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    • 2. 发明授权
    • Catalytic converter
    • 催化转化器
    • US5480620A
    • 1996-01-02
    • US291819
    • 1994-08-17
    • Gordon M. Cameron
    • Gordon M. Cameron
    • C01B17/765C01B17/80B01D50/00
    • C01B17/803C01B17/765
    • A catalytic converter for converting sulfur dioxide to sulfur trioxide comprising an exterior shell of a heat resistant weldable metal; foundations from which the shell vertically extends; an interior tube of same metal vertically disposed within the shell and defining a passage; the interior tube having i. a first inlet aperture through which the passage receives a first portion of a sulfur dioxide-containing gas from a source of such gas; ii. a second inlet aperture through which the passage receives a second portion of the sulfur dioxide-containing gas; and iii. an outlet aperture; at least one catalyst bed including an annular bed extending fully between the shell and the interior tube; wherein the annular bed is in direct gaseous communication within the shell with the first passage through the outlet aperture; a plurality of axial heat exchange tubes within the interior tube for conducting hot sulfur trioxide-containing gas from the catalyst bed through the heat exchange tubes to effect heat transfer with and to heat the first and second portions of the sulfur dioxide-containing gas and to cool the hot sulfur-trioxide containing gas; structure for directing the hot sulfur trioxide-containing gas to the heat exchange tubes, and for directing the heated first and second portions of the sulfur-dioxide containing gas through the outlet aperture to the annular bed. The converter offers improved thermal efficiencies and compactness.
    • 一种用于将二氧化硫转化为三氧化硫的催化转化器,包括耐热可焊接金属的外壳; 壳体垂直延伸的基础; 垂直设置在壳体内并限定通道的相同金属的内管; 内管有i。 第一入口孔,通道从该第一入口孔接收来自这种气体源的第一部分含二氧化硫的气体; ii。 第二入口孔,通道通过该第二入口孔容纳含二氧化硫气体的第二部分; 和iii。 出口孔; 至少一个催化剂床,包括在壳体和内部管之间完全延伸的环形床; 其中所述环形床在所述壳体内与所述第一通道通过所述出口孔直接气体连通; 内部管中的多个轴向热交换管,用于通过热交换管从催化剂床传导含热氧化硫的气体,以实现与含二氧化硫的气体的第一和第二部分的热传递和加热含二氧化硫的气体的第一和第二部分,并且 冷却含热氧化硫的气体; 用于将热的含三氧化硫的气体引导到热交换管的结构,以及用于将加热的含二氧化硫的气体的第一和第二部分通过出口孔引导到环形床。 该转换器提供了改进的热效率和紧凑性。
    • 3. 发明授权
    • Cooled sulphur furnace bypass system
    • 冷却硫化炉旁路系统
    • US5308587A
    • 1994-05-03
    • US956298
    • 1992-10-05
    • Gordon M. Cameron
    • Gordon M. Cameron
    • C01B17/54C01B17/76
    • C01B17/54C01B17/76Y02P20/129
    • Apparatus and process for the production of gaseous sulphur dioxide mixture for conversion to sulphur trioxide in a catalytic converter in the production of sulphuric acid by the contact process. Apparatus comprises the furnace to produce sulphur dioxide gas from elemental sulphur and a first dry air stream; means for feeding a first portion of the sulphur dioxide gas to a waste heat boiler to cool the gas; the improvement comprising combining a second portion of the sulphur dioxide gas exiting the furnace with a second dry air stream to provide a combined gaseous stream which bypasses the boiler and subsequently is combined with the cooled sulphur dioxide stream. The system provides use of a bypass valve which experiences only cooled sulphur dioxide containing gases with its attendant reduced corrosion. Further, the system may operate at higher temperatures than is common to provide further advantages.
