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    • 1. 发明申请
    • POLYCONDENSATION CATALYST FOR PRODUCING POYESTER AND METHOD FOR PRODUCING THE SAME AND METHOD FOR PRODUCING POLYESTER
    • 用于生产聚合物的聚合催化剂及其制备方法和用于生产聚酯的方法
    • US20100152413A1
    • 2010-06-17
    • US12733250
    • 2008-08-14
    • Hiromitsu ShimizuKeiichi TabataAkihiro Kamon
    • Hiromitsu ShimizuKeiichi TabataAkihiro Kamon
    • C08G63/82B01J21/06B01J21/08B01J21/04
    • C08G63/85B01J21/063B01J21/066B01J23/007B01J37/0221B01J37/0244B01J37/035
    • The invention provides a method for producing a catalyst for producing polyester by an esterification reaction or a transesterification reaction between a dicarboxylic acid or an ester-forming derivative thereof and a glycol, the method comprising hydrolyzing an organic titanium compound in an organic solvent in which particles of a solid base are dispersed thereby to form a coat layer of titanic acid on the surface of the particles of solid base.According to the invention, the method preferably comprises hydrolyzing an organic silicon compound and/or an organic aluminum compound and/or an organic zirconium compound in an organic solvent in which particles of a solid base are dispersed thereby to form an inner coat layer either of an oxide of at least one element selected from silicon, aluminum and zirconium or of a composite oxide of at least two elements selected from silicon, aluminum and zirconium, and then hydrolyzing an organic titanium compound in the organic solvent in which the particles of a solid base having the inner coat layer thereon are dispersed thereby to form an outer coat layer of titanic acid on the inner coat layer of the particles of a solid base.
    • 本发明提供了通过二羧酸或其成酯衍生物与二醇之间的酯化反应或酯交换反应制备聚酯的催化剂的方法,该方法包括在有机溶剂中水解有机钛化合物,其中颗粒 的固体碱分散,从而在固体基质颗粒的表面上形成钛酸涂层。 根据本发明,该方法优选包括在有机溶剂中水解有机硅化合物和/或有机铝化合物和/或有机锆化合物,其中固体碱的颗粒被分散,从而形成内涂层 选自硅,铝和锆中的至少一种元素的氧化物或选自硅,铝和锆的至少两种元素的复合氧化物,然后水解有机溶剂中的有机钛化合物,其中固体颗粒 在其上具有内涂层的基底分散,从而在固体基体颗粒的内涂层上形成钛酸外涂层。