基于咪达质的室温离子液体，聚合物，单体和与其混合的膜
公开(公告)号：US20120186446A1
公开(公告)日：2012-07-26
申请号：US13386780
申请日：2010-07-23
申请人： Jason Bara , Trevor K. Carlisle , Evan S. Hatakeyama , Douglas L. Gin , Richard D. Noble , Robert L. Kerr , Andrew L. LaFrate
发明人： Jason Bara , Trevor K. Carlisle , Evan S. Hatakeyama , Douglas L. Gin , Richard D. Noble , Robert L. Kerr , Andrew L. LaFrate
IPC分类号： C09K3/00 , B01D53/22 , B01D71/64
CPC分类号： B01D53/228 , B01D67/0006 , B01D69/10 , B01D69/12 , B01D71/28 , B01D71/44 , B01D71/62 , B01D2252/30 , B01D2256/10 , B01D2256/16 , B01D2256/22 , B01D2256/245 , B01D2257/102 , B01D2257/108 , B01D2257/504 , B01D2257/7025 , B01D2323/30 , B01D2323/345 , B01D2325/16 , B01J31/0284 , B01J31/06 , C08G73/0616 , C08K5/3445 , C09K19/348 , C09K19/3823 , C09K19/582 , Y02C10/10 , Y02C20/20 , Y02P20/152 , Y02P20/156 , C08L79/04
摘要： The present invention provides gels, solutions, films, membranes, compositions, and other materials containing polymerized and/or non-polymerized room-temperature ionic liquids (RTILs). These materials are useful in catalysis, gas separation and as antistatic agents. The RTILs are preferably imidazolium-based RTILs which are optionally substituted, such as with one or more hydroxyl groups. Optionally, the materials of the present invention are composite materials comprising both polymerized and non-polymerized RTILs. The RTIL polymer is formed from polymerized RTIL cations typically synthesized as monomers and polymerized in the presence of the non-polymerized RTIL cations to provide a solid composite material. The non-polymerized RTIL cations are not covalently bound to the cationic polymer but remain as free cations within the composite material able to associate with charged subunits of the polymer. These composite materials are useful in catalysis, gas separation, and antistatic applications.
摘要翻译：本发明提供了含有聚合和/或未聚合的室温离子液体（RTIL）的凝胶，溶液，膜，膜，组合物和其它材料。这些材料可用于催化，气体分离和抗静电剂。 RTIL优选为任选取代的咪唑鎓基RTI，例如具有一个或多个羟基。任选地，本发明的材料是包含聚合和未聚合的RTIL的复合材料。 RTIL聚合物由通常作为单体合成的聚合的RTI阳离子形成，并在非聚合的RTIL阳离子存在下聚合以提供固体复合材料。未聚合的RTIL阳离子不与阳离子聚合物共价结合，而是作为能够与聚合物的带电亚基缔合的复合材料中的游离阳离子保留。这些复合材料可用于催化，气体分离和抗静电应用。

3. 发明申请

US20100096327A1 POLYMER COATINGS THAT RESIST ADSORPTION OF PROTEINS 审中-公开
标题翻译：耐高温蛋白吸附的聚合物涂层
公开(公告)号：US20100096327A1
公开(公告)日：2010-04-22
申请号：US12563717
申请日：2009-09-21
申请人： Douglas L. GIN , Evan S. HATAKEYAMA , Christopher J. GABRIEL , Benny Dean FREEMAN , Hao JU
发明人： Douglas L. GIN , Evan S. HATAKEYAMA , Christopher J. GABRIEL , Benny Dean FREEMAN , Hao JU
IPC分类号： B01D61/14 , B05D3/02 , B01D69/12
CPC分类号： C02F1/444 , B01D69/125 , B01D2325/14 , B01D2325/48 , C02F1/44 , C02F1/441
摘要： The invention provides membranes useful for filtration of water and other liquids. The membrane may be a composite membrane having a polymer layer incorporating quaternary phosphonium or ammonium groups. The polymer layer may be resistant to protein adsorption in an aqueous environment. The membrane may also be a surface-modified membrane in which a polymer having quaternary phosphonium or ammonium groups is covalently attached to the membrane surface. Methods for making and using the membranes of the invention are also provided.
摘要翻译：本发明提供了用于过滤水和其它液体的膜。膜可以是具有掺入季鏻或铵基的聚合物层的复合膜。聚合物层可以在水性环境中耐蛋白质吸附。膜也可以是其中具有季鏻或铵基团的聚合物共价连接到膜表面的表面改性膜。还提供了制备和使用本发明的膜的方法。

