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1. 发明授权

US6127056A Start up of proton exchange membrane fuel cell 失效
标题翻译：启动质子交换膜燃料电池
公开(公告)号：US6127056A
公开(公告)日：2000-10-03
申请号：US169405
申请日：1998-10-09
申请人： Douglas J. Wheeler , Leonard J. Bonville
发明人： Douglas J. Wheeler , Leonard J. Bonville
IPC分类号： H01M8/04
CPC分类号： H01M8/04007 , H01M2300/0082 , H01M8/04022 , H01M8/04223
摘要： A proton exchange membrane fuel cell has a noble metal or noble metal alloy catalyst 15 disposed in its air inlet manifold 13. During start up, a fuel cell is warmed to operating temperature by introducing a small amount of hydrogen into a flow of air to the air inlet 12 of the fuel cell where they react with the catalyst to produce heat at subflame temperatures. The adiabatic temperature rise of the gas stream is limited to about 150.degree. F. by limiting the hydrogen to about one volume percent of the fuel/oxidant mixture, thereby to be capable of raising the fuel cell temperature, for instance, from -40.degree. C. (-40.degree. F.) to about +45.degree. C. (+113.degree. F.), without flame, explosion or drying out of the membrane.
摘要翻译：质子交换膜燃料电池具有设置在其空气入口歧管13中的贵金属或贵金属合金催化剂15.在启动期间，通过将少量的氢气引入到空气流中来将燃料电池温热至工作温度燃料电池的空气入口12，其与催化剂反应以在亚燃烧温度下产生热量。通过将氢气限制为约1体积％的燃料/氧化剂混合物，气流的绝热温度上限被限制在约150°F，从而能够提高燃料电池温度，例如从-40℃ （-40°F）至约+45°C（+ 113°F），无火焰，爆炸或干燥出膜。

2. 发明授权

US6045772A Method and apparatus for injecting a liquid hydrocarbon fuel into a fuel cell power plant reformer 失效
标题翻译：将液体烃燃料注入到燃料电池发电厂重整器中的方法和装置
公开(公告)号：US6045772A
公开(公告)日：2000-04-04
申请号：US136709
申请日：1998-08-19
申请人： Donald F. Szydlowski , Richard A. Sederquist
发明人： Donald F. Szydlowski , Richard A. Sederquist
IPC分类号： B01B1/00 , B01J8/02 , B01J19/26 , C01B3/32 , C01B3/38 , H01M8/06 , C01B3/26
CPC分类号： C01B3/382 , B01B1/005 , B01J19/26 , B01J8/0278 , C01B3/323 , C01B3/38 , B01J2219/00119 , B01J2219/00162 , B01J2219/00182 , B01J2219/00247 , B01J2219/00252 , C01B2203/0244 , C01B2203/066 , C01B2203/0844 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/1288 , C01B2203/142 , C01B2203/82
摘要： A fuel atomizer for a liquid hydrocarbon fuel reformer/processor creates a high velocity atomized stream of a liquid fuel and steam, wherein the liquid fuel is quickly vaporized so as to limit carbon deposition from the fuel on the fuel vaporizer surfaces. The injector includes a small diameter fuel injection tube through which the liquid fuel and steam mixture is ejected at relatively high velocities. The liquid fuel forms an annular film which surrounds a steam core in the tube, which liquid droplet film and steam core composite are ejected from the tube into a stream of super heated steam, or steam and air. The stream of super heated steam substantially instantaneously vaporizes the fuel droplets from the film after the latter leaves the injection tube.
摘要翻译：用于液体烃燃料重整器/处理器的燃料雾化器产生液体燃料和蒸汽的高速雾化流，其中液体燃料被快速蒸发，以便限制来自燃料蒸发器表面上的燃料的碳沉积。喷射器包括一个小直径的燃料喷射管，液体燃料和蒸汽混合物以较高的速度喷射出来。液体燃料形成围绕管中的蒸汽芯的环形膜，该液体薄膜和蒸汽芯复合材料从该管喷射到一个超加热蒸汽或蒸汽和空气流中。超级加热的蒸汽流在离开喷射管之后基本上瞬间蒸发来自薄膜的燃料液滴。

