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1. 发明公开

US20230374274A1 METHODS FOR MODIFYING THE OPTICAL APPEARANCE OF POLYMERS 审中-公开
公开(公告)号：US20230374274A1
公开(公告)日：2023-11-23
申请号：US18248008
申请日：2021-10-06
申请人： Lummus Novolen Technology GmbH
发明人： Manfred Wittner , Volker Räntzsch
IPC分类号： C08K13/02 , C08J3/20
CPC分类号： C08K13/02 , C08J3/201 , C08K2003/2296
摘要： The disclosure relates to a method for modifying the optical appearance of a polymer, the method comprising extruding a molten polymer comprising polypropylene and a composition comprising acid scavengers consisting of zinc oxide and zinc carbonate.

2. 发明授权

US11559937B2 Polypropylene for additive manufacturing (3D printing) 有权
公开(公告)号：US11559937B2
公开(公告)日：2023-01-24
申请号：US15680880
申请日：2017-08-18
申请人： Lummus Novolen Technology GmbH
发明人： Manfred Wittner
IPC分类号： B29C64/118 , B33Y10/00 , B29C64/209 , B29C64/106 , B33Y30/00 , B33Y70/00 , B33Y80/00 , C08F210/06 , B29K23/00 , B29C64/336 , B29C64/321
摘要： A process and printer systems for printing a three-dimensional object are disclosed. The processes may include providing a non-crosslinked peroxydicarbonate-branched polypropylene filament, flake, pellet, or powder adapted for one of a fused deposition modeling (ARBURG Plastic Freeforming) printer or a fused filament fabrication printer; and printing the non-crosslinked peroxydicarbonate-branched polypropylene with fused deposition modeling (ARBURG Plastic Freeforming) printer or a fused filament fabrication printer to form a three-dimensional article. The printer systems may include one or more print heads for printing a polymer provided in filament, powder, flake, or pellet form to form a three-dimensional article; and one or more feed systems for providing a non-crosslinked peroxydicarbonate-branched polypropylene to a respective print head.

3. 发明申请

US20220298266A1 CENTRIC SPRAY PIPE 有权
公开(公告)号：US20220298266A1
公开(公告)日：2022-09-22
申请号：US17425828
申请日：2019-01-24
申请人： Lummus Novolen Technology GmbH
发明人： Hermann Gebhart , Franz Langhauser , Oliver Ruhl , Olli Torma
IPC分类号： C08F2/01 , C08F10/06 , B01J19/26 , B01J4/00 , B01J4/02
摘要： A centric spray pipe apparatus is disclosed, The centric spray pipe includes a plurality of nozzles designed to provide full coverage of liquid spray to a vessel.

4. 发明授权

US10066034B2 High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof 有权
公开(公告)号：US10066034B2
公开(公告)日：2018-09-04
申请号：US15286971
申请日：2016-10-06
申请人： Lummus Novolen Technology GmbH
发明人： Yvonne Denkwitz , Oliver Schuster , Andreas Winter
IPC分类号： C08F110/06 , C08F4/10 , C08F10/06
摘要： Improved Ziegler-Natta catalysts and methods of making the improved catalyst are described. The Ziegler-Natta catalyst is formed using a spherical MgCl2-xROH support, where R is a linear, cyclic or branched hydrocarbon unit with 1-10 carbon atoms and where ROH is an alcohol or a mixture of at least two different alcohols and where x has a range of about 1.5 to 6.0, preferably about 2.5 to 4, more preferably about 2.9 to 3.4, and even more preferably 2.95 to 3.35. The Ziegler-Natta catalyst includes a Group 4-8 transition metal and an internal donor comprising a diether compound. The catalyst has improved activity in olefin polymerization reactions as well as good stereoregularity and hydrogen sensitivity, and may be useful in the production of phthalate-free propylene polymers having a molecular weight distribution (PI(GPC)) in the range from about 5.75 to about 9.

