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1. 发明授权

US08415517B2 Continuous process for converting natural gas to liquid hydrocarbons 有权
标题翻译：将天然气转化为液态碳氢化合物的连续工艺
公开(公告)号：US08415517B2
公开(公告)日：2013-04-09
申请号：US12504865
申请日：2009-07-17
申请人： Sagar Gadewar , Michael Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman , Peter Stoimenov , Hongfei Lin , Shawn Huff , Shouli Sun
发明人： Sagar Gadewar , Michael Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman , Peter Stoimenov , Hongfei Lin , Shawn Huff , Shouli Sun
IPC分类号： C07C1/00
CPC分类号： B01J8/00 , B01J8/18 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C17/06 , C07C17/10 , C07C17/23 , C07C17/26 , Y02C20/30 , C07C19/075 , C07C25/02
摘要： A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.
摘要翻译：一种方法，包括：提供第一卤素流; 提供第一烷烃流; 使第一卤素流的至少一部分与至少一部分第一烷烃流在第一反应容器中反应以形成第一卤化流; 提供包含C2和高级烃的第二烷烃流; 提供第二卤素流; 以及使第二卤素流的至少一部分与第二烷烃物流的至少一部分在第二反应容器中反应以形成第二卤化物流。

2. 发明授权

US07838708B2 Hydrocarbon conversion process improvements 失效
标题翻译：烃转化过程改进
公开(公告)号：US07838708B2
公开(公告)日：2010-11-23
申请号：US12692831
申请日：2010-01-25
申请人： Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Breed , Michael F. Doherty
发明人： Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Breed , Michael F. Doherty
IPC分类号： C07C29/48 , C07C29/58
CPC分类号： C07C1/30 , C07C17/10 , C07C29/124 , C07C29/58 , C07C45/27 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/06 , C07C2523/42 , C07C2523/745 , C07C2523/75 , C07C2523/80 , C07C2527/128 , C07C2527/133 , C07D301/26 , Y02P20/582 , C07C19/075 , C07C19/043 , C07C19/07 , C07C47/06 , C07C41/01 , C07C43/04 , C07C31/02
摘要： Improvements in previously disclosed methods of and apparatuses for converting alkanes, alkenes, and aromatics to olefins, alcohols, ethers, and aldehydes includes: safety improvements, use of alternative feedstocks, process simplification, improvements to the halogenation step, improvements to the reproportionation step, improvements to the solid oxide reaction, improvements to solid oxide regeneration, improvements in separations, maintenance, start-up, shut-down, and materials of construction.
摘要翻译：将烷烃，烯烃和芳族化合物转化为烯烃，醇，醚和醛的先前公开的方法和装置的改进包括：安全性改进，替代原料的使用，工艺简化，改进卤化步骤，改性步骤，固体氧化物反应的改进，固体氧化物再生的改进，分离改进，维护，启动，停机和施工材料。

3. 发明授权

US07148390B2 Integrated process for synthesizing alcohols, ethers, aldehydes, and olefins from alkanes 失效
公开(公告)号：US07148390B2
公开(公告)日：2006-12-12
申请号：US10375464
申请日：2003-02-27
申请人： Xiao Ping Zhou , Ivan Marc Lorkovic , Jeffrey H. Sherman
发明人： Xiao Ping Zhou , Ivan Marc Lorkovic , Jeffrey H. Sherman
IPC分类号： C07C11/02 , C07C11/04 , C07C11/06 , C07C11/09
CPC分类号： C07D301/26 , C07C17/10 , C07C29/124 , C07C45/27 , Y02P20/125 , C07C19/075 , C07C47/06 , C07C31/04 , C07C31/08
摘要： Alcohols, ethers, aldehydes, and olefins are manufactured from alkanes by mixing an alkane and a halogen selected from the group including chlorine, bromine, and iodine in a reactor to form alkyl halide and hydrogen halide. The alkyl halide only or the alkyl halide and the hydrogen halide are directed into contact with metal oxide to form an alcohol and/or an ether, or an olefin and metal halide. The metal halide is oxidized to form original metal oxide and halogen, both of which are recycled.

