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    • 81. 发明授权
    • Ion exchangers
    • 离子交换剂
    • US5647987A
    • 1997-07-15
    • US624478
    • 1996-04-03
    • Egbert MullerRoland GensertPeter Poguntke
    • Egbert MullerRoland GensertPeter Poguntke
    • G01N30/02B01D15/04B01D15/08B01J20/285B01J20/32B01J39/26B01J41/12C08F220/00C08F220/10C08F220/28C08F220/34C08F220/38C08F291/00C08F291/08G01N30/34G01N30/74G01N30/88
    • B01J20/3278B01D15/361B01J20/327B01J39/26
    • The invention relates to separation materials for ion exchange chromatography which are based on hydroxyl-containing base supports on whose surfaces polymers are covalently bonded, characterized in thata) the base support contains aliphatic hydroxyl groups,b) the covalently bonded polymers are bonded to the base support via a terminal monomer unit,c) the polymers contain monomer units of both the formula II and the formula III,d) the monomer units are linked linearly, ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another are H or CH.sub.3,R.sup.4 is H, C.sub.1 -C.sub.5 -alkyl or C.sub.6 -C.sub.12 -aryl,n is an integer between 1 and 5,one radical X is OH and the other radical X is NR.sup.5 R.sup.6, N.sup.+ R.sup.5 R.sup.6 R.sup.7 or SO.sub.3 H, andR.sup.5, R.sup.6 and R.sup.7 independently of one another are C.sub.1 -C.sub.4 -alkyl, it also being possible for one or both radicals R.sup.5 and/or R.sup.6 to be H.
    • PCT No.PCT / EP94 / 03168 Sec。 371日期:1996年4月3日 102(e)日期1996年4月3日PCT 1994年9月22日PCT公布。 出版物WO95 / 09695 日期1995年04月13日本发明涉及用于离子交换层析的分离材料,其基于含羟基的基础载体,其表面聚合物共价键合,其特征在于a)所述基体载体含有脂族羟基,b)共价键合 聚合物通过末端单体单元结合到基础载体上,c)聚合物含有式II和式III的单体单元,d)单体单元线性连接,其中R 1 ,R 2和R 3彼此独立地是H或CH 3,R 4是H,C 1 -C 5 - 烷基或C 6 -C 12 - 芳基,n是1和5之间的整数,一个基团X是OH,另一个基团X是NR 5 R 6 ,N + R5R6R7或SO3H,R5,R6和R7彼此独立地为C1-C4烷基,也可以是基团R5和/或R6中的一个或两个为H.
    • 83. 发明授权
    • Apparatus for treating a fluid in an ion exchange process
    • 用于在离子交换过程中处理流体的装置
    • US5626750A
    • 1997-05-06
    • US507208
    • 1995-07-26
    • Alan F. Chinn
    • Alan F. Chinn
    • B01D15/04B01J47/02B01D24/02B01D24/12B01D24/14B01D24/46
    • B01J47/022
    • An apparatus for treating a fluid to remove at least part of a component or components from the fluid in a reciprocating flow ion exchange system. The apparatus includes a vessel having a central holding chamber that is enclosed at each end by an end cap. A packed bed of ion exchange particles is held within the central holding chamber through the use of upper and lower retaining means so that a particle free cavity is created above and below the particle bed. The flow of fluid is distributed substantially evenly across the end of the particle bed by the pressure drop through the bed when one of the particle free cavities is filled with pressurized fluid.
