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    • 5. 发明授权
    • Production of emulsion-polymerized butadiene rubber in powder form
    • 生产粉末形式的乳液聚合丁二烯橡胶
    • US4383108A
    • 1983-05-10
    • US288226
    • 1981-07-29
    • August H. Jorgensen, Jr.
    • August H. Jorgensen, Jr.
    • C08F2/00C08C1/00C08C1/15C08F2/22C08J3/16
    • C08C1/15
    • There is disclosed a simple economical method of producing butadiene rubber, particularly NBR, in dry powder form free of extraneous material influencing its utility in rubber products manufacture. The method consists of preparing the butadiene rubber in latex form in the usual manner but using sodium lauryl sulfate or equivalent as emulsifier and then coagulating the latex with a combination of magnesium sulfate and aluminum sulfate, or their equivalents, in a molar ratio of Mg to Al in the range of 0.3 to 1 to 2 to 1. The coagulum wet cake obtained contains powder size particles of the rubber and is dried to give a dry free-flowing rubber powder, preferably after addition of zinc stearate or equivalent which functions as an anticake agent and prevents agglomeration of the powder size particles during drying. The zinc stearate can be added to the wet cake as dry powder or as a wet paste or produced in situ.
    • 公开了一种生产丁二烯橡胶,特别是NBR的简单经济方法,其干粉形式不含外来材料,影响其在橡胶制品制造中的应用。 该方法包括以常规方式制备胶乳形式的丁二烯橡胶,但使用十二烷基硫酸钠或等同物作为乳化剂,然后用硫酸镁和硫酸铝的组合或其等同物以与Mg的摩尔比 Al为0.3〜1〜2比例。所得到的凝块湿饼含有粉末粒径的橡胶,干燥后得到干燥的自由流动的橡胶粉,优选在加入硬脂酸锌或其等同物之后 防粉剂,防止粉末粒子在干燥时的团聚。 硬脂酸锌可以作为干粉或湿糊剂加入到湿滤饼中或原地制备。