    • 用于生产气态二氧化硫混合物的装置和方法,用于在催化转化器中通过接触方法生产硫酸转化为三氧化硫。 装置包括从元素硫和第一干燥空气流产生二氧化硫气体的炉; 用于将第一部分二氧化硫气体供给到废热锅炉以冷却气体的装置; 所述改进包括将离开炉的二氧化硫气体的第二部分与第二干燥空气流组合以提供绕过锅炉并随后与冷却的二氧化硫流组合的组合气流。 该系统提供使用旁通阀,其仅经历冷却的含二氧化硫的气体,伴随着降低的腐蚀。 此外,该系统可以在比常见的更高的温度下操作以提供进一步的优点。
    • 5. 发明授权
    • Packed absorption towers
    • 包装吸收塔
    • US5679290A
    • 1997-10-21
    • US714370
    • 1996-09-16
    • Gordon M. CameronDahya Bhaga
    • Gordon M. CameronDahya Bhaga
    • B01D53/18B01F3/04C01B17/80
    • C01B17/806B01D53/18B01F3/04468B01J2219/30Y10S261/72
    • An improved packed tower for effecting the absorption of a gas into a liquid, comprising a cylindrical tower wall defining a packing zone; a plurality of packing pieces contained within the packing zone; a liquid distributor above the packing zone for distributing liquid onto the packing pieces; a gas feed inlet below the packing pieces for feeding gas through the packing zone, the improvement wherein the plurality of packing pieces comprises a first plurality of packing pieces, of a first packing piece size, disposed within a first region of the packing zone defining an annulus adjacent at an upper part of the tower wall, and a second plurality of packing pieces of a second packing piece size greater than the first packing piece size, within a second region of the packing zone. The packed tower provides higher efficiencies in gas absorption over prior art towers as to offer reduced tower and/or packing heights.
    • 一种用于将气体吸收到液体中的改进的填充塔,包括限定填料区的圆柱形塔壁; 包装在包装区内的多个包装件; 在包装区域上方的液体分配器,用于将液体分配到包装件上; 包装件下方的气体进料入口用于将气体输送通过填料区,其改进在于,多个填料件包括第一填料段的第一多个填料件,第一填料段设置在填料区的第一区域内, 在塔壁的上部相邻的环形空间,以及在包装区域的第二区域内的尺寸大于第一包装件尺寸的第二包装件的第二多个包装件。 填充塔提供比现有技术塔更高的气体吸收效率,以提供降低的塔和/或包装高度。
    • 6. 发明授权
    • Furnace-heat exchanger preheating system
    • 炉 - 热交换器预热系统
    • US5477846A
    • 1995-12-26
    • US291818
    • 1994-08-17
    • Gordon M. Cameron
    • Gordon M. Cameron
    • F24H3/08
    • F24H3/087F28D7/0066F28D7/1607
    • The invention provides in one broad aspect an improved process fluid preheater system for raising the temperature of a process fluid with a hot furnace gas, having a combustion furnace in communication with a shell and tube heat exchanger, wherein the furnace operably produce the hot furnace gas and comprises air inlet means, fossil fuel combustion means and hot furnace gas exit means; and the heat exchanger comprises an exchanger shell, a first end radial tube sheet and a second end radial tube sheet, which define a shell space; a plurality of longitudinal tubes retained by the first and second end tube sheets within the shell and comprising heat exchange means; hot furnace gas inlet means; cooled furnace gas outlet means; process gas inlet means; and heated process fluid outlet means; the improvement comprising the plurality of tubes further comprises the hot furnace gas inlet means and the cooled furnace gas outlet means; the hot furnace gas exit means in communication with the plurality of tubes furnace gas inlet means to operably provide the tubes with the hot furnace gas. The process fluid inlet means comprises a first process fluid inlet adjacent the first tube sheet and in communication with the shell space, and a second process fluid inlet adjacent the second tube sheet and in communication with the shell space; and the heated process fluid outlet means comprises a fluid outlet essentially midway between the first and the second tube sheets and in communication with the shell space.