4. 发明授权

US6156279A Method of and apparatus for manufacturing methanol 失效
标题翻译：制造甲醇的方法和装置
公开(公告)号：US6156279A
公开(公告)日：2000-12-05
申请号：US370945
申请日：1999-08-09
申请人： Jeffrey H. Sherman
发明人： Jeffrey H. Sherman
IPC分类号： B01J8/00 , B01J10/00 , B01J12/00 , B01J19/12 , B01J19/24 , B01J35/00 , C01B3/38 , C07C29/00 , C07C29/48 , B01J19/08
CPC分类号： B01J12/007 , B01J10/007 , B01J19/123 , B01J19/127 , B01J19/2415 , B01J19/2475 , B01J35/002 , B01J35/004 , B01J8/009 , C01B3/38 , C07C29/00 , C07C29/48 , B01F2003/04858 , B01F2215/0431 , B01J2219/00081 , B01J2219/00139 , B01J2219/00162 , B01J2219/00189 , B01J2219/0869 , B01J2219/0877 , B01J2219/0884 , B01J2219/0892 , C01B2203/0233 , C01B2203/1035 , C01B2203/1041 , C01B2203/1241 , C01B2203/84 , Y02P20/52
摘要： In a method of and apparatus for manufacturing methanol from methane, a catalytic area is formed on the exterior of a hollow sintered stainless steel tube. Methane is maintained within the sintered stainless steel tube at predetermined pressure, and water continuously flowing across the exterior surface thereof strips the methane forming sub-micron sized methane bubbles. Light energy is directed onto the catalytic surface to form hydroxyl radicals from the flowing water. The hydroxyl radicals cleave the carbon-hydrogen bonds of the methane to form methyl ions which combine with the hydroxyl ions to form methanol.
摘要翻译：在从甲烷制造甲醇的方法和装置中，在中空烧结不锈钢管的外部形成催化区域。甲烷以预定压力保持在烧结的不锈钢管内，并且连续流过其外表面的水分离甲烷形成亚微米尺寸的甲烷气泡。光能被引导到催化表面上以从流动的水中形成羟基自由基。羟基自由基切割甲烷的碳氢键形成与羟基离子结合形成甲基的甲基离子。

5. 发明授权

US08278493B2 Hydrocarbon synthesis 失效
标题翻译：烃合成
公开(公告)号：US08278493B2
公开(公告)日：2012-10-02
申请号：US13107611
申请日：2011-05-13
申请人： Ivan M. Lorkovic
发明人： Ivan M. Lorkovic
IPC分类号： C07C1/00
CPC分类号： C10G50/00 , C07C1/26 , C07C2521/10 , C07C2523/02 , C07C2529/18 , C07C2529/40 , C10G27/00 , C10G2400/02 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y10S585/935 , Y10S585/943
摘要： A method of synthesizing hydrocarbons from smaller hydrocarbons includes the steps of hydrocarbon halogenation, simultaneous oligomerization and hydrogen halide neutralization, and product recovery, with a metal-oxygen cataloreactant used to facilitate carbon-carbon coupling. Treatment with air or oxygen liberates halogen and regenerates the cataloreactant.
摘要翻译：从较小的烃合成烃的方法包括烃卤化，同时低聚和卤化氢中和以及用于促进碳 - 碳偶联的金属 - 氧催化反应物的产物回收步骤。用空气或氧气处理释放卤素并再生催化反应物。

6. 发明授权

US08053616B2 Continuous process for converting natural gas to liquid hydrocarbons 有权
标题翻译：将天然气转化为液态碳氢化合物的连续工艺
公开(公告)号：US08053616B2
公开(公告)日：2011-11-08
申请号：US12496348
申请日：2009-07-01
申请人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman
发明人： Sagar B. Gadewar , Michael D. Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman
IPC分类号： C07C17/00
CPC分类号： C07C15/02 , C07C1/26 , C07C11/04 , C07C11/06 , C07C17/10 , C07C17/37 , C07C2527/053 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/83 , C07C2529/85 , C07C2529/89 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C19/075
摘要： A method comprising providing a halogen stream; providing a first alkane stream; reacting at least a portion of the halogen stream with at least a portion of the first alkane stream to form a halogenated stream, wherein the halogenated stream comprises alkyl monohalides, alkyl polyhalides, and a hydrogen halide; providing a second alkane stream; and reacting at least a portion of the second alkane stream with at least a portion of the alkyl polyhalides to create at least some additional alkyl monohalides.
摘要翻译：一种包括提供卤素流的方法; 提供第一烷烃流; 使卤素物流的至少一部分与至少一部分第一烷烃物流反应以形成卤化物流，其中卤代物流包含烷基一卤化物，烷基多卤化物和卤化氢; 提供第二烷烃流; 并使第二烷烃物流的至少一部分与至少一部分烷基多卤化物反应以产生至少一些另外的烷基一卤化物。

