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    • 4. 发明授权
    • Process for producing highly pure terephthalic acid
    • 高纯度对苯二甲酸生产方法
    • US5684187A
    • 1997-11-04
    • US639966
    • 1996-04-29
    • Fumio OhkoshiMasato InaryFumiya Zaima
    • Fumio OhkoshiMasato InaryFumiya Zaima
    • C07C51/487C07C51/43C07C63/26C07C51/42
    • C07C51/43
    • There is disclosed a process for producing highly pure terephthalic acid by converting a slurry of terephthalic acid crystals in acetic acid solvent which crystals are obtained by liquid-phase oxidation of p-alkylbenzene, into a slurry thereof in water solvent by mother liquor replacement and then subjecting the latter slurry to a catalytic hydrogenation treatment which process comprises the steps of introducing the slurry of terephthalic acid crystals in acetic acid into a mother liquor replacement column at the top portion; forming an accumulation layer of the terephthalic acid crystals at the bottom portion by the sedimentation of the crystals; feeding replacing water sufficient for the formation of upward rising stream of water to the inside of the column at the bottom portion; and withdrawing the accumulation layer of the crystals from the bottom portion of the column. The accumulation layer is kept at a slightly fluidized stable state and is smoothly withdrawn from the bottom of the column by slowly rotating an arm-type agitation blade placed in the layer or by feeding the replacing water dividedly into two trains.
    • 公开了通过将通过液相氧化对烷基苯获得的结晶的乙酸溶剂中的对苯二甲酸晶体的浆料转化成其在水溶剂中的浆液,通过母液置换,生产高纯对苯二甲酸的方法,然后 对后一种浆料进行催化加氢处理,该方法包括以下步骤:将对苯二甲酸晶体的淤浆在乙酸中引入到顶部的母液置换塔中; 通过晶体的沉淀在底部形成对苯二甲酸晶体的堆积层; 将足够的水替换为在塔底部向上升起的水流形成塔的内部; 并从柱的底部排出晶体的积聚层。 蓄积层保持在稍微流化的稳定状态,并且通过缓慢旋转放置在该层中的臂式搅拌叶片或通过将替代水分成两部分进料来平缓地从塔的底部排出。
    • 5. 发明授权
    • Process for producing 3-methyltetrahydrofuran
    • 3-甲基四氢呋喃的制备方法
    • US5618953A
    • 1997-04-08
    • US595271
    • 1996-02-01
    • Takafumi AbeFumio TanakaHiroyuki NitobeMasaki Takemoto
    • Takafumi AbeFumio TanakaHiroyuki NitobeMasaki Takemoto
    • C07D307/06C07D307/02
    • C07D307/06
    • A process for producing 3-methyltetrahydrofuran, wherein in a first step, prussic acid is reacted with methyl methacrylate to produce methyl 3-cyanoisobutyrate. The methyl 3-cyanoisobutyrate is then reacted with water and sulfuric acid to produce a resultant product which is reacted with a C.sub.1 -C.sub.8 aliphatic alcohol to produce a methylsuccinic acid ester. The methylsuccinic acid ester is catalytically hydrogenated to prepare the 3-methyltetrahydrofuran. Alternatively, the methyl 3-cyanoisobutyrate is hydrated to produce methyl 3-carbamoylisobutyrate, which is then reacted with a formic acid ester to form a methylsuccinic acid ester and formamide and the resultant methylsuccinic acid ester is catalytically hydrogenated. The 3-methyltetrahydrofuran is produced in high selectivity and in a commercially advantageous manner from inexpensive reactants. The 3-methyltetrahydrofuran is useful as a commoner for producing polyether glycol, which is utilized as starting raw material for preparing spandex fiber.
    • 一种生产3-甲基四氢呋喃的方法,其中在第一步中,使二异丁酸与甲基丙烯酸甲酯反应产生3-氰基异丁酸甲酯。 然后使3-氰基异丁酸甲酯与水和硫酸反应,生成与C1-C8脂族醇反应生成甲基琥珀酸酯的产物。 将甲基琥珀酸酯催化氢化以制备3-甲基四氢呋喃。 或者,将3-氰基异丁酸甲酯水合,得到3-氨基甲酰基异丁酸甲酯,然后与甲酸酯反应形成甲基琥珀酸酯和甲酰胺,得到的甲基琥珀酸酯被催化氢化。 3-甲基四氢呋喃以廉价的反应物以高选择性和商业上有利的方式生产。 3-甲基四氢呋喃可用作制备聚醚二醇的通用剂,其用作制备氨纶纤维的起始原料。
    • 6. 发明授权
    • Method for enrichment and purification of aqueous hydrogen peroxide
solution
    • 富含和纯化过氧化氢水溶液的方法
    • US5456898A
    • 1995-10-10
    • US303834
    • 1994-09-09
    • Shigeki ShimokawaYoshitsugu MinamikawaSeishi Murakami
    • Shigeki ShimokawaYoshitsugu MinamikawaSeishi Murakami
    • C01B15/013C01B15/01
    • C01B15/013C01B15/0135
    • Proposed is an improvement in a method for the preparation of an enriched and purified aqueous hydrogen peroxide solution from a crude aqueous hydrogen peroxide solution comprising the steps of evaporating the crude aqueous hydrogen peroxide solution in an evaporator into vapor with accompanying liquid in the form of a mist, separating the vapor from the mist of liquid in a gas-liquid separator and subjecting the vapor to fractionating distillation in a fractionating distillation column in order to greatly upgrade the product solution relative to the impurity content. The improvement is achieved by subjecting the crude aqueous hydrogen peroxide solution, prior to introduction into the evaporator, to a contacting treatment with a porous synthetic adsorbent resin to remove organic impurities from the crude aqueous hydrogen peroxide solution to such an extent that the crude aqueous hydrogen peroxide solution after the contacting treatment contains organic impurities in an amount not exceeding 50 ppm by weight calculated as organic carbon. Although the mechanism is not well understood, the preliminary removal of organic impurities from the crude aqueous hydrogen peroxide solution has an effect of greatly increasing the efficiency of gas-liquid separation of the vapor accompanied by a mist of liquid in the gas-liquid separator to decrease the amount of contaminant impurities introduced into the distillation column as carried by the mist.
    • 提出了从粗制过氧化氢水溶液制备富集和纯化的过氧化氢水溶液的方法的改进,包括以下步骤:将蒸发器中的粗过氧化氢水溶液蒸发成蒸汽,伴随液体为 在气 - 液分离器中分离蒸气与液雾的蒸气,并在分馏蒸馏塔中对蒸汽进行分馏,以相对于杂质含量大大提升产物溶液。 改进之处在于,将粗水过氧化氢溶液在引入蒸发器之前,与多孔合成吸附剂树脂进行接触处理以从粗过氧化氢水溶液中除去有机杂质,使得粗制氢水 接触处理后的过氧化物溶液含有不超过作为有机碳计算的50重量ppm的有机杂质。 虽然机理尚不清楚,但是从粗过氧化氢水溶液中初步除去有机杂质具有大大提高伴随气液分离器中的液体雾气的气液分离效率, 减少由雾气引入到蒸馏塔中的污染物杂质的量。