    • 本发明在一个广泛的方面提供了一种改进的工艺流体预热器系统,其用于利用具有与壳管式热交换器连通的燃烧炉的热炉气体来提高工艺流体的温度,其中炉可操作地产生热炉气体 包括进气装置,化石燃料燃烧装置和热炉气体出口装置; 并且所述热交换器包括限定外壳空间的交换器外壳,第一端径向管板和第二端径向管板, 多个纵管,由第一和第二端管板保持在壳体内并包括热交换装置; 热炉煤气进口装置; 冷却炉煤气出口装置; 工艺气体进口装置; 和加热过程流体出口装置; 包括多个管的改进还包括热炉气体入口装置和冷却炉气体出口装置; 热炉气体出口装置与多个炉管气体入口装置连通,以可操作地为管提供热炉气体。 过程流体入口装置包括邻近第一管板并与壳体空间连通的第一工艺流体入口和邻近第二管板并与壳体空间连通的第二工艺流体入口; 并且加热的过程流体出口装置包括基本在第一和第二管板之间的中间并与壳体空间连通的流体出口。
    • 7. 发明授权
    • Method and apparatus for sulfuric acid concentration
    • 硫酸浓缩的方法和装置
    • US5075097A
    • 1991-12-24
    • US595516
    • 1990-10-11
    • Gordon M. Cameron
    • Gordon M. Cameron
    • C01B17/88
    • C01B17/88Y10S423/02
    • Dilute waste sulfuric acid is concentrated by heating it against product acid and then passing it through two contact zones separated by a collection zone. The dilute acid scrubs vapour produced in the collection zone and from a high temperature acid reboiler. In the collection zone acid is drawn off, heated, and recirculated to the collection zone where part of the liquid flashes to vapour. The main heat input is to the more dilute low temperature recirculating acid from the first contact zone rather than to the more concentrated high temperature acid in the reboiler. As a result, less sulfuric acid vapour is generated; the major portion of the heat can be fed to the process at low temperature; and only a single column is required, having a single cool clear water vapour exit stream to dispose of.
    • 稀释废硫酸通过加热产品酸浓缩,然后将其通过由收集区分离的两个接触区域。 稀酸洗涤收集区产生的蒸气和高温酸再沸器。 在收集区中,酸被抽出,加热并再循环到收集区,其中部分液体闪蒸至蒸气。 主要的热量输入是来自第一接触区域的更稀释的低温再循环酸,而不是再沸器中更浓缩的高温酸。 结果,产生较少的硫酸蒸气; 热的主要部分可以在低温下进料到工艺中; 并且仅需要单个柱,具有单个清澈的透明水蒸气出口流以处置。
    • 8. 发明授权
    • Liquid distributor for a packed tower
    • 用于包装塔的液体分配器
    • US5884658A
    • 1999-03-23
    • US708750
    • 1996-09-05
    • Gordon M. Cameron
    • Gordon M. Cameron
    • B01D3/00B01F5/06B01F3/04
    • B01D3/008B01F15/0264B01F5/0601Y10T137/85938
    • A liquid distributor for use within a cylindrical tower containing tower packing to provide dispersed liquid to the packing comprising (a) a plurality of cordially disposed feed liquid conduits interconnected one to another to form, at least, one coplanar essentially continuous loop, (b) a feed entry for feeding the liquid to the conduits, and (c) sprayers for dispersing the liquid onto the packing. The distributor is of particular value in the sulfric acid manufacturing field as a drying tower, sulfur dioxide stripping tower, sulfur trioxide absorption tower and an oleum tower. The distributor provides improved irrigation across the tower and, particularly, adjacent the tower wall.
