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81. 发明授权

US5554349A Process for scavenging H.sub.2 S by mixtures of hexahydrotriazines 失效
标题翻译：通过六氢三嗪混合物清除H2S的方法
公开(公告)号：US5554349A
公开(公告)日：1996-09-10
申请号：US302548
申请日：1994-09-08
申请人： Gordon T. Rivers , Richard L. Rybacki
发明人： Gordon T. Rivers , Richard L. Rybacki
IPC分类号： B01D53/52 , C07D251/04 , B01D53/48
CPC分类号： B01D53/52 , C07D251/04 , C09K8/532 , C23F11/10 , C23F11/149 , C09K2208/20 , Y02P20/51
摘要： A mixture of amines made by reacting an amine compound with an aldehyde compound has been found to reduce the levels of H.sub.2 S in liquid or gaseous hydrocarbon streams. At least one of the compounds must have an alkoxyalkylene radical. In one embodiment of the invention, the mixture of amines contains at least one hexahydrotriazine compound of the formula: ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently selected from the group consisting of hydrogen and an alkyl radical, including substituted alkyl radicals, of 1 to 5 carbon atoms; where at least one of the groups is an alkoxyalkylene group. In another embodiment of the invention, the amine mixture may contain other by products, such as the monomers which make up the hexahydrotriazine, with or without the hexahydrotriazine being present. These materials are selective to the reduction of H.sub.2 S levels in hydrocarbon or aqueous streams in the presence of CO.sub.2 which does not compromise their performance.
摘要翻译：已经发现通过使胺化合物与醛化合物反应制得的胺的混合物降低液态或气态烃流中的H 2 S的水平。至少一种化合物必须具有烷氧基亚烷基。在本发明的一个实施方案中，胺的混合物含有至少一种下式的六氢三嗪化合物：其中R 1，R 2，R 3，R 4，R 5和R 6独立地选自氢和具有1-5个碳原子的烷基，包括取代的烷基; 其中至少一个基团是烷氧基亚烷基。在本发明的另一个实施方案中，胺混合物可以含有其它产物，例如构成六氢三嗪的单体，存在或不存在六氢三嗪。这些材料对于在不影响其性能的CO 2存在下在烃或水流中降低H 2 S水平是选择性的。

82. 发明授权

US5523069A Carbonyl sulfide abatement in fluids 失效
标题翻译：流体中的羰基硫化物减少
公开(公告)号：US5523069A
公开(公告)日：1996-06-04
申请号：US147624
申请日：1993-11-05
申请人： M. Linda Lin
发明人： M. Linda Lin
IPC分类号： B01D53/48
CPC分类号： B01D53/485 , Y10S423/19
摘要： A method for removing carbonyl sulfide from fluids, particularly gases, involves contacting them with alkaline aqueous solutions containing peroxide and hindered amine. The sulfur products so formed can then be separated from the fluid. In one embodiment, gas containing carbonyl sulfide is cycled through a wet scrubber containing a solution of hydrogen peroxide and methyldiethanolamine, triethylamine, dimethylmonoethanolamine, diethylmonoethanolamine, triethanolamine, 2-amino-2-meth-yl-1-propanol, and/or 1,8-p-menthanediaminemethyldiethanolamine at a pH of about 9 to 11, e.g., about 10. Methyldiethanolamine is preferred in one embodiment. A dispersant such as a water-soluble polymer having a molecular weight of about 500 to 100,000 may optionally be employed in the solution. Abatement of greater than 90% of the carbonyl sulfide is achieved in preferred embodiments.
摘要翻译：从流体，特别是气体中除去羰基硫的方法包括使它们与含有过氧化物和受阻胺的碱性水溶液接触。这样形成的硫产物可以与流体分离。在一个实施方案中，含有硫化羰的气体循环通过含有过氧化氢和甲基二乙醇胺，三乙胺，二甲基一乙醇胺，二乙基单乙醇胺，三乙醇胺，2-氨基-2-甲基-1-丙醇和/ 8-p-薄荷氨基甲基二乙醇胺，pH为约9至11，例如约10.在一个实施方案中，优选甲基二乙醇胺。分散剂如分子量约为500至100,000的水溶性聚合物可以任选地用于溶液中。在优选的实施方案中可以实现大于90％的硫化羰的消除。