3. 发明授权

US6024848A Electrochemical cell with a porous support plate 失效
标题翻译：电化学电池与多孔支撑板
公开(公告)号：US6024848A
公开(公告)日：2000-02-15
申请号：US60583
申请日：1998-04-15
申请人： Bryan Franz Dufner , Richard David Breault
发明人： Bryan Franz Dufner , Richard David Breault
IPC分类号： C25B9/08 , H01M8/02 , H01M8/04 , H01M8/08 , H01M8/10 , C25B9/00 , H01M2/14
CPC分类号： H01M8/0243 , C25B9/08 , H01M8/0245 , H01M8/0267 , H01M8/08 , H01M8/1007 , H01M2300/0082 , H01M8/0234 , H01M8/0239 , H01M8/04029 , H01M8/04291 , Y02P70/56
摘要： An improved electrochemical cell such as a fuel cell is disclosed including a porous support plate for enhancing transport of fluids throughout the cell and for enhancing capacitance and transient response capability of the cell. The electrochemical cell includes an electrolyte having opposed major surfaces with an anode and a cathode electrode supported in intimate contact with the opposed major surfaces. A porous support plate is secured adjacent each electrode, and each porous support plate includes a contact bi-layer in intimate contact with the electrode. Each contact bi-layer is comprised of a hydrophobic phase including a mixture of carbon black and a hydrophobic polymer defining a network of hydrophobic gas passages and each contact bi-layer also includes a hydrophilic phase including a mixture of carbon black and a proton exchange resin defining a network of hydrophilic liquid passages integrated throughout the contact bi-layer. Each porous support plate also includes a porous substrate layer adjacent and supporting the contact bi-layer. A method of manufacture of the porous support plate includes the steps of preparing a hydrophobic phase compound, preparing a hydrophilic phase compound, mixing and filtering the two compounds to form a contact bi-layer, transferring the contact bi-layer onto a porous substrate layer to form a porous support plate. An alternative method includes an additional step of activating the contact bi-layer in an acid bath at controlled electrical potentials to enhance capacitance of the cell.
摘要翻译：公开了一种改进的电化学电池，例如燃料电池，其包括用于增强流体在整个电池中的输送并用于增强电池的电容和瞬态响应能力的多孔支撑板。电化学电池包括具有相对的主表面的电解质，阳极和阴极电极与相对的主表面紧密接触。多孔支撑板固定在每个电极附近，并且每个多孔支撑板包括与电极紧密接触的接触双层。每个接触双层由包含炭黑和限定疏水性气体通道网络的疏水性聚合物的混合物的疏水相组成，并且每个接触双层还包括亲水相，其包括炭黑和质子交换树脂的混合物限定整个接触双层中集成的亲水液体通道的网络。每个多孔支撑板还包括邻近和支撑接触双层的多孔基底层。制造多孔支撑板的方法包括制备疏水相化合物，制备亲水相化合物，混合和过滤两种化合物以形成接触双层的步骤，将接触双层转移到多孔基材层上以形成多孔支撑板。替代方法包括在受控电位的酸浴中激活接触双层以增强电池电容的附加步骤。

