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    • 7. 发明授权
    • Method of fabricating thermoelectric materials using core-shell structured nano-particles, and thermoelectric materials fabricated by the same
    • 使用核 - 壳结构化纳米颗粒制造热电材料的方法,以及由其制造的热电材料
    • US09336922B2
    • 2016-05-10
    • US13552372
    • 2012-07-18
    • Kyung Tae KimGook Hyun Ha
    • Kyung Tae KimGook Hyun Ha
    • H01L35/16H01B1/20B82Y30/00H01L35/12H01L35/18H01L35/34
    • H01B1/20B82Y30/00H01L35/12H01L35/16H01L35/18H01L35/34
    • A fabrication method of thermoelectric materials using core-shell structured nano-particles and thermoelectric materials fabricated by the same are provided. The method includes preparing core-shell structured nano-particles having thermoelectric elements coated on the surface thereof (step 1); adding and mixing the prepared core-shell structured nano-particles of step 1, bismuth (Bi) salts, tellurium (Te) salts and a surfactant in a solvent (step 2); adding and dispersing a reducing agent in the mixture of step (step 3); and heating the mixture of step 3 in which reducing agent is added and dispersed (step 4). According to the present invention, thermoelectric materials, nano-phase is homogeneously dispersed inside of thermoelectric grain boundary, can be fabricated and if the fabricated materials are used after sintering and bulking, the thermoelectric materials are maintained in a state that the nano-particles remain in dispersed phase even after sintering.
    • 提供了使用芯壳结构的纳米颗粒的热电材料及其制造的热电材料的制造方法。 该方法包括制备具有涂覆在其表面上的热电元件的芯壳结构的纳米颗粒(步骤1); 将制备的步骤1的核 - 壳结构纳米颗粒,铋(Bi)盐,碲(Te)盐和表面活性剂加入并混合在溶剂中(步骤2); 在步骤(步骤3)的混合物中加入和分散还原剂; 并加热其中添加和分散还原剂的步骤3的混合物(步骤4)。 根据本发明,可以制造热电材料纳米相均匀地分散在热电晶界内部,并且如果在烧结和膨胀之后使用制造的材料,则将热电材料保持在纳米颗粒保持的状态 即使在烧结后也是分散相。
    • 10. 发明申请
    • METHOD OF MANUFACTURING SUPER HARD ALLOY CONTAINING CARBON NANOTUBES, SUPER HARD ALLOY MANUFACTURED USING SAME, AND CUTTING TOOL COMPRISING SUPER HARD ALLOY
    • 制造含有碳纳米管的超硬合金的方法,使用其制造的超硬合金以及包含超硬合金的切割工具
    • US20140178139A1
    • 2014-06-26
    • US14076460
    • 2013-11-11
    • KOREA INSTITUTE OF MACHINERY AND MATERIALS
    • KyungTae KIMGOOK-HYUN HA
    • B22F5/00B23B27/14
    • C22C26/00B22F3/225B22F2005/001C22C2026/002Y10T407/27
    • Disclosed is a method of manufacturing a super hard alloy containing carbon nanotubes, including (a) forming a carbon nanotube-metal composite from carbon nanotubes and metal powder, (b) mixing the carbon nanotube-metal composite obtained in (a) with hard-phase powder, (c) molding the powder mixture obtained in (b), and (d) sintering the molded body obtained in (c). In the method of the invention, the reaction between carbon nanotubes and transition metal carbide in the super hard alloy is minimized, thus maximizing an increase in toughness by virtue of the addition of carbon nanotubes, thereby obtaining the super hard alloy having both high hardness and high toughness. The super hard alloy containing carbon nanotubes manufactured using the method of the invention has high hardness and high toughness, and thus can be effectively utilized in cutting tools, molds, wear-resistant members, heat-resistant structural materials, etc.
    • 公开了一种制造含有碳纳米管的超硬合金的方法,其包括(a)从碳纳米管和金属粉末形成碳纳米管 - 金属复合物,(b)将(a)中得到的碳纳米管 - 金属复合物与硬质合金 (c)成型(b)中得到的粉末混合物,(d)烧结(c)中得到的成型体。 在本发明的方法中,超硬合金中的碳纳米管与过渡金属碳化物之间的反应最小化,由于添加碳纳米管而使韧性增加最大化,从而获得具有高硬度和高硬度的超硬合金 高韧性 使用本发明的方法制造的包含碳纳米管的超硬合金具有高硬度和高韧性,因此可有效地用于切削工具,模具,耐磨构件,耐热结构材料等。