83. 发明授权

US5500196A Method of reagent and oxidation air delivery 失效
标题翻译：试剂和氧化空气输送方法
公开(公告)号：US5500196A
公开(公告)日：1996-03-19
申请号：US107387
申请日：1993-08-16
申请人： Kevin J. Rogers , Dennis W. Johnson
发明人： Kevin J. Rogers , Dennis W. Johnson
IPC分类号： B01D53/50 , B01D53/48
CPC分类号： B01D53/501 , B01D53/504
摘要： A method of forced oxidation flue gas desulfurization uses an oxidation air system air stream to not only provide oxidation air into an absorber vessel, but also to pneumatically convey and inject dry reagent into the absorber vessel to satisfy reagent addition requirements. If necessary, other dry additives can be added to the dry reagent so that the oxidation air stream injects both the dry reagent and the dry additives into the absorber vessel.
摘要翻译：强制氧化烟气脱硫的方法使用氧化空气系统空气流，不仅向吸收容器提供氧化空气，而且还将干试剂气动输送并注入吸收器容器中以满足试剂添加要求。如果需要，可以向干燥试剂中加入其它干燥添加剂，使得氧化空气流将干试剂和干燥添加剂都注入吸收器容器中。

84. 发明授权

US5417946A Process for removing total reduced sulfur compounds from gaseous stream 失效
标题翻译：从气流中除去总还原硫化合物的方法
公开(公告)号：US5417946A
公开(公告)日：1995-05-23
申请号：US176045
申请日：1993-12-30
申请人： Charles C. Chou , Chaoliang Yao
发明人： Charles C. Chou , Chaoliang Yao
IPC分类号： B01D53/48 , B01D53/52 , C01B17/00 , C01B17/16
CPC分类号： B01D53/48 , B01D53/52
摘要： A process for removing Total Reduced Sulfur compounds from a gaseous stream such as those containing natural gas, industrial gas, and digester gas by oxidation with a fine flocculent acidic catalyst slurry which is regenerable during the process by pH adjustment in the absence of added heat. The catalyst slurry comprises MnO.sub.2, Mn.sub.2 O.sub.3, and Mn.sub.3 O.sub.4 having pH in the range from about 0.5 to about 6.5 and is prepared by oxidizing a divalent manganous salt in an aqueous solution having a pH in the range from about 8.0 to about 13.5 with an oxygen-containing gaseous stream.
摘要翻译：一种从气态物流中除去总还原硫化合物的方法，例如含有天然气，工业气体和蒸煮器气体的气体，通过在不加热的情况下通过pH调节在该过程中可再生的细絮凝酸性催化剂浆料进行氧化。催化剂浆料包含pH在约0.5至约6.5范围内的MnO 2，Mn 2 O 3和Mn 3 O 4，并且通过在pH为约8.0至约13.5的水溶液中氧化二价锰盐来制备，含有气流。

85. 发明授权

US5354545A Process for the removal of sulphur compounds from gases 失效
标题翻译：从气体中除去硫化合物的方法
公开(公告)号：US5354545A
公开(公告)日：1994-10-11
申请号：US70336
申请日：1993-05-26
申请人： Cees J. N. Buisman
发明人： Cees J. N. Buisman
IPC分类号： B01D53/14 , B01D53/34 , B01D53/48 , B01D53/50 , B01D53/52 , B01D53/77 , B01D53/84 , C01B17/05 , C02F3/34 , C12S5/00 , C01B17/00
CPC分类号： C12M47/18 , B01D53/48 , B01D53/507 , B01D53/52 , B01D53/84 , C01B17/05 , C02F3/345 , C12M21/04 , Y02C10/06 , Y02E50/343 , Y10S423/17
摘要： A process for the removal of sulphur compounds from a gaseous effluent, comprising the steps of: a) contacting the gaseous effluent with an aqueous solution wherein sulphur compounds are dissolved; b) adjusting the concentration of buffering compounds such as carbonate and/or bicarbonate and/or phosphate in the aqueous solution to a value between 20 and 2000 meq/l; c) subjecting the aqueous solution containing sulphide to sulphide-oxidizing bacteria in the presence of oxygen in a reactor wherein sulphide is oxidized to elemental sulphur; d) separating elemental sulphur from the aqueous solution; and e) recycling the aqueous solution to step a). This process is suitable for removing H.sub.2 S from biogas, ventilation air etc. It can be used for removing SO.sub.2 from combustion gases by introducing the additional step, after step a) and before step c), of subjecting the aqueous solution containing the sulphur compounds to a reduction of the sulphur compounds to sulphide. H.sub.2 S and SO.sub.2 removal is further enhanced by a residual sulphur content in the washing liquid of 1-50 g/l.
摘要翻译： PCT No.PCT / NL91 / 00250 Sec。 371日期：1993年5月26日 102（e）日期1993年5月26日PCT 1991年12月4日PCT PCT。出版物WO92 / 10270 日期：1992年6月25日。一种从气态流出物中除去硫化合物的方法，包括以下步骤：a）使气态流出物与其中硫化合物溶解的水溶液接触; b）将水溶液中缓冲化合物如碳酸盐和/或碳酸氢盐和/或磷酸盐的浓度调节至20至2000meq / l之间的值; c）在其中硫化物被氧化成元素硫的反应器中，使含有硫化物的水溶液在氧气存在下进行硫化物氧化细菌; d）从水溶液中分离元素硫; 和e）将水溶液再循环到步骤a）。该方法适用于从沼气，通风空气等中除去H2S。可以在步骤a）和步骤c）之后引入附加步骤，将含硫化合物的水溶液将硫化合物还原成硫化物。 H2S和SO2的去除通过洗涤液中残留的硫含量进一步提高了1-50g / l。

