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    • 81. 发明授权
    • Enhancing the strength, moisture resistance, and fire-resistance of
wood, timber, lumber, similar plant-derived construction and building
materials, and other cellulosic materials
    • 提高木材,木材,木材,类似植物来源的建筑和建筑材料以及其他纤维素材料的强度,耐湿性和耐火性
    • US6146766A
    • 2000-11-14
    • US44909
    • 1998-03-20
    • Karen Marie SlimakRobert Andrew Slimak
    • Karen Marie SlimakRobert Andrew Slimak
    • B27K3/08B27K3/15D06M11/22D06M11/45D06M11/71D06M11/79D06M11/82D06M11/84D21H21/34B05D3/04B05D1/18B32B9/04
    • B27K5/001B27K3/08B27K3/15C08L97/02D06M11/22D06M11/45D06M11/71D06M11/79D06M11/82D06M11/84D21H21/34B27K5/0055C08L83/02D06M2200/10D06M2200/12D06M2200/30Y10T428/31989
    • A sodium silicate polymerization method was used to incorporate sodium silicate and/or other water soluble inorganic fire retardants into an insoluble matrix. By using a vacuum/pressure technique, a water soluble sodium silicate/borate mixture was forced into the interior of various cellulosic materials, then was heat polymerized into an insoluble fire retardant matrix. This produced a dual action fire retardant material also with the following properties: moisture resistant, weather proof, and improved strength. Water insoluble forms of sodium silicate and borates have not been possible until now. This process and testing was then repeated with six other water soluble fire retardant combinations, making them similarly water insoluble. The process was used to incorporate water soluble substances into the intercellular structures of cotton fibers, polymerized to the insoluble form in the interior, thus becoming trapped inside the fibers, producing weavable fibers, that were flexible, very strong and highly fire retardant. Because some of the best fire retardants are water soluble inorganic compounds, from both fire retardant and environmental considerations, until now, the problem of water solubility has greatly restricted the widespread use of the water soluble inorganic fire retardants. The present invention provides a very promising approach for solving this problem while providing the added properties of increased strength. It was further found that chemicals and substances could be forced to penetrate cellular interiors, and further that reactions could be caused to occur within the cells by the choice of materials, chemicals, and conditions of the infusion process.
    • 使用硅酸钠聚合方法将硅酸钠和/或其它水溶性无机阻燃剂掺入不溶性基质中。 通过使用真空/压力技术,将水溶性硅酸钠/硼酸盐混合物强制进入各种纤维素材料的内部,然后被热聚合成不溶性阻燃基质。 这产生了具有以下特性的双作用阻燃材料:防潮,防风雨,强度提高。 到目前为止,水不溶性的硅酸钠和硼酸盐形式是不可能的。 然后用六种其他水溶性阻燃剂组合重复该方法和测试,使它们类似地不溶于水。 该方法用于将水溶性物质引入棉纤维的细胞间结构中,在内部聚合成不溶性形式,从而被捕获在纤维内部,产生柔韧的,非常坚固和高度阻燃的可生产的纤维。 因为一些最好的阻燃剂是水溶性无机化合物,从阻燃和环境两方面考虑,到目前为止,水溶性的问题极大地限制了水溶性无机阻燃剂的广泛应用。 本发明提供了一种非常有希望的方法来解决这个问题,同时提供增加强度的附加特性。 进一步发现,化学物质和物质可能被迫穿透细胞内部,并且进一步可以通过选择材料,化学品和输注过程的条件在细胞内发生反应。
    • 82. 发明授权
    • Process and product for rendering a substance flame resistant
    • 使物质具有阻燃性的工艺和产品
    • US6066198A
    • 2000-05-23
    • US345553
    • 1999-06-30
    • Ricardo Cuevas B.
    • Ricardo Cuevas B.