4. 发明申请

US20090291872A1 Ionic Liquids and Methods For Using the Same 审中-公开
标题翻译：离子液体及其使用方法
公开(公告)号：US20090291872A1
公开(公告)日：2009-11-26
申请号：US12333115
申请日：2008-12-11
申请人： Jason E. Bara , Dean E. Camper , Douglas L. Gin , Richard D. Noble
发明人： Jason E. Bara , Dean E. Camper , Douglas L. Gin , Richard D. Noble
IPC分类号： B01D53/44 , B01D53/46 , B01D53/56 , B01D53/62 , C07C7/10 , C11D3/30
CPC分类号： B01D19/0005
摘要： The present invention provides compositions comprising ionic liquids and an amine compound, and methods for using and producing the same. In some embodiments, the compositions of the invention are useful in reducing the amount of impurities in a fluid medium or a solid substrate.
摘要翻译：本发明提供了包含离子液体和胺化合物的组合物及其制备方法。在一些实施方案中，本发明的组合物可用于减少流体介质或固体基质中杂质的量。

5. 发明授权

US07521003B2 Functionalized nanostructured lyotropic liquid crystal polymers 失效
标题翻译：官能化纳米结构溶致液晶聚合物
公开(公告)号：US07521003B2
公开(公告)日：2009-04-21
申请号：US10544322
申请日：2004-02-13
申请人： Douglas L. Gin , Weiqiang Gu , Yanjie Xu , Cory Pecinovsky
发明人： Douglas L. Gin , Weiqiang Gu , Yanjie Xu , Cory Pecinovsky
IPC分类号： C09K19/00 , C09K19/52 , G02F1/03
CPC分类号： C09K19/38 , B82Y30/00 , C09K2019/0418 , Y10T428/10 , Y10T428/1005 , Y10T428/1036
摘要： The invention provides cross-linked lyotropic liquid crystal (LLC) copolymers having ordered nanometer-sized pores lined with functional groups. The copolymers are formed by copolymerizing LLC monomers with strong LLC character and functionalized monomers with no or weak LLC character to form an LLC phase. Both the LLC monomers and the functionalized monomers contain hydrogen-bonding groups and hydrogen-bonding is believed to assist in the formation of the LLC phase of the blended mixture. Different classes of functional groups useful for the invention include, but are not limited to, acidic groups, basic groups, catalytic groups, oxidizing agents, reducing agents, polymerization initiators, binding agents, optically active groups, and electrically active groups. The invention also provides methods for making the cross-linked LLC copolymers of the invention. In these methods, the LLC monomer and the functionalized monomer are blended in a polar solvent, thereby allowing self-assembly of the first and second monomer into an LLC phase. The LLC phase in then cross-linked with retention of the LLC microstructure.
摘要翻译：本发明提供具有排列有官能团的有序纳米尺寸孔的交联溶致液晶（LLC）共聚物。共聚物通过将LLC单体与强LLC特性和不具有或弱的LLC特性的官能化单体共聚形成LLC相形成。 LLC单体和官能化单体都含有氢键基团，氢键被认为有助于共混混合物的LLC相的形成。可用于本发明的不同类别的官能团包括但不限于酸性基团，碱性基团，催化剂基团，氧化剂，还原剂，聚合引发剂，粘合剂，光学活性基团和电活性基团。本发明还提供了制备本发明交联的LLC共聚物的方法。在这些方法中，LLC单体和官能化单体在极性溶剂中共混，从而允许第一和第二单体自组装成LLC相。 LLC阶段随后保留LLC微结构交联。