86. 发明授权

US5320992A Disposable oxide carrier for scavenging hydrogen sulfide 失效
标题翻译：用于清除硫化氢的一次性氧化物载体
公开(公告)号：US5320992A
公开(公告)日：1994-06-14
申请号：US69073
申请日：1993-05-28
申请人： Irwin Fox , Alvin Samuels
发明人： Irwin Fox , Alvin Samuels
IPC分类号： B01D53/48 , B01D53/52 , B01J20/02 , B01J23/745 , B01J37/00 , B01J37/02 , B01J23/70
CPC分类号： B01J23/745 , B01D53/485 , B01D53/52 , B01J20/02 , B01J20/06 , B01J20/12 , B01J20/3204 , B01J20/3236 , B01J37/0072 , B01J37/0203 , B01D2257/30 , B01D2257/304
摘要： A mineral carrier for those iron oxides which react to remove hydrogen sulfide and mercaptans from fluid streams. The new carrier avoids the problem encountered with wood chip beds of bed solidification which occurs when reacted oxide particles adhere to each other. Calcined montmorillonite, for example, possesses the necessary crush strength, porosity, insolubility in water and wettability, to maintain bed perviousness and avoid caking as reaction continues to the full capacity of the oxide.
摘要翻译：用于从流体流中除去硫化氢和硫醇的那些铁氧化物的矿物载体。新载体避免了当氧化物颗粒彼此粘附时发生的床层固化木屑床遇到的问题。例如，煅烧的蒙脱石具有必要的压碎强度，孔隙率，不溶于水和润湿性，以保持床的透水性，并避免结晶，因为反应持续到氧化物的全部容量。

87. 发明授权

US5298228A Method and apparatus for treating hydrocarbon gas streams contaminated with carbonyl sulfide 失效
标题翻译：用于处理受硫化羰污染的烃类气流的方法和装置
公开(公告)号：US5298228A
公开(公告)日：1994-03-29
申请号：US941509
申请日：1992-09-08
申请人： S. Travis Palomares , Thomas G. Morrison
发明人： S. Travis Palomares , Thomas G. Morrison
IPC分类号： B01D53/18 , B01D53/48 , B01J10/00 , C01B17/00
CPC分类号： B01J10/00 , B01D53/18 , B01D53/485 , Y10S203/06
摘要： An improved method of reducing the concentration of carbonyl sulfide in a hydrocarbon gas containing carbonyl sulfide, which method comprises (a) feeding the hydrocarbon gas containing carbonyl sulfide to a hydrolysis section to contact the hydrocarbon gas with hot aqueous absorbent to heat the hydrocarbon gas to form hydrolysis section effluent absorbent and hydrolysis section effluent gas containing carbon dioxide and hydrogen sulfide and having a lower concentration of carbonyl sulfide than the hydrocarbon gas; (b) withdrawing and cooling the hydrolysis section effluent absorbent to form a cool aqueous absorbent; (c) cooling the hydrolysis section effluent gas in a cooling section by contacting the hydrolysis section effluent gas with the cool aqueous absorbent to form warm aqueous absorbent and a cooling section effluent gas containing hydrogen sulfide and carbon dioxide; (d) heating the warm aqueous absorbent to form hot aqueous absorbent; (e) feeding the hot aqueous absorbent to the hydrolysis section; and, (f) recovering the cooling section effluent gas as product and an apparatus for treating hydrocarbon gas.
摘要翻译：一种降低含硫羰基硫化物的烃气体中羰基硫化物浓度的改进方法，该方法包括（a）将含有羰基硫化物的烃气体进料到水解部分，以使烃气与热水吸收剂接触以将烃气体加热至形成水解段废水和水解段，含有二氧化碳和硫化氢的排放气体，其碳氢化合物浓度低于烃气; （b）取出并冷却水解段流出物吸收剂以形成冷的含水吸收剂; （c）通过使水解部分流出气体与冷的含水吸收剂接触来冷却冷却部分中的水解部分流出气体，以形成温水性吸收剂和含有硫化氢和二氧化碳的冷却段流出气体; （d）加热温热的含水吸收剂以形成热水性吸收剂; （e）将热水性吸收剂供给水解部分; 和（f）回收作为产物的冷却段流出气体和用于处理烃气体的装置。

