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81. 发明授权

US4973680A Organosiloxane-containing polysaccharides 失效
标题翻译：含有机硅氧烷的多糖
公开(公告)号：US4973680A
公开(公告)日：1990-11-27
申请号：US318579
申请日：1989-03-03
申请人： Robert L. Billmers
发明人： Robert L. Billmers
IPC分类号： A61K47/14 , A61K31/21 , A61K31/35 , A61K31/445 , A61K31/56 , A61P9/08 , A61P9/10 , C03C25/10 , C03C25/40 , C08B3/00 , C08B11/04 , C08B31/00 , C08B31/02 , C08B33/00 , C08B37/00 , C08F290/10 , D06M15/643 , D06M101/00 , D21H17/24 , D21H17/28 , D21H17/29 , D21H17/59
CPC分类号： C08B31/00 , C03C25/40 , C08B11/04 , C08B31/02 , C08B37/0096 , C08F290/10 , D21H17/24 , D21H17/29 , D21H17/59 , Y10T428/2913 , Y10T428/2962 , Y10T428/2965 , Y10T428/2967
摘要： Disclosed are a polysaccharide derivative having the structure: ##STR1## and a polysaccharide graft polymer having the structure: Sacch-O-(G).sub.m -(M)-.sub.n, wherein Sacch- is a polysaccharide; m is zero or one; G is the residue of a polymerizable, unsaturated monomer which is bonded to the polysaccharide in an ether or ester linkage; n is greater than one; M is the residue of one or more polymerizable, unsaturated, monomer(s), at least one of which is a siloxane-containing monomer, which have been grafted to the polysaccharide by free radical polymerization; R is an organic group which is bonded to the polysaccharide by an ether or ester linkage and to the silicon by a carbon-silicon linkage; R.sub.1 is a straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl group, or an aryl, aralkyl or alkaryl group; and R.sub.2 and R.sub.3 are, independently, straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl groups, or aryl, aralkyl or alkaryl groups, or alkoxides of straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl groups, or aryl, aralkyl or alkaryl groups, or alkoxides wherein R.sub.2 and R.sub.3 together form a cyclic structure of at least five members. The siloxane-containing polysaccharide derivatives and polysaccharide graft polymers are useful in glass fiber forming size compositions, in paper making and in other applications.

82. 发明授权

US4804769A Acetals useful for the preparation of polysaccharide derivatives 失效
标题翻译：用于制备多糖衍生物的缩醛
公开(公告)号：US4804769A
公开(公告)日：1989-02-14
申请号：US037282
申请日：1987-04-10
申请人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
发明人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler , Robert L. Billmers , Diane J. Lamb , John J. Tsai
IPC分类号： C07H15/04 , C07H15/12 , C08B11/04 , C08B11/08 , C08B11/14 , C08B31/12 , C08B37/00 , C08B37/14 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31 , C07D319/06
CPC分类号： C08B11/14 , C08B11/04 , C08B31/12 , C08B31/125 , C08B37/0096 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31
摘要： Polysaccharide aldehydes having the formula Sacch-O-CH.sub.2 -CH.dbd.CH-CHO, Sacch-O-CH.sub.2 -C.tbd.C-CHO, ##STR1## such as starch, cellulose, and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formulas, n is 1-3; R.sup.11 and R.sup.12 are independently an alkyl, aryl, aralkyl, or alkaryl group when n is 1, R.sup.11 or R.sup.12 is one of the groups when n is 2, or R.sup.11 and R.sup.12 are not present when n is 3; R.sup.13 is an alkyl group, optionally containing an ether linkage, or an aralkyl group; R.sup.14 and R.sup.15 are individually a hydrogen or a methyl group; R.sup.16, R.sup.17, and R.sup.18 are individually an alkyl group; Y.sup.- is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.19, if present, is a divalent organic group containing no reactive substiuents; and A and A' are lower alkyls or together form at least a 5-membered cyclic acetal.
摘要翻译：具有式Sacch -O-CH 2 -CH = CH-CHO，Sacch -O-CH 2 -C 3OND C-CHO，图像＆gt;＆lt; IMAGE＆gt;＆lt; IMAGE＆gt;和+ TR＆lt; IMAGE＆gt;的多糖醛例如淀粉，纤维素和醛醛可用于赋予纸张湿，干或临时湿强度。它们通过非氧化方法制备，其包括在碱存在下使多糖碱与具有一般结构“IMAGE”的衍生化缩醛试剂反应，然后通过将pH调节至小于7，优选2来水解缩醛 -4。在式中，n为1-3; 当n为1时，R11和R12独立地为烷基，芳基，芳烷基或烷芳基，当n为2时，R11或R12为基团之一，当n为3时，R11和R12不存在; R13是任选含有醚键或芳烷基的烷基; R 14和R 15分别为氢或甲基; R16，R17和R18各自为烷基; Y-是阴离子; Z是能够与多糖基反应形成醚衍生物并选自环氧化物，烯属不饱和基，卤代醇和卤素的有机基团; R19如果存在，是不含反应性残基的二价有机基团; 并且A和A'是低级烷基或一起形成至少5元环缩醛。