    • C09D5/18D06M11/56D06M11/70D06M11/72D06M11/76D06M11/82D06M15/263D06M15/693D21H21/34
    • D06M15/263C09D5/18D06M11/56D06M11/70D06M11/72D06M11/76D06M11/82D06M15/693D21H21/34D06M2200/30
    • A process and product for increasing the flame resistance and thermal insolation properties of chemically treated substances, in some cases providing the treated substance with flame resistance at temperatures higher than 1800.degree. C. (direct fire), with no limit to the time of exposure. A number of embodiments of flame resistant compositions are discussed herein but all embodiments include a mixture containing water, inorganic acids, ammonium salts, sodium carbonate and pyrophosphate and, in some instances other constituents. The disclosed process treats substances to prevent the generation of any flames. The substances that have successfully been tested with the disclosed process include cloth (natural and synthetic), rugs and carpets, wood, cardboard, and paper. However, it is believed that this process can be applied to an unlimited number of flammable cellulose substances. With respect to the treatment of cloth, another advantage asserted for the disclosed process is that the texture and colors of the treated cloth are minimally affected, if at all. The cloth will not look or feel hard, thick or tough. Furthermore, the chemical treatment of the cloth will last through six months of domestic washing. A further application of the disclosed invention is as a coating on foam, particularly polyurethane foam and laminated foam. Applying the disclosed invention to foam material results in a resistance to all fire, not just an impedance to the flame for a limited period of time as known in the prior art. An even further application of the disclosed invention is as an additive to paint, resulting in an increase in the paint's tolerance to fire. This increase in thermal resistance would necessarily be transferred to any articles coated with said paint.
    • 一种用于提高化学处理物质的阻燃性和热绝缘性能的方法和产品,在某些情况下,在高于1800℃的温度(直接燃烧)下使处理物质具有阻燃性,而且暴露时间没有限制。 本文讨论了阻燃组合物的许多实施方案,但是所有实施方案包括含有水,无机酸,铵盐,碳酸钠和焦磷酸盐以及在某些情况下其它组分的混合物。 所公开的方法处理物质以防止产生任何火焰。 已经通过公开的方法成功测试的物质包括布(天然和合成的),地毯和地毯,木材,纸板和纸。 然而,相信该方法可以应用于无限数量的易燃纤维素物质。 关于布的处理,所公开的方法所证明的另一个优点是,如果根本没有影响处理过的布的质地和颜色。 布不会看起来或感觉很硬,厚或硬。 此外,布的化学处理将持续六个月的家庭洗涤。 所公开的本发明的另一个应用是泡沫上的涂层,特别是聚氨酯泡沫和层压泡沫。 将所公开的发明应用于泡沫材料导致对所有火焰的抵抗力,而不仅仅是在现有技术中已知的有限时间段内对火焰的阻抗。 所公开的发明的进一步应用是作为涂料的添加剂,导致涂料耐火性的增加。 这种耐热性的增加必然会转移到涂有所述涂料的任何物品上。
    • 83. 发明授权
    • Fire retarding composition and a method for impregnation of a
combustible material
    • 阻燃组合物和浸渍可燃材料的方法
    • US06042639A
    • 2000-03-28
    • US117698
    • 1998-08-04
    • Arve Valso Egil Kleven
    • Arve Valso Egil Kleven
    • B27K3/52C09K21/10D06M11/71D06M11/72D06M13/453D21H21/34D06M11/70D06M13/322D21H17/07
    • D21H21/34C09K21/10D06M11/71D06M11/72D06M13/453B27K2240/30B27K3/08B27K3/166B27K3/52B27K5/04Y10S428/921
    • Fire retarding and smoke inhibiting aqueous composition and a method for a one-step impregnation of aqueous-absorbable--and normally inflammable materials, such as wood, paper and textiles, said composition comprising ammoniumphosphates, phosphoric acid, water soluble metal salts with ability to form water insoluble salts with phosphate ions and/or ammoniumphosphate ions, and other optional additives.The composition comprises in combination:0.5-90% by weight monoammoniumphosphate and/or diammoniumphosphate,0.1-30% water-soluble metal salts with ability to form water insoluble salts with phosphate ions and/or ammoniumphosphate ions,1-20% by weight acid especially phosphoric acid (85%),1-15 % by weight dicyandiamide, andoptionally up to 5% by weight additivesin a total concentration of from 1 to 50% by weight with respect to the total weight of the aqueous solution, whereby phosphoric acid and dicyandiamide are present in the form of the reaction product guanylureaphosphate.