5. 发明授权

US10000589B2 High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof 有权
公开(公告)号：US10000589B2
公开(公告)日：2018-06-19
申请号：US15286991
申请日：2016-10-06
申请人： Lummus Novolen Technology GmbH
发明人： Yvonne Denkwitz , Oliver Schuster , Andreas Winter
IPC分类号： C08F110/06 , C08F4/64 , C08F10/00
CPC分类号： C08F110/06 , C08F4/64 , C08F10/00 , C08F4/651 , C08F4/6546
摘要： A method for making a solid catalyst component for use in a Ziegler-Natta catalyst includes combining in a hydrocarbon solvent a porous particulate support with a hydrocarbon soluble organomagnesium compound to form a suspension. The organomagnesium compound is halogenated followed by addition of an alcohol and the mixture is then reacted with a titanium compound followed by a reaction with at least one diether compound to form the solid catalyst component. Afterwards the reaction product is extracted with a mixture of a titanium compound and a hydrocarbon solvent. The solid catalyst component recovered is combined with an aluminum cocatalyst to form a Ziegler-Natta catalyst system for the polymerization of olefins. In particular, the catalyst system including a diether internal electron donor may have an activity and hydrogen response suitable for the production of propylene polymers having a molecular weight distribution (PI(GPC)) in the range from about 5.75 to about 9.

6. 发明授权

US09522968B2 High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof 有权
标题翻译：高性能齐格勒 - 纳塔催化剂体系，用于生产这种MgCl 2的催化剂的方法及其用途
公开(公告)号：US09522968B2
公开(公告)日：2016-12-20
申请号：US14082595
申请日：2013-11-18
申请人： Yvonne Denkwitz , Oliver Schuster , Andreas Winter
发明人： Yvonne Denkwitz , Oliver Schuster , Andreas Winter
IPC分类号： C08F4/10 , C08F10/06
CPC分类号： C08F110/06 , C08F4/10 , C08F10/06 , C08F4/6543 , C08F4/651
摘要： Improved Ziegler-Natta catalysts and methods of making the improved catalyst are described. The Ziegler-Natta catalyst is formed using a spherical MgCl2-xROH support, where R is a linear, cyclic or branched hydrocarbon unit with 1-10 carbon atoms and where ROH is an alcohol or a mixture of at least two different alcohols and where x has a range of about 1.5 to 6.0, preferably about 2.5 to 4, more preferably about 2.9 to 3.4, and even more preferably 2.95 to 3.35. The Ziegler-Natta catalyst includes a Group 4-8 transition metal and an internal donor comprising a diether compound. The catalyst has improved activity in olefin polymerization reactions as well as good stereoregularity and hydrogen sensitivity, and may be useful in the production of phthalate-free propylene polymers having a molecular weight distribution (PI(GPC)) in the range from about 5.75 to about 9.
摘要翻译：描述了改进的齐格勒 - 纳塔催化剂和制备改进的催化剂的方法。齐格勒 - 纳塔催化剂使用球形MgCl 2 -xROH载体形成，其中R是具有1-10个碳原子的直链，环状或支链烃单元，其中ROH是醇或至少两种不同醇的混合物，其中x 具有约1.5至6.0，优选约2.5至4，更优选约2.9至3.4，甚至更优选2.95至3.35的范围。齐格勒 - 纳塔催化剂包括4-8族过渡金属和包含二醚化合物的内给体。该催化剂具有改进的烯烃聚合反应活性以及良好的立构规整性和氢敏感性，并且可用于生产分子量分布（PI（GPC））在约5.75至约 9。

