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    • 83. 发明授权
    • Method for processing silver halide color photographic material
    • 卤化银彩色照相材料的处理方法
    • US4820623A
    • 1989-04-11
    • US151848
    • 1988-02-03
    • Toshio KoshimizuKeiji Mihayashi
    • Toshio KoshimizuKeiji Mihayashi
    • G03C7/26G03C7/30G03C7/38G03C7/392G03C7/44G03C1/08G03C5/24G03C7/32
    • G03C7/3012G03C7/44
    • A method for processing a silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer and containing a magenta dye forming coupler represented by formula (I) shown below and a compound represented by formula (II) shown below in the same layer is described, wherein the silver halide color photographic material is subjected to color development using a replenisher for a color developing solution, whose concentration of bromide is not more than 3.times.10.sup.-3 mol per liter and the amount of the replenisher for a color developing solution is not more than 900 ml per m.sup.2 of the silver halide color photographic material, wherein ##STR1## wherein R.sub.1 represents an aromatic group, an aliphatic group or a heterocyclic group; R.sub.2 represents a substituent; Za, Zb, Zc and Zd, which may be the same or different, each represents an unsubstituted methine group, a substituted methine group or --N.dbd.; and formula (II) is represented by(R'--COO.sup.-).sub.n M.sup.n+ (III)wherein R' represents a substituent which imparts a diffusion-resistant property to the compound represented by formula (II); M.sup.n+ represents a hydrogen ion, a metal ion or an ammonium ion; and n represents an integer from 1 to 4.According to the method of the present invention, the amount of replenisher for a color developing solution can be reduced without adverse affects on photographic properties. Further, the formation of precipitates in the color developing solution is prevented and adhesion of scum onto the photographic material does not occur.
    • 一种用于处理卤化银彩色照相材料的方法,其包括其上具有至少一个卤化银乳剂层的载体,并含有下述式(I)表示的品红色染料形成成色剂和下述式(II)表示的化合物在 描述了相同的层,其中使用用于彩色显影液的补充剂对卤化银彩色照相材料进行显色,其中溴化物的浓度不大于3×10 -3 mol /升,并且用于显色的补充剂的量 溶液不超过900ml / m 2的卤化银彩色照相材料,其中R 1表示芳族基团,脂族基团或杂环基团的化合物(I) R2表示取代基; Za,Zb,Zc和Zd可以相同或不同,各自表示未取代的次甲基,取代的次甲基或-N =; 式(II)由(R'-COO-)n Mn +(III)表示,其中R'表示赋予由式(II)表示的化合物具有扩散阻力特性的取代基。 Mn +表示氢离子,金属离子或铵离子; n表示1〜4的整数。根据本发明的方法,可以减少显色液的补充量,而不影响照相性能。 此外,防止在显色溶液中形成沉淀物,并且不会发生浮渣对照相材料的附着。
    • 85. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4628024A
    • 1986-12-09
    • US817239
    • 1986-01-09
    • Hidetoshi KobayashiKeiji MihayashiIsamu Itoh
    • Hidetoshi KobayashiKeiji MihayashiIsamu Itoh
    • G03C7/26C07C331/28C07D235/28C07D257/04C07D403/12G03C7/18G03C7/30G03C7/305G03C7/32G03C8/00G03C1/40
    • C07D257/04C07C243/00C07C331/28C07D235/28C07D403/12G03C7/30552Y10S430/156
    • A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer and a compound represented by the following general formula (I): ##STR1## wherein COUP represents a coupler residue capable of being subjected to a coupling reaction with an oxidation product of an aromatic primary amine developing agent; TIME represents a timing group which is released upon the coupling reaction and subsequently releases ##STR2## Z represents a monocyclic or condensed heterocyclic ring consisting of a nitrogen atom and a carbon atom; L represents a divalent linking group; R.sup.1 represents a hydrogen atom or an alkoxycarbonyl group; R.sup.2 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a thioacyl group or a thiocarbamoyl group; R.sup.3 represents a hydrogen atom; R.sup.2 and R.sup.3 may be bonded each other to form a hydrazone structure; a part of L and R.sup.1 may be bonded each other to form a hydrazone structure; and n represents 0 or 1.The silver halide color photographic light-sensitive material containing the compound capable of imagewise releasing a fogging agent represented by the general formula (I) is improved in stability during preservation and has a high contrast and sensitivity. A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.