6. 发明授权

US5128418A Polymerization of cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadiene and other substituted cyclohexadienes 失效
标题翻译：顺式-5,6-二（三甲基甲硅烷氧基）-1,3-环己二烯和其它取代的环己二烯的聚合
公开(公告)号：US5128418A
公开(公告)日：1992-07-07
申请号：US647576
申请日：1991-01-29
申请人： Robert H. Grubbs , Douglas L. Gin , Vincent P. Conticello , Philip D. Hampton , David R. Wheeler
发明人： Robert H. Grubbs , Douglas L. Gin , Vincent P. Conticello , Philip D. Hampton , David R. Wheeler
IPC分类号： C08F8/10 , C08F8/12 , C08G61/10
CPC分类号： C08F8/10 , C08F8/12 , C08G61/10
摘要： The monomer cis-5,6-bis(trimethylsiloxy)-1,3-cyclohexadiene can be polymerized with certain catalysts, such as bis(allyltrifluoroacetato nickel (II) and bis(allylpentafluorophenoxy nickel II). The resulting polymer is a precursor to poly(para-phenylene). Other substituted cyclohexadienes may also be polymerized by these catalysts to form useful polymers.
摘要翻译：单体顺式-5,6-双（三甲基甲硅烷氧基）-1,3-环己二烯可以与某些催化剂如双（烯丙基三氟乙酰基镍（II）和双（烯丙基五氟苯氧基镍II））聚合，得到的聚合物是聚（对亚苯基），其它取代的环己二烯也可以通过这些催化剂聚合形成有用的聚合物。

7. 发明申请

US20130228520A1 POLYMER COATINGS THAT RESIST ADSORPTION OF PROTEINS 审中-公开
标题翻译：耐高温蛋白吸附的聚合物涂层
公开(公告)号：US20130228520A1
公开(公告)日：2013-09-05
申请号：US13854769
申请日：2013-04-01
申请人： Douglas L. GIN , Evan S. Hatakeyama , Christopher J. Gabriel , Benny Dean Freeman , Hao Ju
发明人： Douglas L. GIN , Evan S. Hatakeyama , Christopher J. Gabriel , Benny Dean Freeman , Hao Ju
IPC分类号： C02F1/44
CPC分类号： C02F1/444 , B01D69/125 , B01D2325/14 , B01D2325/48 , C02F1/44 , C02F1/441
摘要： The invention provides membranes useful for filtration of water and other liquids. The membrane may be a composite membrane having a polymer layer incorporating quaternary phosphonium or ammonium groups. The polymer layer may be resistant to protein adsorption in an aqueous environment. The membrane may also be a surface-modified membrane in which a polymer having quaternary phosphonium or ammonium groups is covalently attached to the membrane surface. Methods for making and using the membranes of the invention are also provided.
摘要翻译：本发明提供了用于过滤水和其它液体的膜。膜可以是具有掺入季鏻或铵基的聚合物层的复合膜。聚合物层可以在水性环境中耐蛋白质吸附。膜也可以是其中具有季鏻或铵基团的聚合物共价连接到膜表面的表面改性膜。还提供了制造和使用本发明的膜的方法。