83. 发明授权

US4675394A Polysaccharide derivatives containing aldehyde groups, their preparation from the corresponding acetals and use as paper additives 失效
标题翻译：含有醛基的多糖衍生物，由相应的缩醛制成，用作纸添加剂
公开(公告)号：US4675394A
公开(公告)日：1987-06-23
申请号：US758634
申请日：1985-07-24
申请人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler
发明人： Daniel B. Solarek , Patrick G. Jobe , Martin M. Tessler
IPC分类号： C07H15/04 , C07H15/12 , C08B11/04 , C08B11/08 , C08B11/14 , C08B31/12 , C08B37/00 , C08B37/14 , D21H17/24 , D21H17/25 , D21H17/28 , D21H17/31 , C08B11/00 , C08B15/06 , C08B31/08
CPC分类号： C08B11/04 , C08B11/14 , C08B31/12 , C08B31/125 , C08B37/0087 , C08B37/0096 , D21H17/25 , D21H17/28 , D21H17/31
摘要： Polysaccharide aldehydes having the general structure ##STR1## such as starch, cellulose and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. R is (CH.sub.2).sub.n or a divalent aromatic group and n is 0 or greater; R.sup.1, R.sup.6, and R.sup.7 are hydrogen or an organic group; R.sup.2, R.sup.5, and R.sup.8 are (CH.sub.2).sub.m with m being 1-6; R.sup.3 and R.sup.4 are hydrogen or a lower alkyl; Y is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.11, if present, is a divalent organic group containing no reactive substiuents; and A and A' are lower alkyls or together form at least a 5-membered cyclic acetal.
摘要翻译：具有一般结构 + TR 的多糖醛如淀粉，纤维素和醛醛可用于赋予纸张湿，干或临时湿强度。它们通过非氧化方法制备，其包括在碱存在下使多糖碱与具有一般结构“IMAGE”的衍生化缩醛试剂反应，然后通过将pH调节至小于7，优选2来水解缩醛 -4。 R为（CH 2）n或二价芳族基，n为0以上; R1，R6和R7是氢或有机基团; R2，R5和R8是（CH2）m，其中m是1-6; R3和R4是氢或低级烷基; Y是阴离子; Z是能够与多糖基反应形成醚衍生物并选自环氧化物，烯属不饱和基，卤代醇和卤素的有机基团; R11如果存在，是不含反应性的二价有机基团; 并且A和A'是低级烷基或一起形成至少5元环缩醛。

