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    • 4. 发明授权
    • Bis-propargyl thermosets
    • 双炔丙基热固性塑料
    • US5475133A
    • 1995-12-12
    • US346108
    • 1994-11-28
    • Elliot P. DouglasDavid A. LangloisBrian C. Benicewicz
    • Elliot P. DouglasDavid A. LangloisBrian C. Benicewicz
    • C07C69/773C07C69/92C08F38/00C07C69/76
    • C07C69/92C08F38/00
    • The present invention provides (1) curable bispropargyl-containing monomers represented by the formula: B.sup.1 --A.sup.1.sub.m --R--A.sup.2.sub.n --B.sup.2 wherein R is a radical selected from the group consisting of 1,4-phenylene, 4,4'-biphenyl, 2,6-naphthalene, --C.sub.6 H.sub.4 --CR.sup.2 .dbd.CR.sup.2 --C.sub.6 H.sub.4 -- wherein R.sup.2 is H or CH.sub.3, and the same where said groups contain one or more substituents selected from the group consisting of halo, nitro, lower alkyl, lower alkoxy, fluoroalkyl or fluoroalkoxy, A.sup.1 and A.sup.2 are selected from the group consisting of --C.sub.6 H.sub.4 --C(O)--O-- and --C.sub.6 H.sub.4 --O--C(O)--, m and n are 0 or 1, m+n is 0, 1 or 2, and B.sup.1 and B.sup.2 are --OCH.sub.2 --C.tbd.C--H, (2) thermoset compositions comprised of cured segments derived from monomers represented by the formula: B.sup.1 --A.sup.1.sub.m --R--A.sup.2.sub.n --B.sup.2 as described above, and (3) curable blends of at least two of the monomers.
    • 本发明提供(1)由式B1-A1m-R-A2n-B2表示的可固化双炔丙基单体,其中R是选自1,4-亚苯基,4,4'-联苯, 2,6-萘,-C6H4-CR2 = CR2-C6H4-,其中R2是H或CH3,并且相同,其中所述基团含有一个或多个选自卤素,硝基,低级烷基,低级烷氧基,氟代烷基 或氟烷氧基,A1和A2选自-C6H4-C(O)-O-和-C6H4-OC(O) - ,m和n为0或1,m + n为0,1或2 ,和B1和B2是-OCH2-C3BCH,(2)由如上所述由式B1-A1m-R-A2n-B2表示的单体衍生的固化链段组成的热固性组合物,和(3)可固化共混物 至少两种单体。
    • 5. 发明授权
    • Polyamide thermosets
    • 聚酰胺热固性材料
    • US5198551A
    • 1993-03-30
    • US711721
    • 1991-06-07
    • Brian C. BenicewiczAndrea E. Hoyt
    • Brian C. BenicewiczAndrea E. Hoyt
    • C07D207/44C07D207/452C07D209/76C08G73/14
    • C07D207/452C07D209/76C08G73/14
    • The present invention provides (1) curable polyamide monomers represented by the formula: R.sup.1 -A.sup.1 -B.sup.1 -A.sup.2 -B.sup.2 -A.sup.3 -R.sup.2 where R.sup.1 and R.sup.2 are radicals selected from the group consisting of maleimide, substituted maleimide, nadimide, substituted nadimide, ethynyl, and (C(R.sup.3).sub.2).sub.2 where R.sup.3 is hydrogen with the proviso that the two carbon atoms of (C(R.sup.3).sub.2).sub.2 are bound on the aromatic ring of A.sup.1 or A.sup.3 to adjacent carbon atoms, A.sup.1 and A.sup.3 are 1,4-phenylene and the same where said group contains one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro, lower alkyl, e.g., methyl, ethyl, and propyl, lower alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl or fluoroalkoxy, e.g., trifluoromethyl, pentafluoroethyl and the like, A.sup.2 is selected from the group consisting of 1,4-phenylene, 4,4'-biphenyl, 2,6-naphthylene and the same where said groups contain one or more substitutents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro, lower alkyl, e.g., methyl, ethyl, and propyl, lower alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl or fluoroalkoxy, e.g., trifluoromethyl, pentafluoroethyl and the like, and B.sup.1 and B.sup.2 are selected from the group consisting of --C(O)--N(H)-- and --N(H)--C(O)--, (2) thermoset polyamide compositions comprised of cured segments derived from monomers represented by the formula: R.sup.1 -A.sup.1 -B.sup.1 -A.sup.2 -B.sup.2 -A.sup.3 -R.sup.2 as described above, and curable blends of at least two of the polyamide monomers and (4) processes of preparing the curable polyamide monomers.
