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    • 88. 发明申请
    • Method for the production of block foam
    • 块状泡沫的生产方法
    • US20030144368A1
    • 2003-07-31
    • US10311394
    • 2002-12-13
    • Hans-Michael SulzbachReiner RaffelMartin Schamberg
    • C08J009/00
    • C08J9/122B29C44/348B29C44/461B29C44/60C08G18/14C08J2375/04
    • The present invention is directed to an improved process for producing block foam from polyurethane forming component wherein dissolved carbon dioxide is used as a blowing agent. The process broadly comprises a) suddenly expanding a polyurethane reactive mixture containing carbon dioxide from a pressure above the equilibrium solution pressure of the carbon dioxide to normal pressure, the liquid polyurethane reactive mixture foams with the release of dissolved carbon dioxide, b) applying the foamed mixture to a substrate and c) curing the foamed mixture to form block foam>In the improved process, i) the carbon dioxide is initially completely dissolved in the reactive mixture, or in at least one of the components, either polyol and isocyanate, at a first pressure substantially above the equilibrium solution pressure, ii) the pressure is then reduced to a value close to the equilibrium solution pressure, falling in the meantime below the equilibrium solution pressure with the release of small amounts of carbon dioxide to form a bubble microdispersion, iii) the components are mixed, if necessary, and iv) the pressure is suddenly reduced to normal pressure before the released carbon dioxide is completely redissolved. The invention is also directed to a pressure-maintaining device useful in producing polyurethane foams.
    • 本发明涉及从聚氨酯形成组分制备块状泡沫的改进方法,其中使用溶解的二氧化碳作为发泡剂。 该方法广泛地包括a)从高于二氧化碳的平衡溶液压力的压力突然膨胀含有二氧化碳的聚氨酯反应混合物至常压,液体聚氨酯反应混合物随着溶解的二氧化碳的释放而发泡,b) 混合物到基材中,c)固化发泡混合物以形成块状泡沫体>在改进的方法中,i)二氧化碳最初完全溶解在反应混合物中,或至少一种组分,多元醇和异氰酸酯, 基本上高于平衡溶液压力的第一压力,ii)然后将压力降低到接近平衡溶液压力的值,同时低于平衡溶液压力,同时释放少量二氧化碳以形成气泡微分散体 ,iii)如果需要,组分是混合的,以及iv)在th之前压力突然降低到正常压力 e释放的二氧化碳完全重新溶解。 本发明还涉及可用于生产聚氨酯泡沫的保压装置。