7. 发明授权

US07498008B2 Process of gas treatment to remove pollutants 失效
标题翻译：气体处理过程去除污染物
公开(公告)号：US07498008B2
公开(公告)日：2009-03-03
申请号：US11359779
申请日：2006-02-23
申请人： Jeffrey H. Sherman , Sagar B. Gadewar , Peter K. Stoimenov
发明人： Jeffrey H. Sherman , Sagar B. Gadewar , Peter K. Stoimenov
IPC分类号： B01D53/50 , B01D53/52 , B01D53/64
CPC分类号： B01D53/507 , B01D53/52 , B01D53/64 , C01B17/60
摘要： A process for the removal of a pollutant from a gas is provided that includes contacting a gas comprising a pollutant with a cataloreactant wherein the cataloreactant reacts with the pollutant and wherein an oxidation state of the cataloreactant is reduced. The cataloreactant may be regenerated with an oxidizing agent.
摘要翻译：提供了从气体中除去污染物的方法，包括使包含污染物的气体与催化反应物接触，其中催化反应物与污染物反应，并且其中催化反应物的氧化态降低。催化反应剂可以用氧化剂再生。

8. 发明申请

US20080314758A1 Process for converting hydrocarbon feedstocks with electrolytic recovery of halogen 审中-公开
标题翻译：用卤素电解回收来转化烃原料的方法
公开(公告)号：US20080314758A1
公开(公告)日：2008-12-25
申请号：US12152515
申请日：2008-05-14
申请人： Philip Grosso , Eric W. McFarland , Jeffrey H. Sherman
发明人： Philip Grosso , Eric W. McFarland , Jeffrey H. Sherman
IPC分类号： C25B3/06 , C25B3/00
CPC分类号： C25B1/24 , C07C1/30 , C07C11/02 , C10B53/04 , C10B57/06 , C10G29/02 , C10G2300/1011 , C10G2300/1025 , C10G2400/30 , C25B1/04 , H01L2924/014 , Y02E60/366 , Y02P20/145
摘要： An improved continuous process for converting methane, natural gas, and other hydrocarbon feedstocks into one or more higher hydrocarbons, methanol, amines, or other products comprises continuously cycling through hydrocarbon halogenation, product formation, product separation, and electrolytic regeneration of halogen, optionally using an improved electrolytic cell equipped with an oxygen depolarized cathode.
摘要翻译：将甲烷，天然气和其他烃原料转化成一种或多种高级烃，甲醇，胺或其它产物的改进的连续方法包括连续循环通过烃卤化，产物形成，产物分离和卤素的电解再生，任选地使用配备有氧去极化阴极的改进的电解槽。

9. 发明申请

US20030125589A1 Zone reactor 失效
公开(公告)号：US20030125589A1
公开(公告)日：2003-07-03
申请号：US10369148
申请日：2003-02-19
申请人： GRT, Inc.
发明人： Philip Grosso
IPC分类号： C07C029/62
CPC分类号： C07C29/124 , C07C41/16 , C07C31/04 , C07C43/043
摘要： In a method of converting alkanes to their corresponding alcohols and ethers a vessel comprises a hollow, unsegregated interior defined first, second, and third zones. In a first embodiment of the invention oxygen reacts with metal bromide in the first zone to provide bromine; bromine reacts with the alkane in the second zone to form alkyl bromide; and the alkyl bromide reacts with metal oxide in the third zone to form the corresponding alcohol and/or ether. Metal bromide from the third zone is transported through the vessel to the first zone and metal oxide from the first zone is recycled to the third zone. A second embodiment of the invention differs from the first embodiment in that metal oxide is transported through the vessel from the first zone to the third zone and metal bromide is recycled from the third zone to the first zone. In a third embodiment of the invention the flow of gases through the vessel is reversed to convert the metal oxide back to metal bromide and to convert the metal bromide back to the metal oxide.

10. 发明授权

US07847139B2 Hydrocarbon synthesis 失效
标题翻译：烃合成
公开(公告)号：US07847139B2
公开(公告)日：2010-12-07
申请号：US12217311
申请日：2008-07-02
申请人： Ivan M. Lorkovic , Maria Noy , Jeffrey H. Sherman , Michael J. Weiss , Galen D. Stucky
发明人： Ivan M. Lorkovic , Maria Noy , Jeffrey H. Sherman , Michael J. Weiss , Galen D. Stucky
IPC分类号： C07C1/00
CPC分类号： C07C1/26 , C07C2521/10 , C07C2523/02 , C07C2529/18 , C07C2529/40 , Y10S585/935 , Y10S585/943
摘要： A method of synthesizing hydrocarbons from smaller hydrocarbons includes the steps of hydrocarbon halogenation, simultaneous oligomerization and hydrogen halide neutralization, and product recovery, with a metal-oxygen cataloreactant used to facilitate carbon-carbon coupling. Treatment with air or oxygen liberates halogen and regenerates the cataloreactant.
摘要翻译：从较小的烃合成烃的方法包括烃卤化，同时低聚和卤化氢中和以及用于促进碳 - 碳偶联的金属 - 氧催化反应物的产物回收步骤。用空气或氧气处理释放卤素并再生催化反应物。

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