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    • 84. 发明授权
    • Method for assembling an electrochemical cell
    • 组装电化学电池的方法
    • US4309817A
    • 1982-01-12
    • US145108
    • 1980-04-29
    • Franz GoebelIbsen R. Hansen
    • Franz GoebelIbsen R. Hansen
    • H01M2/26H01M4/70H01M6/14H01M4/08H01M6/00
    • H01M4/70H01M2/26H01M6/14Y10T29/49108Y10T29/49911Y10T29/4994
    • A method for assembling a primary electrochemical cell including a carbon cathode structure. The carbon cathode structure is assembled by arranging a selected number of individual annular-shaped porous carbon elements, each having an opening extending therethrough, together with an elongated, hollow, cylindrical metal current collector tube so that the carbon elements are in a stacked array and the tube is loosely disposed within and along the openings in the array of carbon elements. The current collector tube is an expandable member and is initially in a non-expanded state and loosely surrounded by the stacked array of carbon elements. A porous separator and an anode structure are then placed around the aforementioned assembly of the carbon elements and the current collector tube, and the resultant assembly, representing a battery stack, is placed within an elongated housing of an electrochemical cell. A tool is then employed to permanently expand the current collector tube outwardly so that the tube makes direct physical contact with the array of carbon elements. An electrolytic solution is placed within the cell in contact with the battery stack and the hollow opening of the tube. The electrolytic solution permeates the carbon elements directly and also by way of a large number of small holes formed in the tube, causing the porous carbon elements to be permeated with the electrolytic solution and expand outwardly. The expansion of the carbon elements causes constituent particles thereof to fill the openings in the current collector thus thereby permanently locking the carbon elements to the current collector tube.
    • 一种用于组装包括碳阴极结构的初级电化学电池的方法。 通过布置选定数量的各自具有延伸穿过其中的开口的单个环形多孔碳元素以及细长的中空圆柱形金属集流管来组装碳阴极结构,使得碳元素为堆叠阵列,并且 管松散地设置在碳元素阵列内和沿着碳元素阵列中的开口。 集流管是可扩展的构件,并且最初处于非膨胀状态并且被碳元素的堆叠排列松散地包围。 然后将多孔分离器和阳极结构放置在碳元素和集流管的上述组件周围,并且将所得组件(代表电池组)放置在电化学电池的细长壳体内。 然后使用工具将集流管向外扩张,使得管与碳元素阵列直接物理接触。 将电解液放置在电池内与电池组和管的中空开口接触。 电解液直接渗透碳元素,并且还通过形成在管中的大量小孔渗透,导致多孔碳元素被电解液渗透并向外扩张。 碳元素的膨胀导致其组成颗粒填充集电器中的开口,从而将碳元素永久地锁定到集流管。
    • 85. 发明授权
    • Battery and method for fabricating same
    • 电池及其制造方法
    • US4234667A
    • 1980-11-18
    • US16929
    • 1979-03-02
    • Douglas N. BennionSu-Chee S. Wang
    • Douglas N. BennionSu-Chee S. Wang
    • H01M4/02H01M4/04H01M4/66H01M6/14H01M6/26H01M10/39H01M6/36
    • H01M4/0454H01M10/39H01M4/0438H01M4/38H01M6/14H01M6/26H01M2004/027H01M2300/0048H01M4/661
    • A battery includes a negative electrode comprising metallic lithium (Li) in conjunction with lithium chlorate (LiClO.sub.3) electrolyte. Lithium perchlorate (LiClO.sub.4) may also be used as the electrolyte. Lithium chloride (LiCl) and lithium oxide (Li.sub.2 O), individually or together, may also be utilized with lithium chlorate or lithium perchlorate in forming the electrolyte. A positive electrode comprises a metal, such as nickel. In one form, a sheet of lithium metal is sandwiched between two sheets of nickel comprising a negative electrode, one nickel sheet being perforated to permit contact between the lithium sheet and a lithium chlorate electrolyte contained within an insulative member, the other electrode comprising a film of metallic nickel disposed upon the insulative member and in contact with the electrolyte; alternatively, a film or sheet of lithium metal may be disposed upon the insulator as a negative electrode. An additional form includes a ceramic housing comprising a solid ionic conductor and having an interior chamber containing sodium (Na) or lithium as a negative electrode; a liquid electrolyte is disposed within a recess formed by the exterior walls of the housing and a positive electrode in the form of a layer of metallic nickel disposed around the exterior walls of the housing, the electrolyte being in electrical contact with the respective electrodes. A pocket cell form comprises a liquid electrolyte disposed within a recess of a block with the negative electrode inside the recess and the positive electrode in the form of a screen at the mouth of the recess.
    • 电池包括含有金属锂(Li)与氯酸锂(LiClO 3)电解质结合的负极。 也可以使用高氯酸锂(LiClO 4)作为电解质。 单独或一起使用氯化锂(LiCl)和氧化锂(Li2O)也可用氯酸锂或高氯酸锂形成电解质。 正极包括诸如镍的金属。 在一种形式中,将一片锂金属夹在包含负极的两片镍片之间,一块镍片被穿孔以允许锂片与包含在绝缘构件内的氯酸锂电解质之间的接触,另一电极包括膜 设置在绝缘构件上并与电解质接触的金属镍; 或者,可以在绝缘体上设置锂金属片或片作为负电极。 附加形式包括:陶瓷壳体,其包含固体离子导体并具有包含钠(Na)或锂作为负极的内部室; 液体电解质设置在由壳体的外壁形成的凹部中,并且金属镍层形式的正电极设置在壳体的外壁周围,电解质与各个电极电接触。 袋形电池形式包括设置在块的凹部内的液体电解质,负极位于凹部内部,正极在凹口的口处呈屏幕形式。