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    • 1. 发明授权
    • Liquid concentrate of mineral fillers containing grafted polymers and their use for preparing paints in aqueous and/or organic medium
    • 含有接枝聚合物的矿物填料的液体浓缩物及其在水和/或有机介质中制备油漆的用途
    • US07193008B2
    • 2007-03-20
    • US10472489
    • 2002-03-29
    • Pierre LegrandDaniel Lefevre
    • Pierre LegrandDaniel Lefevre
    • C08J3/00C08K3/10C08K3/30C08L37/00C08L39/00
    • C08F290/062C08F290/046C09D151/00
    • A liquid concentrate of mineral fillers including an aqueous or organic solvent, mineral fillers useful for making paints, with a dry extract of mineral fillers not less than 65%, and a grafted copolymer of: 1) 5 to 40 wt. %, preferably 15 to 35 wt. %, more preferably 20 to 30 wt. % of anchoring sequences of a linear copolymer formed from at least two different monomer units including: a first ethylene monomer unit of at least a basic nitrogenous group, and a second unsaturated ethylene monomer unit of an aromatic group, preferably a phenyl, with the weight content of the first monomer units relative to th second monomer units is from 40 to 60 wt. %, preferably about 50 wt. %; 2) 25 to 90 wt. %, preferably 40 to 80 wt. %, more preferably 50 to 70 wt. % of organo-soluble hydrophobic sequences to disperse the particles in a polar medium; and 3) 5 to 70 wt. %, preferably 15 to 30 wt. %, more preferably 10 to 20 wt. % of hydrophilic sequences of a water-soluble polymer.
    • 含有水溶液或有机溶剂的矿物填料的液体浓缩物,可用于制备油漆的矿物填料,矿物填料的干提取物不少于65%,接枝共聚物为:1〜5重量% %,优选15〜35重量% %,更优选为20〜30wt。 由至少两种不同单体单元形成的线性共聚物的锚定序列的%,包括:至少碱性含氮基团的第一乙烯单体单元和芳族基团,优选苯基的第二不饱和乙烯单体单元,其重量 第一单体单元相对于第二单体单元的含量为40至60wt。 %,优选约50wt。 %; 2)25〜90重量% %,优选40〜80wt。 %,更优选50〜70重量%。 %的有机溶解性疏水序列以将颗粒分散在极性介质中; 和3)5-70wt。 %,优选15〜30wt。 %,更优选10〜20wt。 %水溶性聚合物的亲水序列。