4. 发明授权

US5931658A Fuel cell power plant furnace 失效
标题翻译：燃料电池发电厂炉
公开(公告)号：US5931658A
公开(公告)日：1999-08-03
申请号：US863643
申请日：1997-05-28
申请人： Richard A. Sederquist , Donald F. Szydlowski , Thomas J. Corrigan , Stanley P. Bonk
发明人： Richard A. Sederquist , Donald F. Szydlowski , Thomas J. Corrigan , Stanley P. Bonk
IPC分类号： B01J8/02 , B01J8/06 , F23D14/66 , F23K5/00 , F23L15/04 , H01M8/04 , H01M8/06 , F23D11/44
CPC分类号： H01M8/0631 , B01J8/0285 , B01J8/062 , F23D14/66 , F23L15/04 , Y02E20/348
摘要： A fuel cell system, generally, has a fuel processing apparatus for steam reforming a hydrocarbon fuel and steam into a product gas, and a fuel cell stack for converting the product gas into electricity. The fuel processing apparatus is a catalytic reaction apparatus having a furnace and a catalytic reactor. In an effort to increase the efficiency of the catalytic reaction apparatus and decrease the size and/or number of catalytic reactors, the present invention relates to a furnace that utilizes air and fuel pre-heat chambers to increase the flame temperature within the furnace.
摘要翻译：燃料电池系统通常具有用于将烃燃料和蒸汽蒸汽重整成产物气体的燃料处理装置和用于将产物气体转换成电的燃料电池堆。燃料处理装置是具有炉和催化反应器的催化反应装置。为了提高催化反应装置的效率并减小催化反应器的尺寸和/或数量，本发明涉及利用空气和燃料预热室来增加炉内火焰温度的炉。

5. 发明授权

US5726105A Composite article 失效
公开(公告)号：US5726105A
公开(公告)日：1998-03-10
申请号：US425282
申请日：1995-04-20
申请人： Albert P. Grasso , Ronald G. Martin , Robert P. Roche
发明人： Albert P. Grasso , Ronald G. Martin , Robert P. Roche
IPC分类号： C04B35/52 , C04B35/83 , H01M8/02 , D04H1/08
CPC分类号： C04B35/83 , H01M8/0213 , Y02P70/56 , Y10S428/902 , Y10T442/59
摘要： The graphitized composite article of the present invention is formed by embedding carbon fiber felt in a matrix of a carbon filler; a thermosetting resin and a solvent; curing the composite article; then, carbonizing and graphitizing the cured composite article to form the graphitized composite article for use as a separator plate capable of substantially inhibiting mixing of hydrogen and oxygen and/or the loss of electrolyte within a fuel cell stack. The graphitized composite article may be a graphitized laminate.

6. 发明授权

US5718881A Catalytic reactor designed to reduce catalyst slumping and crushing 失效
标题翻译：催化反应器旨在减少催化剂的坍塌和破碎
公开(公告)号：US5718881A
公开(公告)日：1998-02-17
申请号：US669187
申请日：1996-06-24
申请人： Richard A. Sederquist , Thomas J. Corrigan , Donald F. Szydlowski , Stanley P. Bonk
发明人： Richard A. Sederquist , Thomas J. Corrigan , Donald F. Szydlowski , Stanley P. Bonk
IPC分类号： B01J8/00 , B01J8/02 , C01B3/38 , H01M8/06 , C01B3/26 , B01J8/06
CPC分类号： H01M8/0631 , B01J8/008 , B01J8/02 , B01J8/0257 , C01B3/384 , B01J2208/00495 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/1017 , C01B2203/1052 , C01B2203/1082 , C01B2203/1609 , Y10S423/13
摘要： A steam reformer for converting a reactor fuel into a product gas includes a segmented catalyst bed. The steam reformer side walls have a thermal coefficient of expansion which is greater than the thermal coefficient of expansion of the catalyst. By forming low volume catalyst bed segments in the hotter portions of the catalyst bed, slumping and subsequent damage of the catalyst pellets is minimized. The catalyst bed is divided into segments whose volumes are inversely proportional to the temperatures of the various zones in the reformer. The segments are formed by utilizing sequential catalyst support assemblies which include perforated catalyst support members that are differentially spaced apart from each other by support assembly legs having varying lengths. Catalyst support assemblies with shorter length legs are used in the hotter zones of the reformer, and support assemblies with progressively longer length legs are used in the cooler zones of the reformer.
摘要翻译：用于将反应堆燃料转化为产物气体的蒸汽重整器包括分段的催化剂床。蒸汽重整器侧壁的热膨胀系数大于催化剂的热膨胀系数。通过在催化剂床的较热部分中形成低体积的催化剂床段，使催化剂颗粒的坍落和随后的破坏最小化。催化剂床被分成其体积与重整器中的各个区域的温度成反比的段。这些段通过利用连续的催化剂支撑组件形成，催化剂支撑组件包括通过具有不同长度的支撑组件腿彼此间隔开的穿孔催化剂支撑构件。在重整器的较热区域中使用具有较短长度腿部的催化剂支撑组件，并且在重整器的较冷区域中使用具有逐渐更长长度腿部的支撑组件。