    • 一种用于处理流体以在往复流动离子交换系统中从流体中除去至少部分组分的装置。 该装置包括具有中央保持室的容器,该中央保持室在每个端部处被端盖封闭。 通过使用上下保持装置将离子交换颗粒的填充床保持在中心保持室内,使得在颗粒床的上方和下方产生无颗粒的空腔。 当一个无颗粒的空腔充满加压流体时,流体的流动基本上均匀地分布在颗粒床的端部,通过床的压降。
    • 84. 发明授权
    • Method for sludge conditioning
    • 污泥调理方法
    • US5614458A
    • 1997-03-25
    • US497510
    • 1995-06-30
    • John L. WebbW. William CoeRobert D. KilgoreShitalprasad N. Patil
    • John L. WebbW. William CoeRobert D. KilgoreShitalprasad N. Patil
    • C02F1/68C09K3/32B01D15/04B01J39/00C02F1/28C02F1/42
    • C02F1/681C09K3/32Y10S210/92
    • A method for conditioning sludge is disclosed which includes adding a treatment material to the sludge, the treatment material including pieces of cellulose with a hydrophobic agent applied thereto. A method for conditioning sludge is disclosed which includes adding a treatment material to the sludge, and the treatment material including pieces of cellulose with wax applied thereto, the pieces of cellulose ranging in size between one-eighth inch and seven-sixteenths inch in a largest dimension and having about 0.5% to about 3% wax by weight, and at least ninety percent of surface area of the pieces of cellulose covered with wax. A method for conditioning sludge is disclosed which includes forming a slurry of sludge and pieces of cellulose treated with a hydrophobic agent, introducing the slurry into a sludge feed stream producing a secondary stream for feeding into sludge dewatering apparatus, and feeding the secondary stream into sludge dewatering apparatus to dewater sludge in the sludge dewatering apparatus.
    • 公开了一种调节污泥的方法,其包括向污泥中加入处理材料,处理材料包括施加有疏水剂的纤维素片。 公开了一种调节污泥的方法,其包括向污泥中加入处理材料,并且处理材料包括施加蜡的纤维素片,尺寸在八分之一英寸至七十六分之一英寸之间的纤维素片最大 并且具有约0.5重量%至约3重量%的蜡,以及用蜡覆盖的纤维素片的至少百分之九十的表面积。 公开了一种调节污泥的方法,其中包括用疏水剂处理的淤泥和纤维素浆料,将浆料引入污泥进料流中,产生用于进料到污泥脱水装置中的二次流,并将二次流送入污泥 脱水装置对污泥脱水装置中的污泥进行脱水。
    • 85. 发明授权
    • Anion-exchange membrane extractor for boric acid separation
    • 阴离子交换膜提取器用于硼酸分离
    • US5589071A
    • 1996-12-31
    • US502758
    • 1995-07-14
    • Kun-Jai LeeJong-Kil Park
    • Kun-Jai LeeJong-Kil Park
    • G21F9/12B01D61/24B01D61/28B01D63/08G21C19/307G21D1/00B01D15/04
    • B01D61/246B01D61/28B01D63/082G21C19/307
    • The present invention relates to an anion-exchange membrane extractor for boric acid separation, which is capable of separating boric acid from the radioactive liquid waste concentrated by evaporation of the radioactive liquid waste produced in the pressurized light water reactor and a method of separating boric acid from the radioactive liquid waste employing the extractor. The onion-exchange membrane extractor for boric acid separation which comprises: an upper cell being equipped with an inlet, an outlet, and fluid-injecting holes; a concentrate cell, an extract cell and a lower cell, each of which is equipped with an inlet, an outlet, fluid-injecting holes, and a supporting shelf on the upper layer; a. water-proofing means for preventing leaking-out of the concentrate and the extract, being inserted into the interface between the said cells; a transporting tube being connected to the inlets and outlets of the said cells for the transfer of the concentrate and the extract between the cells; a supporting screen being held up on the supporting shelf positioned in each of the said cells, holding up the onion-exchange membrane; and, an onion-exchange membrane being supported by the said supporting screen to extract boric acid.