88. 发明授权

US4923688A Wet scrubber process for removing total reduced sulfur compounds from industrial gases 失效
标题翻译：用于从工业气体中除去总还原硫化合物的湿式洗涤器工艺
公开(公告)号：US4923688A
公开(公告)日：1990-05-08
申请号：US799494
申请日：1985-11-19
申请人： Joseph Iannicelli
发明人： Joseph Iannicelli
IPC分类号： B01D53/48 , B01D53/52
CPC分类号： B01D53/485 , B01D53/48 , B01D53/52
摘要： A wet scrubber process for removing Total Reduced Sulfur compounds and non-magnetic entrained particulates from an industrial gas is described which employs an aqueous absorbent slurry containing manganese dioxide absorbent particles. Scrubbing of the industrial gas with the absorbent slurry is followed by regeneration and recirculation of the aqueous absorbent slurry and magnetic separation to recover the non-magnetic entrained particulates separate from the manganese dioxide absorbent particles which are recycled.
摘要翻译：描述了一种用于从工业气体中除去总还原硫化合物和非磁性夹带颗粒的湿式洗涤器方法，其使用含有二氧化锰吸收剂颗粒的含水吸收剂浆料。用吸收剂浆液洗涤工业气体之后，再次再循环水性吸收剂浆料并进行磁力分离，以回收与再循环的二氧化锰吸收剂颗粒分离的非磁性夹带颗粒。

89. 发明授权

US4844874A Method and means for controlling mist scrubber operation 失效
标题翻译：用于控制雾洗涤器操作的方法和装置
公开(公告)号：US4844874A
公开(公告)日：1989-07-04
申请号：US119534
申请日：1987-11-12
申请人： Egbert deVries
发明人： Egbert deVries
IPC分类号： B01D47/05 , B01D53/34 , B01D53/48 , B01D53/72
CPC分类号： B01D53/485 , B01D47/05 , B01D53/34 , B01D53/72
摘要： A control system is provided for a mist scrubbing process in which a gas containing odorous and acidic contaminants is cocurrently contacted in a reaction chamber with tiny droplets of an aqueous reagent to react with and destroy the contaminants. The reagent contains an oxidizing agent and a base and the process is controlled by measuring a property, typically pH, of spent spray liquid settling at the bottom of the chamber. That measurement is used to meter the flow rate of base into the system while at the same time the concentration of an acidic contaminant in the scrubbed gas stream leaving the reaction chamber is measured and that measurement is used to meter the injection rate of an oxidizing agent into the system.
摘要翻译：提供了一种用于雾气洗涤过程的控制系统，其中含有恶臭和酸性污染物的气体在反应室中与微量的水性试剂微滴并流接触以与污染物反应并破坏污染物。试剂含有氧化剂和碱，并且通过测量在室底部沉降的废喷雾液体的性质（通常为pH）来控制该方法。该测量用于测量基底进入系统的流速，同时测量离开反应室的洗涤气流中的酸性污染物的浓度，并且测量用于测量氧化剂的注射速率进入系统。

90. 发明授权

US4808341A Process for the separation of mercaptans contained in gas 失效
标题翻译：用于分离气体中所含的硫醇的方法
公开(公告)号：US4808341A
公开(公告)日：1989-02-28
申请号：US557112
申请日：1983-12-01
申请人： Guy Desgranchamps
发明人： Guy Desgranchamps
IPC分类号： C10L3/10 , B01D53/14 , B01D53/48 , C07C7/11 , C07C139/00
CPC分类号： B01D53/1493 , C07C7/11
摘要： A process for the separation of mercaptans from gases, and especially from natural gas by absorption in a hydrocarbon oil and regeneration of the oil by oxidation of the mercaptans to sulfonic acids. The oxidation can be carried out at the absorption temperature and pressure by means of an oxidant in an aqueous medium. The regenerated oil is recycled after separation from the aqueous phase containing the sulfonic acids.
摘要翻译：一种从气体中分离硫醇的方法，特别是通过在烃油中的吸收分离天然气，并通过将硫醇氧化成磺酸来再生油。氧化可以在吸收温度和压力下通过氧化剂在水性介质中进行。从含有磺酸的水相分离后再生再生油。

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