7. 发明授权

US5607786A Fuel cell transport frame 失效
标题翻译：燃料电池运输框架
公开(公告)号：US5607786A
公开(公告)日：1997-03-04
申请号：US435693
申请日：1995-05-05
申请人： Robin J. Guthrie , Thomas J. Corrigan
发明人： Robin J. Guthrie , Thomas J. Corrigan
IPC分类号： H01M8/24 , H01M12/08
CPC分类号： H01M8/247
摘要： The present invention discloses a transport frame for transporting and maintaining a fuel cell stack assembly in a fixed position. The fuel cell stack asembly which is under compression by a top and bottom plate held together by tie rods positioned at the corners of each plate. The top and bottom plates are then mounted to a rigid frame for transporting the fuel cell. The tie rods being attached to mounts in the base plate of the rigid frame and an insulated attachment between the top plate of the fuel cell stack frame and the rigid frame is made. The fuel cell stack assembly being electrically insulated from the rigid frame.
摘要翻译：本发明公开了一种用于将燃料电池堆组件运输和维持在固定位置的运输框架。由顶板和底板压缩的燃料电池堆组件，其通过位于每个板的角落处的拉杆保持在一起。然后将顶板和底板安装到用于运输燃料电池的刚性框架。连接杆安装在刚性框架的底板中，并且在燃料电池堆架框架的顶板和刚性框架之间形成绝缘附件。燃料电池堆组件与刚性框架电绝缘。

8. 发明授权

US5478663A Edge seals for molten carbonate fuel cell stacks 失效
标题翻译：熔融碳酸盐燃料电池堆的边缘密封
公开(公告)号：US5478663A
公开(公告)日：1995-12-26
申请号：US216198
申请日：1994-03-22
申请人： Ned E. Cipollini , Lawrence J. Bregoli , Donald L. Maricle
发明人： Ned E. Cipollini , Lawrence J. Bregoli , Donald L. Maricle
IPC分类号： H01M8/14 , H01M2/08 , H01M8/02 , H01M8/24
CPC分类号： H01M8/244 , H01M8/0271 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： The reactant manifolds and corners of a molten carbonate fuel cell stack are sealed with particulate lithium aluminate members which are sufficiently porous so as to resist significant electrolyte migration therethrough. The seal members which are disposed in vertical planes of the stack are preferentially formed from lithium aluminate grains which are bonded together by a silica-free glass binder. The seal members which are disposed in horizontal planes in the stack are preferably formed from lithium aluminate grains which are bonded together by surface hydrolysis. Alumina-clad stainless steel labyrinth seal members are associated with each of the horizontal seal members to inhibit electrolyte migration from the cell electrolyte matrices to the vertical seal members.
摘要翻译：熔融碳酸盐燃料电池堆的反应物歧管和拐角用足够多孔的铝酸锂构件密封，以便抵抗由此产生的显着的电解质迁移。设置在堆叠的垂直平面中的密封构件优选由铝硅酸盐颗粒形成，所述铝酸锂颗粒通过无二氧化硅的玻璃粘结剂粘合在一起。叠置在水平面上的密封构件优选由铝酸锂颗粒形成，所述铝酸锂颗粒通过表面水解结合在一起。氧化铝包覆的不锈钢迷宫式密封件与每个水平密封件相关联，以抑制电解质从电池电解质基质迁移到垂直密封件。