84. 发明授权

US4582899A Manufacturing method for cellulose ether having high degree of substitution 失效
标题翻译：具有高取代度的纤维素醚的制造方法
公开(公告)号：US4582899A
公开(公告)日：1986-04-15
申请号：US720927
申请日：1985-04-08
申请人： Hiroyuki Nakamura
发明人： Hiroyuki Nakamura
IPC分类号： C08B11/04 , C08B11/187 , C08B13/00 , C08B11/00 , C08B11/16 , C08B11/18
CPC分类号： C08B11/04 , C08B11/187 , C08B13/00
摘要： A manufacturing method for cellulose ether having a high degree of substitution characterized in that an etherifying agent represented by a general formula RCH.sub.2 X (where R is aromatic group, heterocyclic group, vinyl group or ethynyl group or the same group substituted and X is chlorine or bromine) is reacted with a uniform solution of cellulose acetate having a degree of substitution of 2.0 and over in an organic solvent in the presence of a base to manufacture a highly substituted cellulose ether having a degree of substitution of 2.0 and over per anhydrous glucose unit by a one stage reaction at a good yield.As a general method for manufacturing cellulose ether, a method for reacting an etherifying agent with alkali cellulose is now in use. For the general method, several improved methods have been proposed. However, it is difficult to manufacture cellulose ether having a degree of substitution of 2.5 and over by a one stage reaction using the general method. As manufacturing methods for cellulose ether other than the general method, a method for using a solvent-soluble cellulose derivative as the raw material and a method for using a special solvent in which cellulose is soluble were proposed. However, the former had a defect of a low yield and the latter had a defect of too long a reaction time.
摘要翻译：具有高取代度的纤维素醚的制造方法，其特征在于，由通式RCH2X（其中R是芳族基，杂环基，乙烯基或乙炔基或与之相同基团取代的醚化剂）和X是氯或溴）与有机溶剂中的取代基为2.0以上的醋酸纤维素的均匀溶液在碱的存在下反应，以通过以下方式制备高度取代的取代度为2.0的纤维素醚一个阶段的反应以良好的收益率。作为制造纤维素醚的一般方法，现在使用醚化剂与碱纤维素反应的方法。对于一般方法，已经提出了几种改进的方法。然而，通过一般方法，难以通过一步反应制造取代度为2.5以上的纤维素醚。作为除一般方法以外的纤维素醚的制造方法，提出了使用溶剂可溶性纤维素衍生物作为原料的方法和使用其中可溶解纤维素的特殊溶剂的方法。然而，前者具有低产量的缺点，后者具有反应时间太长的缺点。

85. 发明授权

US4501887A Preparing cellulose ethers in a dimethoxyethane/(dispersing auxiliary) medium 失效
标题翻译：在二甲氧基乙烷/（分散助剂）介质中制备纤维素醚
公开(公告)号：US4501887A
公开(公告)日：1985-02-26
申请号：US581233
申请日：1984-02-17
申请人： Wolfgang Kornrumpf , Eberhard Perplies , Josef Hilbig , Utz-Hellmuth Felcht
发明人： Wolfgang Kornrumpf , Eberhard Perplies , Josef Hilbig , Utz-Hellmuth Felcht
IPC分类号： C08B11/02 , C08B11/00 , C08B11/04 , C08B11/08 , C08B11/12 , C08B11/193
CPC分类号： C08B11/00
摘要： In modern processes for the preparation of cellulose ethers containing one or more types of substituents (such as MC, CMC, HEC, HPC, MHEC or EHEC), cellulose is reacted with etherifying agents in the presence of water, base and a mixture of preferably inert organic solvents (as a dispersing auxiliary). Dimethoxyethane (ethylene glycol dimethyl ether) and at least one organic solvent selected from the group including alkanols, alkane diols and alkoxy alkanols (for example, methanol and/or isopropanol) are employed in the mixture of organic solvents used for these syntheses, particularly in quantities of 1 to 30 parts by weight per 1 part by weight of cellulose.
摘要翻译：在制备含有一种或多种取代基（例如MC，CMC，HEC，HPC，MHEC或EHEC）的纤维素醚的现代方法中，纤维素与醚化剂在水，碱和优选的混合物的存在下与醚化剂反应惰性有机溶剂（作为分散助剂）。在用于这些合成的有机溶剂的混合物中使用二甲氧基乙烷（乙二醇二甲醚）和选自烷醇，烷二醇和烷氧基链烷醇（例如甲醇和/或异丙醇）的至少一种有机溶剂，特别是在相对于1重量份的纤维素，其含量为1〜30重量份。