    • 一种卤化银彩色照相感光材料,其包含其上具有卤化银乳剂层的支持体和由以下通式(I)表示的化合物:其中COUP表示能够经受 与芳族伯胺显影剂的氧化产物偶联反应; TIME表示在偶联反应后释放并随后释放的时基.Z表示由氮原子和碳原子组成的单环或稠合杂环; L表示二价连接基团; R1表示氢原子或烷氧基羰基; R 2表示氢原子,烷基,芳基,杂环基,酰基,磺酰基,烷氧基羰基,氨基甲酰基,氨磺酰基,硫代酰基或硫代氨基甲酰基。 R3表示氢原子; R2和R3可以相互结合形成腙结构; L和R1的一部分可以相互结合形成腙结构; 并且n表示0或1.含有能够成像释放由通式(I)表示的起雾剂的化合物的卤化银彩色照相感光材料在保存期间的稳定性提高并且具有高对比度和灵敏度。 还公开了使用卤化银彩色照相感光材料形成彩色图像的方法。
    • 88. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4474870A
    • 1984-10-02
    • US457318
    • 1983-01-11
    • Morio YagiharaKeiji MihayashiTakashi Ozawa
    • Morio YagiharaKeiji MihayashiTakashi Ozawa
    • G03C7/38C08F20/00C08F20/34C08F20/36C08F20/52C08F20/60C09B26/02G03C7/327G03C7/16G03C7/26
    • G03C7/3275
    • A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a polymer or copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; R.sub.2 represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain; R.sub.3 represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain, an unsubstituted or substituted phenylene group or an unsubstituted or substituted aralkylene group; X represents --CONH--, --NHCONH-- or --NHCOO--; Y represents --CONH-- or --COO--; Z represents --O--, --S--, --SO--, --SO.sub.2 --, --CONH-- or --COO--; Ar represents an unsubstituted or substituted phenyl group; l represents 0 or 1; m represents 0 or 1; and n represents 0 or 1.The magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs, and the silver halide color photographic light-sensitive material containing the magenta color image forming polymer coupler latex has good film strength and a reduced layer thickness and provides a stable magenta image having an improved sharpness and a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
    • 一种卤化银彩色照相感光材料,其包括其上具有卤化银乳剂层的载体,所述卤化银乳剂层含有品红色图像形成聚合物偶联剂胶乳,其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料, 是具有源自由以下通式(I)表示的单体的重复单元的聚合物或共聚物:其中R 1表示氢原子,含有1至4个碳原子的低级烷基或氯 原子; R2表示可以是直链或支链的未取代或取代的亚烷基; R3表示未取代或取代的亚烷基,其可以是直链或支链,未取代或取代的亚苯基或未取代或取代的芳亚烷基; X表示-CONH-,-NHCONH-或-NHCOO-; Y表示-CONH-或-COO-; Z表示-O - , - S - , - SO - , - SO 2 - , - CONH-或-COO-; Ar表示未取代或取代的苯基; l表示0或1; m表示0或1; 并且n表示0或1.品红色成像聚合物成色剂胶乳具有良好的成色性能,能够以高产率形成染料并且不形成不期望的污渍和雾,并且卤化银彩色照相感光 含有品红色成像聚合物偶联胶乳的材料具有良好的膜强度和降低的层厚度,并且提供了具有改善的清晰度和对光,热和湿度的良好牢度的稳定的品红色图像。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。