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81. 发明授权

US4190519A Combination process for upgrading naphtha 失效
标题翻译：石脑油升级的组合过程
公开(公告)号：US4190519A
公开(公告)日：1980-02-26
申请号：US954064
申请日：1978-10-23
申请人： Stephen J. Miller , Thomas R. Hughes
发明人： Stephen J. Miller , Thomas R. Hughes
IPC分类号： B01J29/44 , C10G59/00 , B01J29/28 , C07C15/02 , C10G37/10 , C10G39/00
CPC分类号： C10G59/00 , B01J29/44
摘要： A straight-run naphtha is fractionated at about 66.degree. C., which is just below the boiling point of methylcyclopentane. The 66.degree. C.+ fraction is reformed, and at least a portion of the reformate combined with the 66.degree. C.- fraction and reacted under aromatization conditions over a ZSM-5-type catalyst to form a C.sub.5 + product rich in aromatics. The C.sub.5 + aromaticized product and the remaining reformate can be either sent for BTX recovery or used as a high-octane component of a gasoline blending pool.
摘要翻译：直馏石脑油在约66℃下分馏，其温度低于甲基环戊烷的沸点。将66℃+馏分重整，至少部分重整产物与66℃馏分相结合，并在芳构化条件下在ZSM-5型催化剂上反应形成富含芳族化合物的C5 +产物。可以将C5 +芳族化合物和剩余的重整产物用于BTX回收或用作汽油混合池的高辛烷值组分。

82. 发明授权

US08709107B2 Biodiesels useful for improving cloud point 有权
标题翻译：生物柴油有助于改善浊点
公开(公告)号：US08709107B2
公开(公告)日：2014-04-29
申请号：US12751337
申请日：2010-03-31
申请人： Stephen J. Miller
发明人： Stephen J. Miller
IPC分类号： C10L1/02 , C10L1/18 , C10L1/188 , C10L1/19 , C10G45/02 , C11C3/00
CPC分类号： C10L1/19 , C10G45/02 , C10G2300/1014 , C10G2300/304 , C10L1/026 , C11C3/003 , Y02E50/13 , Y02P30/20
摘要： The instant invention pertains to new biodiesels which may be blended with petrodiesel. The biodiesels may comprise a fatty acid C1-C2 alkyl ester and a fatty acid branched C3-C4 alkyl ester. Blends of the novel biodiesel and petrodiesel often exhibit advantageous cloud point properties.
摘要翻译：本发明涉及可与石油纤维混合的新生物柴油。生物柴油可以包含脂肪酸C1-C2烷基酯和脂肪酸支链C 3 -C 4烷基酯。新生物柴油和石油柴油的混合物通常表现出有利的浊点性质。

83. 发明授权

US08658021B2 Multi-stage reforming process to produce high octane gasoline 有权
标题翻译：多级重整工艺生产高辛烷值汽油
公开(公告)号：US08658021B2
公开(公告)日：2014-02-25
申请号：US12845615
申请日：2010-07-28
申请人： Cong-Yan Chen , Stephen J. Miller , James N. Ziemer , Ann J. Liang
发明人： Cong-Yan Chen , Stephen J. Miller , James N. Ziemer , Ann J. Liang
IPC分类号： C10G59/02 , C10G35/085 , C10G35/24
CPC分类号： C10G59/02 , C10G35/085 , C10G35/09 , C10G35/24 , C10G2300/1044 , C10G2300/305 , C10G2300/4006 , C10G2300/4012 , C10G2400/02
摘要： The present invention relates to a multistage reforming process to produce a high octane product. A naphtha boiling range feedstock is processed in a multi-stage reforming process, in which the process involves at least 1) a penultimate stage for reforming the naphtha feedstock to produce a penultimate effluent 2) a final stage for further reforming at least a portion of the penultimate effluent 3) a regeneration step for the final stage catalyst. The severity of the penultimate stage can be increased during final stage catalyst regeneration in order to maintain the target RON of the reformate product and avoid reactor downtime.
摘要翻译：本发明涉及一种生产高辛烷值产品的多级重整方法。石脑油沸程原料在多级重整过程中进行处理，其中该方法涉及至少1）用于重整石脑油原料以产生倒数第二流出物的倒数第二阶段2）用于进一步重整至少一部分倒数第二流出物3）最终阶段催化剂的再生步骤。为了维持重整产物的目标RON，避免反应堆停机，可以在终催化剂再生期间增加倒数第二阶段的严重性。