    • PCT No.PCT / NO97 / 00319 Sec。 371日期:1998年10月19日 102(e)1998年10月19日PCT 1997年12月1日PCT PCT。 出版物WO98 / 24604 日期1998年6月11日防火和烟雾抑制水性组合物和一步浸渍吸水性和通常易燃的材料如木材,纸和纺织品的方法,所述组合物包含磷酸铵,磷酸,水溶性金属 具有与磷酸根离子和/或磷酸铵离子形成水不溶性盐的能力的盐以及其它任选的添加剂。 该组合物组合包括:0.5-90重量%的磷酸二氢铵和/或磷酸氢二铵,0.1-30%的具有与磷酸根离子和/或磷酸铵离子形成水不溶性盐的水溶性金属盐,1-20重量%的酸 特别是相对于水溶液的总重量,磷酸(85%),1-15重量%的双氰胺和任选的至多5重量%的总浓度为1至50重量%的添加剂,其中磷酸 酸和双氰胺以反应产物鸟嘌呤磷酸盐的形式存在。
    • 84. 发明授权
    • Suspension for the solvent-free production of silicone resin-bonded
papers based on sheet silicates
    • 悬浮液用于无硅胶树脂粘合纸的无溶剂生产
    • US6017995A
    • 2000-01-25
    • US73910
    • 1998-05-07
    • Guenter BeuschelHolger Rautschek
    • Guenter BeuschelHolger Rautschek
    • D21H13/36D21H13/44D21H17/13D21H17/59D21H21/34D21H23/04C08L83/00
    • D21H13/44D21H17/13D21H17/59D21H23/04
    • A suspension for the solvent-free production of silicone resin-bonded papers based on sheet silicates, which consists of:(a) 100 parts by weight of a sheet silicate,(b) 100 to 10,000 parts by weight of water,(c) 0.1 to 5 parts by weight of at least one silane of formula (I):(R'O).sub.a SiR.sub.4-a (I) in which R denotes substituted or unsubstituted hydrocarbon radicals having 1 to 20 carbon atoms and R' denotes C.sub.1-10 -alkyl, aryl, alkylaryl or hydrogen and a assumes a value from 1 to 3, and/or the partial hydrolysis product thereof,(d) 1 to 50 parts by weight of a pulverulent silicone resin of formula (II):(R'O).sub.b SiR.sub.C O.sub.(4-b-c)/2 (II) in which R and R.sup.1 have the abovementioned meaning and b assumes a value from 0 to 0.5 and c a value from 0.7 to 1.3, with the proviso that at least 5 parts by weight of the silicone resin of formula (II) are used per part by weight of the compound of formula (I),(e) 0.01 to 20 parts by weight of a compound catalyzing the hydrolysis and/or condensation of the compounds of formulae (I) and/or (II) and(f) optionally further known additives.
