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    • 5. 发明授权
    • Process for separately recovering zinc and lead values from zinc and
lead containing sulphidic ore
    • 从锌和含铅硫化矿石中分别回收锌和铅的过程
    • US4545963A
    • 1985-10-08
    • US536013
    • 1983-09-26
    • Donald R. WeirIan M. MastersBarry N. DoyleMichael E. Chalkley
    • Donald R. WeirIan M. MastersBarry N. DoyleMichael E. Chalkley
    • C22B13/00B03D1/02B03D1/06C22B19/00C22B19/20C01G3/00C01G9/00C01G21/00
    • C22B19/22B03D1/02B03D1/06C22B13/04Y02P10/234
    • A process for separately recovering zinc and lead values from zinc and lead containing sulphidic ore which also contains iron comprises subjecting ground ore to a first flotation step to float an initial lead concentrate containing zinc and produce zinc and iron containing tailings. The zinc and iron containing tailings are subjected to a second flotation step to float an initial zinc concentrate containing iron and also produce tailings. The initial zinc concentrate is subjected to a third flotation step to float a further zinc concentrate containing iron and also produce zinc and iron containing tailings. The zinc and iron containing tailings from the third flotation step and at least a lead and zinc containing portion of the initial lead concentrate are leached in a first leach step under oxidizing conditions at a temperature in the range of from about 130.degree. to about 170.degree. C. in aqueous sulphuric acid solution with a stoichiometric excess of sulphuric acid relative to the zinc content of from about 50 to about 150% so as to give a terminal acidity of from about 50 to about 80 g/L to produce a lead-containing residue and a first leach solution containing zinc and iron. The lead containing residue is separated from the first leach solution and the first leach solution is treated with the further zinc concentrate or calcine produced therefrom by roasting to dissolve zinc therefrom and precipitate a substantial amount of dissolved iron, thereby producing an iron containing residue and a second leach solution containing zinc. The iron containing residue is separated from the second leach solution, and the second leach solution is treated to recover zinc.
    • 还含有铁和含锌硫化矿石的锌和铅值分别回收还含有铁的方法包括对地矿进行第一浮选步骤以漂浮含有锌的初始含铅浓缩物并产生含锌和铁的尾矿。 对含锌和铁的尾矿进行第二浮选步骤以漂浮含有铁的初始锌精矿并且还产生尾矿。 初始锌精矿经受第三浮选步骤以漂浮含有铁的另外的锌精矿,并且还产生含锌和铁的尾矿。 在氧化条件下,在约130℃至约170℃的温度范围内,将第一浮选步骤中含锌和铁的尾矿以及至少含铅和锌的部分初始浓缩铅浸出, 在相对于锌含量为约50至约150%的化学计量过量硫酸的硫酸水溶液中,以产生约50至约80g / L的终端酸度以产生含铅的 残渣和含锌和铁的第一浸出溶液。 含铅残渣与第一浸出溶液分离,第一浸出溶液用另外的浓缩锌或煅烧物通过焙烧处理,从而溶解锌,并沉淀出大量的溶解铁,从而产生含铁残渣和 含锌的第二浸出溶液。 将含铁残渣与第二浸出溶液分离,并处理第二浸出溶液以回收锌。
    • 9. 发明授权
    • Hydrometallurgical process for the production of cobalt powder from
mixed metal sulphides
    • 用于从混合金属硫化物生产钴粉末的湿法冶金工艺
    • US4108640A
    • 1978-08-22
    • US713325
    • 1976-08-11
    • Herbert F. WallaceDonald R. Weir
    • Herbert F. WallaceDonald R. Weir
    • C22B19/00C22B3/00C22B3/26C22B3/30C22B19/20C22B23/00C22B23/04
    • C22B3/0017Y02P10/234
    • A process for recovering metallic cobalt from an aqueous ammoniacal solution containing dissolved cobalt and other metals as ammine sulphates with substantially all the dissolved cobalt being in cobaltic form. The process includes contacting the solution with a water immiscible liquid ion exchange reagent dissolved in an inert organic diluent to selectively substantially completely extract the other metals from the solution and produce an organic extractant loaded with the other metals and an aqueous cobalt bearing raffinate substantially free of the other metals. The cobalt bearing raffinate is separated from the loaded organic extractant and the loaded organic extractant is washed to remove substantially all ammonia therefrom. The other metals are stripped from the washed organic extractant which is then recycled to treat further solution. Cobalt is recovered from the raffinate.