84. 发明授权

US08449760B2 Process for improving the lubricating properties of base oils using a Fischer-Tropsch derived bottoms 有权
标题翻译：使用费 - 托衍生底物改善基础油的润滑性能的方法
公开(公告)号：US08449760B2
公开(公告)日：2013-05-28
申请号：US11285607
申请日：2005-11-21
申请人： Stephen J. Miller
发明人： Stephen J. Miller
IPC分类号： C10M101/02 , C10M105/02
CPC分类号： C10M111/04 , C10G2300/1022 , C10G2300/1062 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M111/00 , C10M169/04 , C10M2203/1006 , C10M2205/17 , C10M2205/173 , C10N2220/021 , C10N2220/022 , C10N2220/028 , C10N2230/02 , C10N2270/00 , Y10S208/95
摘要： A method for improving the lubricating properties of a distillate base oil characterized by a pour point of 0 degrees C. or less and a boiling range having the 10 percent point falling between about 625 degrees F. and about 790 degrees F. and the 90 percent point falling between about 725 degrees F. and about 950 degrees F., the method comprises blending with said distillate base oil a sufficient amount of a pour point depressing base oil blending component to reduce the pour point of the resulting base oil blend at least 3 degrees C. below the pour point of the distillate base oil, wherein the pour point depressing base oil blending component is an isomerized Fischer-Tropsch derived bottoms product having a pour point that is at least 3 degrees C. higher than the pour point of the distillate base oil.
摘要翻译：一种用于改善馏出物基油的润滑性能的方法，其特征在于倾点为0摄氏度或更低，沸点范围为10％的点落在约625华氏度至约790度之间，而90％点落在约725°F和约950°F之间，该方法包括与所述馏出物基础油混合足够量的倾点降低的基础油混合组分以将所得基础油混合物的倾点降低至少3 其中所述倾点降低基础油共混组分是异构化的费 - 托衍生的底部产物，其倾点比所述馏出物基础油的倾点高至少3℃。馏出油基础油。

85. 发明授权

US08394182B2 Crosslinked membrane and polymer for making same and method of using membrane 有权
标题翻译：用于制造相同的交联膜和聚合物以及使用膜的方法
公开(公告)号：US08394182B2
公开(公告)日：2013-03-12
申请号：US12972301
申请日：2010-12-17
申请人： William J. Koros , David Wallace , John Wind , Claudia Staudt-Bickel , Stephen J. Miller
发明人： William J. Koros , David Wallace , John Wind , Claudia Staudt-Bickel , Stephen J. Miller
IPC分类号： B01D53/22 , B01D69/08 , B01D71/40
CPC分类号： B01D53/228 , B01D65/10 , B01D67/0093 , B01D69/08 , B01D71/64 , B01D71/82 , B01D2257/504 , B01D2323/30 , Y02C10/10 , Y10S55/05
摘要： A composition of and a method of making high performance crosslinked membranes are described. The membranes have a high resistance to plasticization by use of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant membrane exhibits a high permeability of CO2 in combination with a high CO2/CH4selectivity. Another embodiment provides a method of making the membrane from a monesterified polymer followed by final crosslinking after the membrane is formed.
摘要翻译：描述了制备高性能交联膜的组合物和方法。膜通过使用交联具有高的抗塑化性。用于膜的优选聚合物材料是包含共价键合的酯交联的聚酰亚胺聚合物。所得到的膜表现出高的二氧化碳渗透性和高CO 2 / CH 4选择性。另一个实施方案提供了在膜形成之后由单酯化聚合物制备膜然后进行最终交联的方法。

86. 发明授权

US08268187B2 Refrigeration oil from gas-to-liquid-derived and bio-derived diesters 有权
标题翻译：从气体到液体衍生的和生物来源的二酯的制冷油
公开(公告)号：US08268187B2
公开(公告)日：2012-09-18
申请号：US13212964
申请日：2011-08-18
申请人： David C. Krammer , Ravindra Shah , Stephen J. Miller , Saleh Elomari
发明人： David C. Krammer , Ravindra Shah , Stephen J. Miller , Saleh Elomari
IPC分类号： C09K5/04
CPC分类号： C09K5/044 , C09K5/045 , C09K2205/22 , C09K2205/24 , C10M105/38 , C10M171/008 , C10M177/00 , C10M2207/283 , C10M2207/2835 , C10N2220/022 , C10N2220/023 , C10N2220/301 , C10N2220/302 , C10N2230/02 , C10N2240/30 , C10N2270/00
摘要： The present invention is directed to a refrigerator oil composition comprising (a) at least one diester species having the following structure: wherein R1, R2, R3, and R4 are the same or independently selected from hydrocarbon groups having from 2 to 17 carbon atoms; and (b) a refrigerant.
摘要翻译：本发明涉及一种冷冻机油组合物，其包含（a）至少一种具有以下结构的二酯物质：其中R 1，R 2，R 3和R 4相同或独立地选自具有2至17个碳原子的烃基; 和（b）制冷剂。