    • 本发明提供(1)由式:R1-A1-B1-A2-B2-A3-R2表示的可固化的聚酰胺单体,其中R 1和R 2是选自马来酰亚胺,取代的马来酰亚胺,酰亚胺,取代的酰亚胺, 乙炔基和(C(R3)2)2,其中R3是氢,条件是(C(R3)2)2的两个碳原子在A1或A3的芳环上键合成相邻的碳原子,A1和A3 是1,4-亚苯基,并且相同,其中所述基团含有一个或多个选自卤素,例如氟,氯,溴或碘,硝基,低级烷基,例如甲基,乙基和丙基的取代基, 低级烷氧基,例如甲氧基,乙氧基或丙氧基,以及氟代烷基或氟代烷氧基,例如三氟甲基,五氟乙基等,A2选自1,4-亚苯基,4,4'-联苯基,2,6 - 亚乙基,并且相同,其中所述基团含有一个或多个选自卤素,例如氟,氯,溴的取代基 低级烷基,例如甲基,乙基和丙基,低级烷氧基,例如甲氧基,乙氧基或丙氧基,氟代烷基或氟代烷氧基,例如三氟甲基,五氟乙基等,而B1和B2是 选自-C(O)-N(H) - 和-N(H)-C(O) - ,(2)热固性聚酰胺组合物,其包含衍生自由式R1- 如上所述的A1-B1-A2-B2-A3-R2,以及至少两种聚酰胺单体的可固化共混物和(4)制备可固化聚酰胺单体的方法。
    • 8. 发明授权
    • Liquid crystal polyester thermosets
    • 液晶聚酯热固性材料
    • US5114612A
    • 1992-05-19
    • US644856
    • 1991-01-22
    • Brian C. BenicewiczAndrea E. Hoyt
    • Brian C. BenicewiczAndrea E. Hoyt
    • C08G63/52C08G63/682C08G63/685C09K19/38
    • C08G63/6858C08G63/52C08G63/6828C09K19/3804C09K19/3823
    • The present invention provides (1) curable liquid crystalline polyester monomers represented by the formula:R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2where R.sup.1 and R.sup.2 are radicals selected from the group consisting of maleimide, substituted maleimide, nadimide, substituted naimide, ethynyl, and (C(R.sup.3).sub.2).sub.2 where R.sup.3 is hydrogen with the proviso that the two carbon atoms of (C(R.sup.3).sub.2).sub.2 are bound on the aromatic ring of A.sup.1 or A.sup.3 to adjacent carbon atoms, A.sup.1 and A.sup.3 are 1,4-phenylene and the same where said group contains one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro lower alkyl, e.g., methyl, ethyl, or propyl, alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl, e.g., trifluoromethyl, pentafluoroethyl and the like, A.sup.2 is selected from the group consisting of 1,4-phenylene, 4,4'-biphenyl, 2,6-naphthylene and the same where said groups contain one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro, lower alkyl, e.g., methyl, ethyl, and propyl, lower alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl or fluoroalkoxy, e.g., trifluoromethyl, pentafluoroethyl and the like, and B.sup.1 and B.sup.2 are selected from the group consisting of --C(O)--O-- and --O--C(O)--, (2) thermoset liquid crystalline polyester compositions comprised of heat-cured segments derived from monomers represented by the formula:R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2as described above, (3) curable blends of at least two of the polyester monomers and (4) processes of preparing the curable liquid crystalline polyester monomers.
    • 本发明提供(1)由式:R1-A1-B1-A2-B2-A3-R2表示的可固化液晶聚酯单体,其中R 1和R 2是选自马来酰亚胺,取代的马来酰亚胺, (C(R3)2)2的两个碳原子在A1或A3的芳香环上键合到相邻的碳原子上,A1(A1) 和A3是1,4-亚苯基,并且相同,其中所述基团含有一个或多个选自卤素,例如氟,氯,溴或碘,硝基低级烷基,例如甲基,乙基或丙基的取代基 ,烷氧基,例如甲氧基,乙氧基或丙氧基,以及氟代烷基,例如三氟甲基,五氟乙基等,A2选自1,4-亚苯基,4,4'-联苯基,2,6-亚萘基 并且相同,其中所述基团含有一个或多个选自卤素,例如氟,氯,溴或 碘,硝基,低级烷基,例如甲基,乙基和丙基,低级烷氧基,例如甲氧基,乙氧基或丙氧基,氟代烷基或氟代烷氧基,例如三氟甲基,五氟乙基等,而B1和B2选自 由-C(O)-O-和-OC(O) - 组成的组,(2)热固性液晶聚酯组合物,其由衍生自由下式表示的单体的热固化链段组成:R1-A1-B1-A2-B2 -A 3-R 2,(3)至少两种聚酯单体的可固化共混物和(4)制备可固化液晶聚酯单体的方法。