8. 发明申请

US20120129045A1 LIQUID ELECTROLYTE FILLED POLYMER ELECTROLYTE 审中-公开
标题翻译：液体电解质填充聚合物电解质
公开(公告)号：US20120129045A1
公开(公告)日：2012-05-24
申请号：US13237518
申请日：2011-09-20
申请人： Douglas L. GIN , Robert L. Kerr , Brian J. Elliott
发明人： Douglas L. GIN , Robert L. Kerr , Brian J. Elliott
IPC分类号： H01M10/02
CPC分类号： H01M10/0565 , H01B1/122 , H01M10/052 , H01M10/0566 , H01M2300/0082
摘要： A polymer-based electrolyte material for use in lithium ion batteries that exhibits high bulk ion conductivity at ambient and sub-ambient temperatures. The polymer electrolyte comprises a polymer matrix and a liquid electrolyte which is an organic solvent containing a free lithium salt. The polymer matrix is cross-linked and can be formed of cross-linkable ionic monomers, particularly ionic LLC surfactant monomers.
摘要翻译：一种用于锂离子电池的聚合物基电解质材料，其在环境温度和次环境温度下表现出较高的体积离子传导率。聚合物电解质包含聚合物基质和作为含有游离锂盐的有机溶剂的液体电解质。聚合物基质是交联的并且可以由可交联的离子单体形成，特别是离子型LLC表面活性剂单体。

9. 发明申请

US20120160095A1 Novel Nanoporous Supported Lyotropic Liquid Crystal Polymer Membranes and Methods of Preparing and Using Same 审中-公开
标题翻译：新型纳米支撑溶致液晶聚合物膜及其制备和使用方法
公开(公告)号：US20120160095A1
公开(公告)日：2012-06-28
申请号：US13303750
申请日：2011-11-23
申请人： Douglas L. Gin , Alan W. Weimer , Xinhua Liang
发明人： Douglas L. Gin , Alan W. Weimer , Xinhua Liang
IPC分类号： B01D71/06 , B01D71/02 , C23C16/44 , B01D53/22 , B01D67/00 , B01D61/14 , B01D69/02
CPC分类号： B01D53/22 , B01D67/0072 , B01D67/0079 , B01D67/0088 , B01D69/12 , B01D69/148 , B01D71/025 , B01D2256/16 , B01D2256/245 , B01D2323/30 , C23C16/045 , C23C16/403 , C23C16/45555
摘要： The invention includes a nanoporous LLC polymer membrane wherein ultra-thin films or clusters of inorganic material are deposited inside the porous structure of the LLC polymer membrane. The membranes of the invention have high levels of pore size uniformity, allowing for size discrimination separation, and may be used for separation processes such as gas-phase and liquid-phase separations.
摘要翻译：本发明包括纳米多孔LLC聚合物膜，其中超薄膜或无机材料簇沉积在LLC聚合物膜的多孔结构内。本发明的膜具有高水平的孔径均匀性，允许尺寸辨别分离，并且可用于气相和液相分离等分离过程。

10. 发明申请

US20080319202A1 FLUID STORAGE AND DISPENSING METHODS AND APPARATUS 审中-公开
标题翻译：流体储存和分配方法和装置
公开(公告)号：US20080319202A1
公开(公告)日：2008-12-25
申请号：US12041574
申请日：2008-03-03
申请人： Douglas L. Gin , Jason E. Bara , Richard D. Noble
发明人： Douglas L. Gin , Jason E. Bara , Richard D. Noble
IPC分类号： C07D233/54 , C07D403/02
CPC分类号： F17C11/00 , C01B7/01 , C01B7/20 , C01B13/0281 , C07D403/06 , C07D403/12 , F17C11/005 , Y10T137/0318
摘要： A method and device for storing and dispensing a fluid includes providing a vessel configured for selective dispensing of the fluid therefrom. Provided within a vessel is a nanocomposite material comprising an imidazolium surfactant and an integral solvent that is essential to the formation of the nanocomposite material. The fluid is contacted with the nanocomposite material for take-up of the fluid by the polymerized nanocomposite material. The fluid is released from the nanocomposite material and dispensed from the vessel.
摘要翻译：用于存储和分配流体的方法和装置包括提供构造用于从其中选择性地分配流体的容器。提供在容器内的是纳米复合材料，其包含咪唑鎓表面活性剂和对形成纳米复合材料至关重要的整体溶剂。流体与纳米复合材料接触，用于通过聚合的纳米复合材料吸收流体。流体从纳米复合材料释放并从容器中分配。

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