    • 一种液体分配器,用于包含塔板填料的圆筒形塔架中,用于向填料提供分散的液体,其包括:(a)多个彼此相互连接形成至少一个共面基本上连续的环的多个精心布置的进料液体导管,(b) 用于将液体输送到管道的进料入口,和(c)用于将液体分散到包装上的喷雾器。 分散剂在作为干燥塔,二氧化硫汽提塔,三氧化硫吸收塔和发烟硫酸塔的硫酸制造领域是特别有价值的。 分销商提供改进的灌溉跨越塔,特别是在塔壁附近。
    • 9. 发明授权
    • Catalytic converter
    • 催化转化器
    • US5302353A
    • 1994-04-12
    • US13536
    • 1993-01-28
    • Gordon M. Cameron
    • Gordon M. Cameron
    • B01J8/04C01B17/80B01D50/00
    • C01B17/803B01J8/0469B01J8/048
    • A converter comprising an exterior shell of a strong, heat resistant weldable metal having an interior core tube formed of such metal and vertically disposed, partway within the shell from an upper part thereof. A foundation is provided from which the shell vertically extends. A plurality of catalyst beds are arranged one above the other within the shell and comprise at least one full catalyst bed having a first full bed extending essentially across a lower part of the shell, and at least one annular catalyst bed having a first annular bed between the shell at an upper part thereof and the core tube. Partitions define with the core tube a plurality of distinct, non-concentric, non-coaxial gas passages within the core tube. Each of the annular beds is in singular, gaseous communication within the shell with at least one of the passages. The converter has minimal axial gaseous flow transfer passages for maximum catalyst bed volume while preserving axial access to the beds.
    • 一种转炉,其特征在于,该外壳具有强耐热可焊接金属的外壳,该金属外壳具有由这种金属形成的内部芯管,并且垂直地设置在壳体的上部的中间。 壳体垂直延伸的基础。 多个催化剂床在壳内一个彼此上下排列,并且包括至少一个完整的催化剂床,其具有基本上延伸穿过壳的下部的第一满床,以及至少一个环状催化剂床, 壳体在其上部和芯管。 分隔件与芯管一起限定在芯管内的多个不同的,非同心的非同轴气体通道。 每个环形床在壳内具有至少一个通道的单一,气体连通。 该转换器具有最小的轴向气流传输通道,用于最大化催化剂床体积,同时保持对床的轴向通路。
    • 10. 发明授权
    • Heat exchanger having improved tube layout
    • 热交换器具有改进的管布局
    • US5277247A
    • 1994-01-11
    • US905452
    • 1992-06-29
    • Gordon M. Cameron
    • Gordon M. Cameron
    • B01D1/06C01B17/80F28D7/16F28F9/22F28D7/10
    • F28D7/163B01D1/06C01B17/806F28F9/22Y10S165/91
    • A heat exchanger for exchanging heat between fluids comprising a shell and five tube bundles laid out as to collectively form a series of concentric pentagons, wherein each adjacent pair of tube bundles define an angle of 108.degree. and extend longitudinally within said shell and define a central space between them, said central space also extending longitudinally in said shell and being parallel to said tubes; each tube bundle consisting of a plurality of longitudinally extending parallel tubes in end view laid out in a set of parallel lines wherein each tube on a first parallel line with the two nearest tubes each on a second line adjacent to said first line forms an isosceles triangle having one angle of 72.degree. and two angles each of 54.degree.. This allows simple heat exchanger tube layout which is easy to fabricate and provide a compact tube bundle. The tube layout utilizes core tube entry of fluids and can accommodate internal core tubes or bypasses to cope with differential expansion.
    • 一种热交换器,用于在流体之间交换热量,所述热交换器包括外壳和布置成共同形成一系列同心五边形的五个管束,其中每个相邻的一对管束限定108度的角度并且在所述壳体内纵向延伸并限定中心 所述中心空间也在所述外壳中纵向延伸并平行于所述管; 每个管束由端部视图中的多个纵向延伸的平行管组成,其平行管线布置在一组平行线中,其中在与第一线相邻的第二线上的两个最近的管的第一平行线上的每个管形成等腰三角形 具有72度的一个角度和54度的两个角度。 这允许简单的热交换器管布置,其易于制造并且提供紧凑的管束。 管道布局利用流体的芯管进入,并且可以容纳内部核心管或旁路以应对差动膨胀。