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    • 4. 发明授权
    • Process for extraction of rare earth elements
    • 稀土元素提取工艺
    • US09115419B2
    • 2015-08-25
    • US13858166
    • 2013-04-08
    • Process Research Ortech Inc.
    • Vaikuntam I. LakshmananRamamritham SridharM. A. Halim
    • C22B59/00C22B3/08C22B3/10
    • C22B59/00C22B3/08C22B3/10Y02P10/234
    • A process for the extraction of rare earth elements, including yttrium, from a rare earth element-bearing ore or concentrate, comprising the steps of leaching the rare earth element-bearing ore or concentrate with a lixiviant of hydrochloric acid and magnesium chloride at atmospheric pressure at a temperature of from 90° C. to the boiling point of the solution and at an Eh of at least 200 mV. After a liquid/solids separation step, the solution obtained is subjected to steps for removal of iron and for recovery of rare earth elements. Alternatively, rare earth element-bearing ore or concentrate may be leached with sulphuric acid and liquid obtained subjected to extraction of iron and other impurities. Raffinate obtained may be treated with oxalic acid, the precipitate dissolved in hydrochloric acid and subjected to solvent extraction for rare earth elements or the raffinate may be subjected to solvent extraction for removal of rare earth elements and then stripped with hydrochloric acid.
    • 一种从含有稀土元素的矿石或浓缩物中提取稀土元素(包括钇)的方法,包括以下步骤:在大气压力下将含稀土元素的矿石或浓缩物与盐酸和氯化镁的浸液浸出 在90℃至该溶液的沸点和至少200mV的Eh下进行。 在液/固分离步骤之后,将所得溶液进行除铁和用于回收稀土元素的步骤。 或者,稀土元素矿石或浓缩物可以用硫酸浸出,所得液体经铁提取和其他杂质。 得到的残液可用草酸处理,沉淀溶解于盐酸中,进行稀土元素的溶剂萃取,或萃取液进行溶剂萃取除去稀土元素,然后用盐酸汽提。