    • 本发明涉及一种用于硼酸分离的阴离子交换膜提取器,其能够将硼酸与由加压轻水反应器中产生的放射性废液蒸发而浓缩的放射性废液分离,并分离硼酸 来自使用提取器的放射性废液。 用于硼酸分离的洋葱交换膜提取器,其包括:上部单元,其具有入口,出口和流体注入孔; 浓缩池,提取池和下室,每个在上层配备有入口,出口,流体注入孔和支撑架; 一个。 用于防止浓缩物和提取物的泄漏的防水装置插入所述细胞之间的界面中; 输送管连接到所述细胞的入口和出口,用于在细胞之间转移浓缩物和提取物; 支撑屏幕被保持在位于每个所述单元中的支撑架上,夹持洋葱交换膜; 以及由所述支撑丝网支撑以提取硼酸的洋葱交换膜。
    • 86. 发明授权
    • Apparatus for maintaining a stable bath for an autodeposition
composition by periodically separating particular metal ions from the
composition
    • 用于通过从组合物中周期性地分离特定金属离子来维持用于自沉积组合物的稳定浴的装置
    • US5578199A
    • 1996-11-26
    • US231075
    • 1994-11-07
    • William G. KozakJoseph C. Topping
    • William G. KozakJoseph C. Topping
    • C23C18/31B01D15/04B05D7/14C23C18/16B01J47/02B05D1/18
    • B05D7/142
    • A system automated for providing at least periodic removal of metal ions and contaminants from a chemical bath, consists of a microprocessor programmed for controlling fluid circuits of pumps and valves, for in one state of operation circulating a first predetermined quantity of the chemical bath from a first tank, through an ion exchange column, and back to the first tank; for in a second state of operation circulating deionized water from a second tank into the IEX column for displacing residual chemical bath therefrom for return to the first tank; for in a third state of operation circulating deionized water through the IEX column, and discharging the rinse water from a waste port; for in a fourth state of operation circulating regenerant acid through the ion exchange column, and discharging the used acid from a waste port; for in a fifth state of operation circulating deionized water through the IEX column for rinsing acid regenerant therefrom and discharging the same out of a waste port; and for in a sixth state of operation circulating chemical bath into the IEX column for displacing residual rinse water therefrom, and discharging the same out of the waste port, in preparation for a cycle of treatment of the chemical bath.
    • 一种自动化用于从化学浴中至少定期去除金属离子和污染物的系统由一个被编程用于控制泵和阀的流体回路的微处理器组成,在一个操作状态下,将第一预定量的化学浴从 第一罐,通过离子交换柱,并返回到第一罐; 用于在第二操作状态下将去离子水从第二罐循环到IEX柱中,用于将残留的化学浴从其中移出以返回到第一罐; 在第三种操作状态下循环去离子水通过IEX柱,并从冲洗水排出冲洗水; 用于在第四操作状态下循环再生剂酸通过离子交换柱,并将废酸从废物口排出; 在第五种操作状态下,通过IEX柱循环去离子水以从其中冲洗酸再生剂并将其从废物口排出; 并且在第六操作状态下将化学浴循环到IEX柱中以从中移出残留的漂洗水,并将其从废物口中排出,以准备化学浴的处理循环。
    • 89. 发明授权
    • Method of separating and recovering plutonium and neptunium from
plutonium- and neptunium-containing nitric acid solution
    • 从钚和含containing硝酸溶液中分离回收钚和。。的方法
    • US5476641A
    • 1995-12-19
    • US285514
    • 1994-08-04
    • Akio TodokoroYoshiyuki KiharaTakashi Okada
    • Akio TodokoroYoshiyuki KiharaTakashi Okada
    • B01D15/00B01D15/04G21C19/46G21F9/06G21F9/12C01G56/00
    • G21C19/46G21F9/06G21F9/12Y02W30/883
    • A method of separating and recovering Pu and Np from a Pu- and Np-containing nitric acid solution. The method comprises the steps of subjecting a nitric acid solution containing Pu and Np to valence adjustment by adding a reducing agent consisting of hydroxylamine nitrate and hydrazlne to said nitric acid solution so as to reduce Pu and Np in said nitric acid solution to Pu (III) and Np (IV), respectively; adjusting a nitric acid concentration of said nitric acid solution after said valence adjustment to 6 to 8 M; bringing said nitric acid solution after said nitric acid concentration adjustment into contact with a strong basic anion exchange resin so as to cause Np to be selectively adsorbed by said resin and to separate and recover Pu as a plutonium nitrate solution; and eluting said adsorbed Np (IV) by using diluted nitric acid of 1 M or below so as to recover Np as a neptunium nitrate solution. The valence adjustment step may be carried out by subjecting the Pu- and Np-containing nitric acid solution to electrolytic reduction instead of using the reducing agent.