    • 一种用于无溶剂生产基于片状硅酸盐的有机硅树脂粘合纸的悬浮液,其由以下组成:(a)100重量份的片状硅酸盐,(b)100至10,000重量份的水,(c) 0.1至5重量份的至少一种式(I)的硅烷:(R'O)aSiR 4-a(I)其中R表示取代或未取代的具有1至20个碳原子的烃基,R'表示C1-10 - 烷基,芳基,烷基芳基或氢,并且其值为1至3,和/或其部分水解产物,(d)1至50重量份的式(II)的粉状有机硅树脂:(R' O)bSiRCO(4-bc)/ 2(II),其中R和R 1具有上述含义,b表示0至0.5的值,ca值为0.7至1.3,条件是至少5重量份 式(II)的有机硅树脂按每重量份式(I)化合物使用,(e)0.01至20重量份催化水解和/或冷凝的化合物 式(I)和/或(II)和(f)任选的另外已知的添加剂。
    • 87. 发明授权
    • Method for producing cellulose insulation materials using liquid fire
retardant compositions
    • 使用液体阻燃剂组合物生产纤维素绝缘材料的方法
    • US5534301A
    • 1996-07-09
    • US438378
    • 1995-05-10
    • Thomas C. Shutt
    • Thomas C. Shutt
    • D21H21/34D21H23/50B05D3/02B05D3/04
    • D21H21/34D21H23/50Y10S428/921
    • A method for producing fire-resistant cellulose insulation materials using liquid fire retardants. Cellulose materials (e.g. paper) are initially shredded into multiple pieces which are sprayed with a mist containing liquid fire retardants. The sprayed paper is then subjected to a delay period before further processing to ensure diffusion of the fire retardants into the paper. The paper is then passed into a drying chamber in combination with a stream of heated air. The air is preferably introduced into the chamber in a non-parallel, angular flow path relative to the longitudinal axis of the chamber. To completely dry the paper, movement of the paper and heated air through the chamber is periodically interrupted so that the paper is completely dried by the air. Interruption may be achieved by providing moving baffle members within the chamber. As a result, a dried cellulose insulation product is manufactured.
    • 一种使用液体阻燃剂生产耐火纤维素绝缘材料的方法。 纤维素材料(例如纸)最初被切碎成多个片,其被喷雾含有液体阻燃剂的雾。 然后在进一步加工之前对喷涂纸进行延迟,以确保阻燃剂扩散到纸中。 然后将纸张与加热空气流组合进入干燥室。 空气优选地以相对于室的纵向轴线的非平行的角度流动路径被引入室中。 为了完全干燥纸张,纸张和加热的空气通过室的移动被周期性地中断,使得纸被空气完全干燥。 可以通过在室内提供移动的挡板构件来实现中断。 结果,制造干燥的纤维素绝缘产品。
    • 88. 发明授权
    • Wallpaper
    • 墙纸
    • US5316840A
    • 1994-05-31
    • US907621
    • 1992-07-02
    • Kouji KuboShigeichi Kobayashi
    • Kouji KuboShigeichi Kobayashi
    • B32B27/10C08K3/22D21H19/22D21H19/58D21H21/34D21H27/20B32B9/00
    • D21H27/20B32B27/10C08K3/22D21H19/22D21H19/58D21H21/34Y10T428/249987Y10T428/31902Y10T428/31993
    • Wallpaper comprising flame retardant paper having laminated thereon an expanded sheet is disclosed, in which the expanded sheet is obtained by expanding at an expansion ratio of 1.5 or more a resin composition containing (A) 100 parts by weight of an ethylene-.alpha.-olefin copolymer having a melt flow rate of from 0.2 to 50 g/10 min, a density of not more than 0.91 g/cm.sup.3, and a maximum melting peak temperature of 100.degree. C. or higher and a heat of fusion at 100.degree. C. or higher of 10 J/g or more as measured with a differential scanning calorimeter and (B) 60 parts by weight or more of magnesium hydroxide or a mixture of magnesium hydroxide and aluminum hydroxide at a weight ratio of from 100/0 to 20/80. The wallpaper has high safety, is free from bleeding of a plasticizer, gives off no offensive odor, and satisfies the requirements of 2nd class (semi-noncombustible) of fireproof wall coverings.
    • 公开了其中层压有发泡片材的阻燃纸的壁纸,其中通过以1.5重量%的膨胀比膨胀获得发泡片材,该树脂组合物含有(A)100重量份的乙烯-α-烯烃共聚物 熔体流动速率为0.2〜50g / 10min,密度不大于0.91g / cm 3,最大熔融峰温度为100℃以上,熔融热为100℃, 用差示扫描量热计测定为10J / g以上,(B)60重量份以上的氢氧化镁或氢氧化镁与氢氧化铝的混合物,重量比为100/0〜20/80 。 壁纸安全性高,不含增塑剂渗色,不发臭,满足二级(半不燃)防火墙体的要求。