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    • 81. 发明申请
    • BLENDED FLUOROPOLYMER COMPOSITIONS
    • 混合氟聚合物组合物
    • US20170066914A1
    • 2017-03-09
    • US15211453
    • 2016-07-15
    • WHITFORD CORPORATION
    • Leonard W. HarveyMichael CoatesJulie K. Wright
    • C08L27/18C09D127/18C08J3/00C09D5/03
    • C08L27/18C08J3/005C08J3/12C08J2327/18C08L27/12C08L27/24C08L29/10C08L2201/50C08L2205/02C08L2205/025C09D5/03C09D127/12C09D127/18C09D129/10Y10T428/2982C08L2666/04
    • Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (□m), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processable fluoropolymer (MPF), such as methylfluoroalkoxy (MFA), fluorinated ethylene propylene (FEP), or perfluoroalkoxy (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (□m). Blending of the dispersions facilitates interaction of the LPTFE and MPF on a submicron level to facilitate intimate blending such that, when the blended fluoropolymer composition is dried, a crystal structure representing a true alloy of the fluoropolymers is formed, having melt characteristics that differ from those of the individual fluoropolymers. The blended fluoropolymer composition may be used to provide a coating having improved impermeability, stain resistance, abrasion resistance, smoothness, and higher contact angles.
    • 提供混合的含氟聚合物组合物。 在一个实施方案中,将第一含氟聚合物的液体分散体与第二含氟聚合物的液体分散体共混。 第一含氟聚合物可以是聚四氟乙烯(PTFE),例如已经通过分散体或乳液聚合方法聚合并且未被聚集,照射或热降解的低分子量PTFE(LPTFE)。 LPTFE可以是水分散体的形式,其平均粒度小于1.0微米(□m),LPTFE的第一熔融温度(Tm)为332℃或更低。 第二含氟聚合物可以是可熔融加工的含氟聚合物(MPF),例如甲基氟代烷氧基(MFA),氟化乙烯丙烯(FEP)或全氟烷氧基(PFA),例如以水分散体的形式,并且具有平均粒径 小于1.0微米(□m)。 分散体的混合促进了LPTFE和MPF在亚微米级的相互作用,以促进紧密共混,使得当混合的含氟聚合物组合物被干燥时,形成表示含氟聚合物的真正合金的晶体结构,其熔体特性与那些 的各种含氟聚合物。 混合的含氟聚合物组合物可用于提供具有改进的不渗透性,耐污性,耐磨性,光滑度和更高接触角的涂层。
    • 83. 发明申请
    • Heat-Shrinkable Tube Having Tearability
    • 具有可撕裂性的热收缩管
    • US20170058115A1
    • 2017-03-02
    • US15228129
    • 2016-08-04
    • Junkosha Inc.
    • Masahiro SuzukiKohei YuriTomoyo Okubo
    • C08L27/18
    • C08L27/18A61L29/041A61L29/049A61M25/00C08L2205/025C08L2207/02C08L2207/04C08L27/12
    • Provided is a heat-shrinkable tube having tearability, which is made of a fluororesin, particularly, a tube having excellent tear straightness and high heat-shrinkability at low temperature. The tube is a heat-shrinkable tube having tearability, which includes, as a base resin, a copolymer including at least tetrafluoroethylene and hexafluoropropylene as constituent monomers, and as a resin other than the base resin, a copolymer including at least tetrafluoroethylene and hexafluoropropylene as constituent monomers, in which a thickness of an entanglement unit of a polymer observed at a cross-section in a longitudinal direction of the tube is 9 μm less, and has excellent tear straightness and high heat-shrinkability.
    • 提供一种具有可撕裂性的热收缩管,其由氟树脂制成,特别是在低温下具有优异的撕裂直线度和高热收缩性的管。 管是具有可撕裂性的热收缩管,其包括作为基础树脂的包含至少四氟乙烯和六氟丙烯作为构成单体的共聚物,作为除基础树脂以外的树脂,包含至少四氟乙烯和六氟丙烯的共聚物作为 在管的长度方向的截面观察到的聚合物的缠结单位的厚度小的构成单体,具有优异的撕裂直线性和高的热收缩性。
    • 84. 发明授权
    • Fluororubber composition
    • 氟橡胶组成
    • US09441101B2
    • 2016-09-13
    • US14097701
    • 2013-12-05
    • NOK Corporation
    • Atsushi Yokota
    • C08L27/14C08L27/18C08L27/20C08L27/16G11B25/04C08K3/22
    • C08L27/20C08K3/22C08K3/26C08K5/13C08K2003/222C08L27/16C08L27/18G11B25/043
    • Provided is a fluororubber composition which does not deteriorate workability during roll kneading, does not cause foaming during crosslinking and molding, and is capable of giving a crosslinked molded article which exhibits desired hardness and sealing property without using a reinforcing inorganic filler such as carbon black and silica. The fluororubber composition includes, relative to 100 parts by weight of a vinylidene fluoride-copolymerized, fluorine-containing elastomer copolymer having a glass transition temperature and a melting point, no reinforcing inorganic filler, 5 to 100 parts by weight of a PTFE filler, 0.5 to 10 parts by weight of a polyol crosslinking agent, 1 to 15 parts by weight of magnesium oxide, and 0.1 to 2 parts by weight of hydrotalcite. Preferably, 0.1 to 10 parts by weight of a quaternary onium salt crosslinking accelerator is further included.
    • 本发明提供一种氟橡胶组合物,其不会降低辊捏合时的加工性,在交联成型时不会发泡,并且能够得到具有所需硬度和密封性的交联成型体,而不使用增强无机填料如炭黑和 二氧化硅。 氟橡胶组合物相对于100重量份具有玻璃化转变温度和熔点的偏二氟乙烯共聚的含氟弹性体共聚物,不含增强无机填料,5〜100重量份PTFE填料,0.5重量份 至10重量份的多元醇交联剂,1至15重量份的氧化镁和0.1至2重量份的水滑石。 进一步包括0.1至10重量份的季铵盐交联促进剂。