7. 发明授权

US08507706B2 Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers 有权
标题翻译：茂金属化合物，包含它们的催化剂，使用催化剂生产烯烃聚合物的方法，以及烯烃均聚物和共聚物
公开(公告)号：US08507706B2
公开(公告)日：2013-08-13
申请号：US13605049
申请日：2012-09-06
申请人： Anita Dimeska , Ralph-Dieter Maier , Nicola Stephanie Paczkowski , Matthew Grant Thorn , Andreas Winter , Joerg Schulte , Thorsten Sell
发明人： Anita Dimeska , Ralph-Dieter Maier , Nicola Stephanie Paczkowski , Matthew Grant Thorn , Andreas Winter , Joerg Schulte , Thorsten Sell
IPC分类号： C07F17/00 , B01J31/22 , C08F4/6592
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F110/06 , C08F210/06 , C08F210/16 , C08F4/65927 , C08F2500/03 , C08F2500/12
摘要： Certain metallocene compounds are provided that, when used as a component in a supported polymerization catalyst under industrially relevant polymerization conditions, afford high molar mass homo polymers or copolymers like polypropylene or propylene/ethylene copolymers without the need for any α-branched substituent in either of the two available 2-positions of the indenyl ligands. The substituent in the 2-position of one indenyl ligand can be any radical comprising hydrogen, methyl, or any other C2-C40 hydrocarbon which is not branched in the α-position, and the substituent in the 2-position of the other indenyl ligand can be any C4-C40 hydrocarbon radical with the proviso that this hydrocarbon radical is branched in the β-position. This metallocene topology affords high melting point, very high molar mass homo polypropylene and very high molar mass propylene-based copolymers. The activity/productivity levels of catalysts including the metallocenes of the present invention are exceptionally high.
摘要翻译：提供某些茂金属化合物，当在工业上相关的聚合条件下作为负载型聚合催化剂中的组分使用时，提供高摩尔质量的均聚物或共聚物如聚丙烯或丙烯/乙烯共聚物，而不需要任何α-支链取代基茚基配体的两个可用的2-位。一个茚基配体的2-位上的取代基可以是包含氢，甲基或任何其它在α-位上不支链的C 2 -C 40烃基的任何基团，以及另一个茚基配体的2-位上的取代基可以是任何C 4 -C 40烃基，条件是该烃基在β-位上分支。该茂金属拓扑结构提供高熔点，非常高摩尔质量的均聚丙烯和非常高摩尔质量的丙烯基共聚物。包括本发明金属茂的催化剂的活性/生产率水平特别高。

8. 发明申请

US20120046396A1 SUPERTRANSPARENT HIGH IMPACT STRENGTH RANDOM BLOCK COPOLYMER 有权
标题翻译：超强度高冲击强度随机块状共聚物
公开(公告)号：US20120046396A1
公开(公告)日：2012-02-23
申请号：US13287262
申请日：2011-11-02
申请人： José Pezzutti , Alberto Benito , Guillermo Cassano , Leandro Roth , Werner Schoene , Hartmut Siebert , Andreas Winter , Anita Dimeska , Vassilios Galiatsatos
发明人： José Pezzutti , Alberto Benito , Guillermo Cassano , Leandro Roth , Werner Schoene , Hartmut Siebert , Andreas Winter , Anita Dimeska , Vassilios Galiatsatos
IPC分类号： C08K5/1575 , C08L23/16
CPC分类号： C08F297/083 , C08F210/06 , C08L23/14 , C08L23/142 , C08L2205/02 , C08F2/001 , C08L2666/06 , C08F210/16 , C08F2500/12 , C08F2500/26
摘要： A high impact strength random block copolymer including (a) about 65-97 wt. % of a crystalline propylene/ethylene copolymer A containing from about 0.5 wt. % to about 6 wt. % derived from ethylene and from about 94 wt. % to about 99.5 wt. % derived from propylene, and (b) about 3-35 wt. % of a propylene/ethylene copolymer B containing from about 8 wt. % to about 40 wt % derived from ethylene and from about 60 wt % to about 92 wt. % derived from propylene. The crystalline to amorphous ratio Lc/La of the random block copolymer ranges from about 1.00 to about 2.25. The random block copolymer is characterized by both high toughness and low haze.
摘要翻译：一种高冲击强度的无规嵌段共聚物，包括（a）约65-97wt。％的结晶丙烯/乙烯共聚物A含有约0.5wt。％至约6wt。衍生自乙烯的％和约94重量％％至约99.5wt。％衍生自丙烯，和（b）约3-35wt。％的丙烯/乙烯共聚物B含有约8wt。％至约40重量％衍生自乙烯和约60重量％至约92重量％％衍生自丙烯。无规嵌段共聚物的晶体与无定形比Lc / La的范围为约1.00至约2.25。无规嵌段共聚物的特征在于高韧性和低雾度。

