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    • 4. 发明授权
    • Purification of wet process phosphoric acid
    • 湿法磷酸的纯化
    • US4349519A
    • 1982-09-14
    • US214671
    • 1980-12-09
    • Yoichi HiragaOsamu WatanabeMasaki Nakatani
    • Yoichi HiragaOsamu WatanabeMasaki Nakatani
    • C01B25/234C01B25/46C01B25/16
    • C01B25/462
    • A wet process phosphoric acid obtained by an solvent extraction method with n-butanol and/or isobutanol comprises(a) feeding a wet process phosphoric acid having a concentration of P.sub.2 O.sub.5 of higher than 35 wt. % into an extraction battery;(b) adding sulfuric acid into a stage in fifth or higher stage from the step of discharging an extracted solution and in second or higher stage from the step of discharging raffinate in the extraction battery at a gram equivalent ratio given by subtracting the amount of sulfuric acid in the wet process phosphoric acid fed into the extraction battery from 1.2 to 2.0 times of the sum of total cation impurities in the wet process phosphoric acid fed into the extraction battery and total components of sodium, potassium and magnesium added to the purification battery;(c) discharging said extracted solution having a concentration of H.sub.3 PO.sub.4 of 130 to 180 g./liter from said extraction battery;(d) adding at least one of the compounds of sodium, potassium and magnesium in second or higher stage from the step of discharging the solvent phase and in second or higher stage from the step of discharging the aqueous phase in the purification battery to give more than 0.4 equivalent per liter of the concentration of sodium, potassium and magnesium in the aqueous phase in the stage where at least one of alkali metal and magnesium compounds is added in the same battery.
    • 通过用正丁醇和/或异丁醇的溶剂萃取方法获得的湿法磷酸包括(a)加入浓度为P 2 O 5的湿法磷酸高于35wt。 %进入提取电池; (b)从排出萃取溶液的步骤的第五阶段或更高阶段的阶段加入硫酸,并且在从萃取电池中排出萃余液的步骤的第二阶段或更高阶段,以克当量比减去硫酸的量 酸在湿法磷酸中加入萃取电池中的1.2倍到2.0倍的总阳离子杂质在湿法中加入磷酸进料到萃取电池中,并将总成分中的钠,钾和镁添加到净化电池中; (c)从所述提取电池中排出浓度为H 3 PO 4的所述提取溶液为130至180克/升; (d)从排出溶剂相的步骤的第二阶段或更高阶段加入至少一种钠,钾和镁的化合物,并且在从净化电池中排出水相的步骤的第二或更高阶段中加入更多 在相同的电池中添加碱金属和镁化合物中的至少一种的阶段中,每升浓度的钠,钾和镁的浓度超过0.4当量。
    • 5. 发明授权
    • Process for producing powdery rubber
    • 生产粉状橡胶的方法
    • US4194999A
    • 1980-03-25
    • US849467
    • 1977-11-07
    • Takao HayashiYasuhiro SakanakaAkihiko Shimizu
    • Takao HayashiYasuhiro SakanakaAkihiko Shimizu
    • C08C1/00B29B9/00B29B15/00B29B15/02C08C1/14C08J3/12C08J3/16C08L1/28
    • C08J3/16C08C1/14C08J2321/00Y10S528/936
    • A powdery rubber is produced by mixing an anionic or nonionic rubber latex with an aqueous solution of an anionic water soluble macro-molecular compound which is dissociated in water to give negative charge; adjusting the pH to an acidic condition; adding to the aqueous solution either a cationic polymer which is water soluble in an acidic condition or a cationic surfactant which causes a coacervation with the anionic water soluble macromolecular compound in an acidic condition to separate the rubber particles from the rubber latex under coacervation and adding an emulsion of a synthetic resin having a glass transition temperature higher than 30.degree. C. to the rubber particles at a ratio of 1 to 50 wt.% (as a solid content) to the solid content of the rubber latex and dehydrating and drying the resulting powdery rubber.
    • 通过将阴离子或非离子橡胶胶乳与在水中分解的阴离子水溶性大分子化合物的水溶液混合而产生负电荷来生产粉状橡胶; 将pH调节至酸性条件; 向水溶液中加入在酸性条件下是水溶性的阳离子聚合物或阳离子表面活性剂,其在酸性条件下与阴离子水溶性大分子化合物凝聚,以在凝聚下将橡胶颗粒与橡胶胶乳分离,并加入 玻璃化转变温度高于30℃的合成树脂的乳液与橡胶颗粒的比例为1至50重量%(作为固体含量)与橡胶胶乳的固体含量的比例,并将所得 粉状橡胶