9. 发明授权

US5468573A Electrolyte paste for molten carbonate fuel cells 失效
标题翻译：用于熔融碳酸盐燃料电池的电解质糊
公开(公告)号：US5468573A
公开(公告)日：1995-11-21
申请号：US264540
申请日：1994-06-23
申请人： Lawrance J. Bregoli , Mark L. Pearson
发明人： Lawrance J. Bregoli , Mark L. Pearson
IPC分类号： H01M8/02 , H01M8/04 , H01M8/14
CPC分类号： H01M8/142 , H01M8/04283 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： The electrolyte matrix and electrolyte reservoir plates in a molten carbonate fuel cell power plant stack are filled with electrolyte by applying a paste of dry electrolyte powder entrained in a dissipatable carrier to the reactant flow channels in the current collector plate. The stack plates are preformed and solidified to final operating condition so that they are self sustaining and can be disposed one atop the other to form the power plant stack. Packing the reactant flow channels with the electrolyte paste allows the use of thinner electrode plates, particularly on the anode side of the cells. The use of the packed electrolyte paste provides sufficient electrolyte to fill the matrix and to entrain excess electrolyte in the electrode plates, which also serve as excess electrolyte reservoirs. When the stack is heated up to operating temperatures, the electrolyte in the paste melts, the carrier vaporizes, or chemically decomposes, and the melted electrolyte is absorbed into the matrix and electrode plates.
摘要翻译：在熔融碳酸盐燃料电池发电厂堆叠中的电解质基质和电解质储存器板通过将夹带在可消散载体中的干电解质粉末的浆料施加到集电板中的反应物流动通道而填充有电解质。堆叠板被预成型并固化成最终操作状态，使得它们是自维持的，并且可以一个放在另一个上以形成发电厂堆叠。用电解质浆料包装反应物流动通道允许使用更薄的电极板，特别是在电池的阳极侧。使用包装的电解质糊剂提供足够的电解质以填充基质并且将过量的电解质夹带在电极板中，这也用作过量的电解质储存器。当堆叠被加热到操作温度时，糊料中的电解质熔化，载体蒸发或化学分解，并且熔融的电解质被吸收到基质和电极板中。

10. 发明授权

US5366825A Laminated electrolyte reservoir plate 失效
标题翻译：层压电解液储罐
公开(公告)号：US5366825A
公开(公告)日：1994-11-22
申请号：US178074
申请日：1994-01-06
申请人： Richard D. Breault , Michael E. Gorman
发明人： Richard D. Breault , Michael E. Gorman
IPC分类号： C04B35/645 , D21H13/50 , H01M8/02 , H01M2/18
CPC分类号： D21H13/50 , C04B35/645 , H01M8/0271 , H01M8/0289 , Y02P70/56 , Y10T29/49112
摘要： An electrolyte reservoir plate is formed in a papermaking process. Graphite powder, reinforcing fibers, cellulosic fibers, and a thermosetting resin are mixed with a liquid to form a slurry and showered onto a screen to form a planar sheet which is dried to form paper. The paper is cut into the desired size and is lay-up with main sheets 4 and edge strips 6. The lay-up is laminated with pressure and heat, carbonized, and graphitized to form an electrolyte reservoir plate.
摘要翻译：在造纸工艺中形成电解质储存器板。将石墨粉末，增强纤维，纤维素纤维和热固性树脂与液体混合以形成浆料并淋浴到筛网上以形成干燥以形成纸的平面片材。将纸切割成所需尺寸，并且与主片材4和边缘条6一起堆叠。叠层层叠有压力和热量，碳化并石墨化以形成电解质储存器板。

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