9. 发明授权

US08076429B2 Supertransparent high impact strength random block copolymer 有权
标题翻译：超透明高冲击强度随机嵌段共聚物
公开(公告)号：US08076429B2
公开(公告)日：2011-12-13
申请号：US12381382
申请日：2009-03-11
申请人： José Pezzutti , Alberto Benito , Guillermo Cassano , Leandro Roth , Werner Schoene , Hartmut Siebert , Andreas Winter , Anita Dimeska , Vassilios Galiatsatos
发明人： José Pezzutti , Alberto Benito , Guillermo Cassano , Leandro Roth , Werner Schoene , Hartmut Siebert , Andreas Winter , Anita Dimeska , Vassilios Galiatsatos
IPC分类号： C08F2/00 , C08F210/00 , C08F4/00
CPC分类号： C08F297/083 , C08F210/06 , C08L23/14 , C08L23/142 , C08L2205/02 , C08F2/001 , C08L2666/06 , C08F210/16 , C08F2500/12 , C08F2500/26
摘要： A high impact strength random block copolymer including (a) about 65-97 wt. % of a crystalline propylene/ethylene copolymer A containing from about 0.5 wt. % to about 6 wt. % derived from ethylene and from about 94 wt. % to about 99.5 wt. % derived from propylene, and (b) about 3-35 wt. % of a propylene/ethylene copolymer B containing from about 8 wt. % to about 40 wt % derived from ethylene and from about 60 wt % to about 92 wt. % derived from propylene. The crystalline to amorphous ratio Lc/La of the random block copolymer ranges from about 1.00 to about 2.25. The random block copolymer is characterized by both high toughness and low haze.
摘要翻译：一种高冲击强度的无规嵌段共聚物，包括（a）约65-97wt。％的结晶丙烯/乙烯共聚物A含有约0.5wt。％至约6wt。衍生自乙烯的％和约94重量％％至约99.5wt。％衍生自丙烯，和（b）约3-35wt。％的丙烯/乙烯共聚物B含有约8wt。％至约40重量％衍生自乙烯和约60重量％至约92重量％％衍生自丙烯。无规嵌段共聚物的晶体与无定形比Lc / La的范围为约1.00至约2.25。无规嵌段共聚物的特征在于高韧性和低雾度。

10. 发明授权

US07893175B2 Ziegler-natta catalyst, preparation, and use for the polymerization of alkenes 有权
标题翻译：齐格勒 - 纳塔催化剂，制备和用于烯烃聚合的用途
公开(公告)号：US07893175B2
公开(公告)日：2011-02-22
申请号：US12001729
申请日：2007-12-12
申请人： Frank Wolf Spaether , David Andrew Presken
发明人： Frank Wolf Spaether , David Andrew Presken
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F110/06 , C08F4/025 , C08F4/6546 , C08F4/651 , C08F2500/12
摘要： A method for making a solid catalytic component for a Ziegler-Natta catalyst includes contacting a particulate porous support with a solution of a hydrocarbon soluble organomagnesium precursor compound in a hydrocarbon solvent; and reacting said hydrocarbon soluble organo-magnesium precursor compound with an amount of aliphatic or aromatic alcohol, said amount being within an acceptable range of a molar equivalent of aliphatic or aromatic alcohol calculated according to formula (I): Equ Alkanol = 2 · [ ( mmole ⁢ ⁢ MgR / g ⁢ ⁢ support ) - 2.1 - 0.55 · wt ⁢ ⁢ % ⁢ ⁢ ( H 2 ⁢ O ) / support ] [ mmole ⁢ ⁢ MgR / g ⁢ ⁢ support ] ( I ) wherein EquAlkanol=molar equivalents of aliphatic or aromatic alkanol relative to the molar amount of magnesium-organic precursor, (mmole MgR/g support)=mmoles of magnesium-organic precursor per gram of particulate solid support, wt % (H2O)/support=weight percent of physically adsorbed water on the solid support, and said magnesium organic precursor compound being converted to a magnesium-oxygen compound.
摘要翻译：用于制备齐格勒 - 纳塔催化剂的固体催化组分的方法包括使颗粒状多孔载体与烃溶性有机镁前体化合物在烃溶剂中的溶液接触; 并使所述烃溶性有机镁前体化合物与一定量的脂族或芳族醇反应，所述量在根据式（I）计算的摩尔当量的脂族或芳族醇的可接受范围内：AlKanol = 2·[（（H 2 O）/支撑体] [mmole·gel MgR / g·支撑体]（I）其中Equ Alkanol =摩尔当量脂族或芳族链烷醇相对于镁 - 有机前体的摩尔量（毫摩尔MgR / g载体）=每克微粒固体载体的镁 - 有机前体的毫摩尔％wt％（H 2 O）/载体=物理吸附水的重量百分数在固体载体上，并且所述镁有机前体化合物转化为镁 - 氧化合物。

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