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    • 88. 发明申请
    • NOVEL METHOD FOR PREPARING HEAT-THICKENING POLYMERS AND NOVEL COMB COPOLYMERS
    • 制备加热聚合物和新型共聚物的新方法
    • US20150299365A1
    • 2015-10-22
    • US14647455
    • 2013-11-26
    • SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC
    • Paul MALLOOlivier BRAUN
    • C08F265/10
    • C08F265/10C08F2400/02
    • Method for preparing a comb copolymer, includes sequentially: (a) reacting a compound of formula (II): CH2═C(R2)—C(═O)—N(R3)(R4) (II), with a chain-limiting compound of formula (IIIa): HS—R1—NH2 (IIIa) or of formula (IIIb): HS—R1—C(═O)—OH (IIIb), to obtain a poly(N-alkyl acrylamide) or poly(N,N-dialkyl acrylamide) telomer, of formula (Ia): H2N—R1—S—{CH2—C(R2)[C(═O)N(R3)(R4)]-}n-H (Ia) or of formula (Ib): HO—C(═O)—R1—S—{CH2—C(R2)[C(⊚O)N(R3)(R4)]-}n-H (Ib) formula (IIIa) or (IIIb) where n represents a whole number ≧2 and ≦100; (b) isolating and/or drying the obtained telomer; (c) reacting the telomer of formula (Ia) or of formula (Ib) in tert-butanol with glycidyl methacrylate (IV) to obtain a solution of the macromonomer of formula (Va): CH2═C(R5)-C(═O)—NH—R1—Z—{CH2—C(R2)[C(═O)N(R3)(R4)]-}n-H (Va) or of formula (Vb); CH2═C(R5)-C(═O)—O—(C═O)-R1—Z—{CH2—C(R2)[C(═O)N(R3) (R4)]-}n-H (Vb); (d) isolating and/or drying the obtained telomer; (e) copolymerizing the macromonomer of formula (Va) or of formula (Vb) in tert-butanol with the ammonium salt of 2-acrylamido-2-methyl-propanesulphonic acid, and, if applicable, with the optional monomer or monomers in the desired molar proportions.
    • 制备梳状共聚物的方法包括:(a)使式(II)化合物:CH 2 = C(R 2)-C(= O)-N(R 3)(R 4)(II) 式(IIIa)化合物:HS-R1-NH2(Ⅲa)或式(Ⅲb):HS-R1-C(= O)-OH(Ⅲb),得到聚(N-烷基丙烯酰胺)或聚 (Ia)的(N,N-二烷基丙烯酰胺)调聚物:H 2 N-R 1 -S- {CH 2 -C(R 2)[C(= O)N(R 3)(R 4)] - 式(Ib)的化合物:HO-C(= O)-R1-S- {CH2-C(R2)[C(◎O)N(R3)(R4)] - } nH (IIIb)其中n表示整数≥2且≦̸ 100; (b)分离和/或干燥获得的调聚物; (c)使式(Ia)或式(Ib)的调聚物在叔丁醇中与甲基丙烯酸缩水甘油酯(IV)反应,得到式(Va)的大分子单体的溶液:CH2 = C(R5)-C(= O)-NH-R1-Z- {CH2-C(R2)[C(= O)N(R3)(R4)] - } nH(Va)或式(Vb) CH2 = C(R5)-C(= O)-O-(C = O)-R1-Z- {CH2-C(R2)[C(= O)N(R3)(R4)] - } nH Vb); (d)分离和/或干燥获得的调聚物; (e)使式(Va)或式(Vb)的大分子单体在叔丁醇中与2-丙烯酰胺基-2-甲基 - 丙磺酸的铵盐和(如果适用)与任选的单体或单体在 所需的摩尔比例。