    • 从含有溶解的钴和其它金属的氨水溶液中回收金属钴的方法,其中硫酸铵为基本上全部溶解的钴为钴酸形式。 该方法包括使溶液与溶解在惰性有机稀释剂中的与水不混溶的液体离子交换剂接触,以从溶液中选择性地基本上完全提取其它金属,并产生负载其它金属的有机萃取剂和基本上不含 其他金属。 从负载的有机萃取剂中分离含钴萃余液,并将负载的有机萃取剂洗涤以从其中除去基本上所有的氨。 从洗涤的有机萃取剂中除去其它金属,然后将其再循环以处理进一步的溶液。 钴从残液中回收。
    • 10. 发明授权
    • Hydrometallurgical process for recovering copper and other metal values
from metal sulphides
    • 用于从金属硫化物中回收铜和其他金属值的湿法冶金工艺
    • US4097271A
    • 1978-06-27
    • US741280
    • 1976-11-12
    • Godefridus M. SwinkelsEdward F. G. MilnerRoman Michael Genik-Sas-Berezowsky
    • Godefridus M. SwinkelsEdward F. G. MilnerRoman Michael Genik-Sas-Berezowsky
    • C22B3/10C22B15/00C22B15/08C22B11/04
    • C22B3/10C22B11/04C22B15/0069C22B15/0089C22B15/0093Y02P10/234Y02P10/236
    • A hydrometallurgical process for the separate recovery of non-ferrous, ferrous, and precious metal values and sulfur from metal sulfide ore concentrates by leaching of metal sulfides with a lixiviant containing ferric chloride, cupric chloride and chlorine, precipitating cuprous chloride from the leach solution with butadiene, separating and decomposing the formed addition compound to recover the cuprous chloride, oxidizing and hydrolyzing the cuprous chloride to precipitate cupric oxychloride, converting the cupric oxychloride to cupric oxide, and reducing the cupric oxide with hydrogen for the recovery of copper. The leach residue is treated for the recovery of elemental sulfur and gold. Brine solution resulting from the conversion of cupric oxychloride to cupric oxide is electrolyzed for the production of sodium hydroxide for the cupric oxychloride conversion, hydrogen for the cupric oxide reduction and chlorine, which is partly used in the recovery of gold and partly recycled to the concentrate leach. Silver is recovered as silver iodide from the mother liquor from the cuprous chloride precipitation with butadiene. A portion of the solution from the silver recovery is treated for recovery of Cu, Zn, Co and Ni, and the remaining portion and residual solution from Cu, Zn, Co and Ni recovery are treated with oxygen at elevated temperature and pressure for the regeneration of ferric chloride and precipitation of excess iron as anhydrous ferric oxide.
    • 一种用于通过用含有氯化铁,氯化铜和氯的氯化锂浸出金属硫化物从金属硫化物矿精矿中分离回收有色金属,亚铁和贵金属值和硫的湿法冶金工艺,从浸出溶液中沉淀出氯化亚铜, 丁二烯,分离和分解形成的加成化合物以回收氯化亚铜,氧化和水解氯化亚铜以沉淀二氯氧化氯,将氯氧化铜转化为氧化铜,并用氢还原氧化铜以回收铜。 处理浸出残渣以回收元素硫和金。 电化铜盐溶液产生的氯氧化铜氧化铜产生氢氧化钠用于二氧化氯氧化物转化,氢气用于氧化铜还原和氯,部分用于金的回收和部分回收到浓缩物 浸出 从碘化亚铜离子沉淀的母液中用丁二烯回收银。 处理一部分来自银回收率的溶液以回收Cu,Zn,Co和Ni,并且将Cu,Zn,Co和Ni回收的剩余部分和残余溶液用氧气在升高的温度和压力下进行再生处理 的氯化铁和作为无水三氧化铁的过量铁的沉淀。