86. 发明授权

US4109080A Ion exchange compounds on cellulose basis and process for the manufacture thereof 失效
标题翻译：纤维素基础上的离子交换化合物及其制造方法
公开(公告)号：US4109080A
公开(公告)日：1978-08-22
申请号：US810963
申请日：1977-06-29
申请人： Karl Heinrich Lieser , Peter Burba
发明人： Karl Heinrich Lieser , Peter Burba
IPC分类号： C09K3/00 , B01J39/22 , B01J45/00 , C08B11/04 , C08B11/14 , C08B11/00
CPC分类号： B01J39/22 , C08B11/04 , C08B11/14
摘要： The present invention relates to ion exchange compounds on cellulose basis having formula ##STR1## wherein R is a group that forms chelate complexes with metal ions, and Cell stands for the cellulose matrix. Suitable functional groups R are derivatives of known metal reactants, which show a high degree of selectivity for specific metal ions. The ion exchange compounds are able to fix specifically preferred ions e.g. metal ions even in a considerable excess of foreign ions, for example in concentrated salt solutions.The improved ion exchange compounds of this invention are prepared by reacting the compound ##STR2## with cellulose in the presence of alkali, diazotizing the cellulose derivative resulting therefrom and subsequently coupling couplable compounds which form chelate complexes with metal ions.

87. 发明授权

US3493407A Preparation of medicinal capsules from hydroxyalkylcellulose ethers 失效
标题翻译：从羟丙基纤维素酶制备药物胶囊
公开(公告)号：US3493407A
公开(公告)日：1970-02-03
申请号：US3493407D
申请日：1967-05-26
申请人： DOW CHEMICAL CO
发明人： GREMINGER GEORGE K JR , DAVIS LEWIS E
IPC分类号： A61J3/07 , A61K9/48 , C08B11/04 , C08B11/193 , C08L1/28 , C09D101/28 , C08B21/24 , A61K9/04
CPC分类号： C08L1/284 , A61J3/077 , A61K9/4816 , C08B11/04 , C08B11/193 , C09D101/284 , Y10S206/828 , C08L2666/28

88. 发明授权

US3446794A Cellulose derivatives 失效
标题翻译：纤维素衍生物
公开(公告)号：US3446794A
公开(公告)日：1969-05-27
申请号：US3446794D
申请日：1964-10-20
申请人： W & R BALSTON LTD
发明人： KNIGHT COLIN SUTHERLAND , REIMER ALEXANDER CLAUDE , WEAVER VICTOR CHARLES , BROOK BRIAN NEVILLE
IPC分类号： C01B31/16 , C08B11/00 , C08B11/04 , C08B11/193 , C08B15/10 , C08B15/00
CPC分类号： C08B15/10 , C08B11/00 , C08B11/04 , C08B11/193

89. 发明授权

US3372132A Graft polymers of cellulose crystallite aggregates 失效
标题翻译：纤维素微晶聚集体的接枝聚合物
公开(公告)号：US3372132A
公开(公告)日：1968-03-05
申请号：US36550864
申请日：1964-05-06
申请人： FMC CORP
发明人： CRUZ JR MAMERTO M
IPC分类号： C08B11/04 , C08F251/02 , H01B3/18 , H01B3/44
CPC分类号： H01B3/185 , C08B11/04 , C08F251/02 , H01B3/44

90. 发明授权

US3353904A Cross-linking cellulose and starch with perfluoropolyenes having at least two unsaturated terminal groups 失效
标题翻译：将纤维素和淀粉与具有至少两个不饱和端基的全氟聚异氰酸酯交联
公开(公告)号：US3353904A
公开(公告)日：1967-11-21
申请号：US43286365
申请日：1965-02-15
申请人： KORATRON COMPANY INC
发明人： ENGLERT ROBERT D , SIERRZ MADRE , RONALD SWIDLER , BERRIMAN LESTER P , WADE ROBERT H
IPC分类号： C08B11/04 , C08B15/10 , C08B31/00
CPC分类号： C08B15/10 , C08B11/04 , C08B31/003

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