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    • 2. 发明申请
    • Low surface energy polyisocyanates and their use in one-or two-component coating compositions
    • 低表面能多异氰酸酯及其在单组分或双组分涂料组合物中的用途
    • US20070032623A1
    • 2007-02-08
    • US11198707
    • 2005-08-05
    • Richard RoeslerJames GarrettAaron LockhartCarol Kinney
    • Richard RoeslerJames GarrettAaron LockhartCarol Kinney
    • C08G18/00
    • C08G18/289C08G18/307C08G18/42C08G18/792C08G18/809C09D175/04
    • The present invention is directed to a polyisocyanate mixture i) having a monomeric diisocyanate content of less than 3% by weight, ii) having a urethane group content of more than 50 equivalent %, based on the total equivalents of urethane and allophanate groups, and iii) containing siloxane groups (calculated as SiO, MW 44) in an amount of 0.002 to 50% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate mixture and wherein the siloxane groups are incorporated by reacting a) an isocyanate group from a polyisocyanate adduct containing isocyanurate groups and prepared from a monomeric diisocyanate having at least one cycloaliphatic group with b) a compound containing one or more hydroxyl groups directly attached to a carbon atom and one or more siloxane groups to form urethane groups. The present invention also relates to the use of this polyisocyanate mixture, optionally in blocked form, as an isocyanate component in one- or two-component coating compositions.
    • 本发明涉及单体二异氰酸酯含量小于3重量%的二异氰酸酯混合物,ii)氨基甲酸酯基含量大于等于50当量的氨基甲酸酯和脲基甲酸酯基,和 iii)含有0.002至50重量%的硅氧烷基团(以SiO,MW 44计算),其中前述百分比基于多异氰酸酯混合物的固体含量,并且其中硅氧烷基团通过使a) 异氰酸酯基团,其由含有异氰脲酸酯基团的多异氰酸酯加合物制备,并由具有至少一个脂环族基团的单体二异氰酸酯制备,b)含有一个或多个直接连接到碳原子上的羟基和一个或多个硅氧烷基团以形成氨基甲酸酯基团的化合物。 本发明还涉及这种多异氰酸酯混合物(任选地为封闭形式)在单组分或双组分涂料组合物中作为异氰酸酯组分的用途。