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    • 2. 发明授权
    • Wear-resistant spark plug electrode tip containing platinum alloys,
spark plug containing the wear-resistant tip, and method of making same
    • 含有铂合金的耐磨火花塞电极头,含有耐磨头的火花塞及其制造方法
    • US6071163A
    • 2000-06-06
    • US264268
    • 1999-03-08
    • Chin-Fong ChangRichard Dale TaylorLee Randall FranzEdgar Arnold LeoneAlex Kozlov
    • Chin-Fong ChangRichard Dale TaylorLee Randall FranzEdgar Arnold LeoneAlex Kozlov
    • C22F1/14C22C5/04C22F1/00H01T13/39H01T21/02H01T13/20
    • H01T21/02H01T13/39
    • A wear-resistant electrode tip for a spark plug, and a spark plug which incorporates the wear-resistant tip. The wear-resistant tip includes an alloy of platinum, iridium, and tungsten. Surprisingly, by addition of a small amount of tungsten to platinum-iridium alloy, the wear-resistance of a resultant spark plug is greatly improved. The spark plug electrode tip according to the invention is either spherical or rivet-shaped. During manufacture, the spark plug electrode tip is annealed in an annealing furnace. The annealing furnace is preferably either charged with an inert gas such as argon or nitrogen, or is subjected to a vacuum. The electrode tip is, optionally, further externally coated with platinum or a compatible bonding metal alloy before attachment to the electrode. Subsequent to annealing and, where used, to external coating, the spark plug electrode tip is placed in a welding fixture. The tip is then aligned with a spark plug electrode and is resistance welded thereto. Similar procedures are preferably performed on both the center and side electrodes of the spark plug. The annealed spark plug electrode tips using the novel alloys according to the invention have a high resistance to attack by lead and other corrosive elements typically present in the combustion chambers of internal combustion engines. A preferred method of making a wear-resistant spark plug is also disclosed.
    • 用于火花塞的耐磨电极端头和包含耐磨端头的火花塞。 耐磨头包括铂,铱和钨的合金。 令人惊奇的是,通过向铂 - 铱合金中添加少量钨,可以大大提高所得到的火花塞的耐磨性。 根据本发明的火花塞电极头是球形或铆钉形的。 在制造过程中,火花塞电极头在退火炉中退火。 退火炉优选用惰性气体例如氩气或氮气填充,或者进行真空。 在连接到电极之前,可选地,电极末端进一步外部涂有铂或相容的粘结金属合金。 在退火之后,如果使用外部涂层,将火花塞电极头放置在焊接夹具中。 然后将尖端与火花塞电极对准并且与其电阻焊接。 类似的方法优选在火花塞的中心和侧面电极上进行。 使用根据本发明的新型合金的退火火花塞电极端头具有高的耐受铅和通常存在于内燃机的燃烧室中的其它腐蚀性元件的侵蚀。 还公开了制造耐磨火花塞的优选方法。
    • 3. 发明授权
    • Method of improving the oxidation resistance of a platinum modified aluminide diffusion coating
    • 提高铂改性铝化物扩散涂层的抗氧化性的方法
    • US06521113B2
    • 2003-02-18
    • US09895761
    • 2001-06-29
    • Thomas E. StrangmanDerek RaybouldAlex Kozlov
    • Thomas E. StrangmanDerek RaybouldAlex Kozlov
    • C23C2800
    • C25D3/50
    • An electrolyte for use in electrolytic platinum plating that results in reduced Cl, S, or P contaminant production. The bath comprises 0.01 to 320 g/lit of platinum in the form of the platinum salt dinitrodiammine platinum, Pt(NH3)2(NO2)2 or variants thereof and 0.1 to 240 g/lit of alkali metal carbonate M2CO3 or bicarbonate MHCO3 where M is selected from a group comprising lithium (Li), sodium (Na), potassium (K), rubidium (Rb) and cesium (Cs). A method of improving oxidation resistance of a platinum modified aluminide diffusion coating on a substrate, comprises electroplating the substrate using this electrolyte and then aluminizing the electroplated substrate at an elevated temperature to grow a platinum modified aluminide diffusion coating.
    • 用于电解铂电镀中的电解质,其导致Cl,S或P污染物产生减少。 该浴包含0.01至320g / l铂的铂盐二硝基二胺铂,Pt(NH 3)2(NO 2)2或其变体形式的铂和0.1至240g / l的碱金属碳酸盐M2CO3或碳酸氢盐MHCO3,其中M 选自锂(Li),钠(Na),钾(K),铷(Rb)和铯(Cs)组成的组。 提高基底上铂改性铝化物扩散涂层的抗氧化性的方法包括使用该电解质对基底进行电镀,然后在升高的温度下对电镀基底进行镀铝以生长铂改性的铝化物扩散涂层。