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    • 82. 发明授权
    • Partially crystalline block copolyester-polyamides
    • 部分结晶嵌段共聚酯 - 聚酰胺
    • US5703177A
    • 1997-12-30
    • US573058
    • 1995-12-15
    • Heinz Hoff
    • Heinz Hoff
    • C08G69/44C08G81/00
    • C08G69/44
    • This invention relates to biologically degradable, partially crystalline block copolyester-polyamides comprising at least two chemically differently structured segments of which at least one is a polyester (PES) block or a copolyester (coPES) block, preferably with a number average molecular mass of 340 to 10,000 g/mole, and at least one is a polyamide (PA) block or a copolyamide (coPA) block, preferably with a number average molecular mass of 400 to 3,000 g/mole. In addition, copolyester-amide (coPEA) blocks can be employed, preferably with a number average molecular mass of 500 to 5,000 g/mole. The invention also relates to a polycondensation process for the manufacture of these partially crystalline block copolyester-polyamides. The block copolymers described are useful for the manufacture of fibers, foils, molded articles and hot melt-type adhesives. Molded components manufactured from the copolymers in accordance with the invention are biologically degradable and are capable of being composted.
    • 本发明涉及生物可降解的部分结晶的嵌段共聚酯 - 聚酰胺,其包含至少两个化学上不同的结构化部分,其中至少一个是聚酯(PES)嵌段或共聚酯(coPES)嵌段,优选数均分子量为340 至10,000g / mol,并且至少一种是聚酰胺(PA)嵌段或共聚酰胺(coPA)嵌段,优选数均分子量为400至3,000g / mol。 此外,可以使用共聚酯 - 酰胺(coPEA)嵌段,优选数均分子量为500-5,000g / mol。 本发明还涉及用于制造这些部分结晶嵌段共聚酯 - 聚酰胺的缩聚方法。 所述的嵌段共聚物可用于制造纤维,箔,模塑制品和热熔型粘合剂。 由本发明的共聚物制成的成型部件是生物可降解的并且能够被堆肥。