    • 从含P和Np的硝酸溶液中分离和回收Pu和Np的方法。 该方法包括以下步骤:通过向硝酸溶液中加入由硝酸羟胺和腙组成的还原剂,使含有Pu和Np的硝酸溶液进行价态调节,以将所述硝酸溶液中的Pu和Np还原成Pu )和Np(IV); 在所述化合价调节后将所述硝酸溶液的硝酸浓度调节至6〜8M; 将硝酸浓度调节后的硝酸溶液与强碱性阴离子交换树脂接触,使Np被所述树脂选择性吸附并分离并回收Pu作为硝酸钚溶液; 并通过使用1M或更低的稀硝酸洗脱所述吸附的Np(IV),以便硝酸硝铵溶液回收Np。 化合价调节步骤可以通过使含有Pu-和Np的硝酸溶液进行电解还原来代替使用还原剂来进行。
    • 90. 发明授权
    • Method for removing a contaminant from a fluid using a chemically
impregnated and coated zeolite
    • 使用化学浸渍和涂覆的沸石从流体中除去污染物的方法
    • US5464598A
    • 1995-11-07
    • US150438
    • 1993-11-10
    • Fred Klatte
    • Fred Klatte
    • A23K1/16A23K1/175B01D15/04B01D46/00B01D53/02B01D53/88B01J8/04B01J20/18B01J20/32B01J29/40B01J37/02C01B11/02C01B17/02
    • B01J20/0222A23K20/105A23K20/142A23K20/174A23K20/30B01D46/00B01D53/02B01D53/885B01J20/04B01J20/06B01J20/186B01J20/3085B01J20/3204B01J20/3229B01J20/3236B01J20/3248B01J20/3289B01J29/40B01J37/0221B01J37/0236B01J8/04C01B11/024B01J2220/56Y10S95/902
    • A process for impregnating zeolite with a quaternary ammonium cation (QAC) and then coating the impregnated zeolite with permanganate (such as potassium permanganate), and for impregnating zeolite with permanganate and then coating the impregnated zeolite with a QAC, and coated, impregnated zeolite crystals resulting from either process. Either coating acts as a protective agent for the impregnating substance in each zeolite crystal's interior, and allows regulated time release control of the impregnating substance, thus permitting a controlled diffusion (or absorption) rate in applications in which the coated, impregnated zeolite is employed to absorb contaminants from air or water. Combinations of coated and uncoated zeolite crystals can be chosen to match specific environmental circumstances calculable by analysis of the air or water to be treated. Mixtures of coated and uncoated QAC-impregnated zeolite can be used to react with organics such as benzene, toluene, and xylene, uncoated zeolite impregnated with permanganate, and mixtures of coated and uncoated permanganate-impregnated zeolite can be used to react with hydrogen sulfide, acetone, ethylene glycols, formaldehyde, and other contaminants. Other embodiments of the invention are methods for producing zeolite crystals impregnated with manganese dioxide, and for using such manganese dioxide-impregnated crystals to absorb contaminants from fluid.
    • 用季铵阳离子(QAC)浸渍沸石的方法,然后用高锰酸盐(例如高锰酸钾)涂覆浸渍的沸石,并用高锰酸盐浸渍沸石,然后用QAC涂覆浸渍的沸石,以及涂覆浸渍的沸石晶体 由任一过程产生。 任一种涂层均作为每种沸石晶体内部的浸渍物质的保护剂,并且允许调节浸渍物质的时间释放控制,从而允许在使用涂覆的浸渍沸石的应用中受控的扩散(或吸收)速率 从空气或水中吸收污染物。 可以选择涂层和未涂层​​的沸石晶体的组合以匹配可通过分析待处理的空气或水来计算的特定环境条件。 可以使用涂覆和未涂覆的QAC浸渍的沸石的混合物与有机物如苯,甲苯和二甲苯反应,用高锰酸盐浸渍的未涂布的沸石,以及涂覆和未涂覆的高锰酸盐浸渍沸石的混合物可与硫化氢反应, 丙酮,乙二醇,甲醛等污染物。 本发明的其它实施方案是用于生产浸渍有二氧化锰的沸石晶体的方法,以及使用这种二氧化锰浸渍的晶体来吸收流体中的污染物。