87. 发明授权

US08252968B2 Process for producing a low volatility gasoline blending component and a middle distillate using an ionic liquid 有权
标题翻译：使用离子液体生产低挥发性汽油调和组分和中间馏分的方法
公开(公告)号：US08252968B2
公开(公告)日：2012-08-28
申请号：US13035265
申请日：2011-02-25
申请人： Sven Ivar Hommeltoft , Stephen J. Miller , Ajit Ramchandra Pradhan
发明人： Sven Ivar Hommeltoft , Stephen J. Miller , Ajit Ramchandra Pradhan
IPC分类号： C07C2/60 , C07C2/62
CPC分类号： C10G57/005 , C10G2300/1022 , C10G2300/1081 , C10G2300/1088 , C10G2300/20 , C10G2300/301 , C10G2300/304 , C10G2300/305 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08
摘要： A process for producing a low volatility gasoline blending component and a middle distillate, comprising alkylating a hydrocarbon stream comprising at least one olefin having from 2 to 4 carbon atoms and at least one paraffin having from 4 to 6 carbon atoms with an ionic liquid catalyst and an unsupported halide containing additive, and separating the alkylate into at least the low volatility gasoline blending component and the middle distillate, wherein the middle distillate is a fuel suitable for use as a jet fuel or jet fuel blending component. Also, a process for producing a gasoline blending component and a middle distillate, comprising adjusting a level of a halide containing additive provided to an ionic liquid alkylation reactor to shift selectivity towards heavier products, and recovering a low volatility gasoline blending component and the middle distillate. Also, processes comprising alkylating isobutane with butene over specific chloroaluminate ionic liquids.
摘要翻译：一种制备低挥发性汽油调和组分和中间馏分的方法，包括使含离子液体催化剂的包含至少一种具有2至4个碳原子的烯烃和至少一种具有4至6个碳原子的链烷烃的烃流烷烃化，无载体的含卤化物的添加剂，并将烷基化物分离成至少低挥发性汽油调和组分和中间馏分，其中中间馏分是适合用作喷气燃料或喷气燃料混合组分的燃料。另外，制备汽油调和成分和中间馏分的方法，包括调节提供给离子液体烷基化反应器的含卤化物添加剂的含量以使选择性向较重的产物转移，以及回收低挥发性汽油调和组分和中间馏分。而且，包括在特定氯铝酸盐离子液体上使异丁烷与丁烯烷基化的方法。

88. 发明授权

US08221531B2 Crosslinked polyimide membrane, method for making the same using organic titanate catalysts to facilitate crosslinking and method of using the membrane for fluid separation 有权
标题翻译：交联聚酰亚胺膜，使用有机钛酸酯催化剂制造其以促进交联的方法以及使用该膜进行流体分离的方法
公开(公告)号：US08221531B2
公开(公告)日：2012-07-17
申请号：US11968080
申请日：2007-12-31
申请人： John D. Wind , Stephen J. Miller , Oluwasijibomi O. Okeowo
发明人： John D. Wind , Stephen J. Miller , Oluwasijibomi O. Okeowo
IPC分类号： B01D53/22
CPC分类号： C08G73/1039 , B01D53/22 , B01D63/02 , B01D67/0093 , B01D69/145 , B01D71/64 , B01D2257/504 , B01D2323/30 , C08G73/1042 , C08G73/1067 , C08L79/08 , Y02C10/10 , Y02P20/152
摘要： A method of making a crosslinked polyimide membrane is described. A monoesterified membrane is formed from a monoesterified polyimide polymer. The monoesterified membrane is subjected to transesterification conditions to form a crosslinked membrane. The monoesterified membrane is incorporated with an organic titanate catalyst before or after formation of the monoesterified membrane. A crosslinked polyimide membrane made using the aforementioned method and a method of using the membrane to separate fluids in a fluid mixture also are described.
摘要翻译：描述制造交联聚酰亚胺膜的方法。单酯化膜由单酯化聚酰亚胺聚合物形成。对单酯化膜进行酯交换条件以形成交联膜。单酯化膜在形成单酯化膜之前或之后与有机钛酸酯催化剂结合。还描述了使用上述方法制备的交联聚酰亚胺膜和使用该膜分离流体混合物中的流体的方法。

89. 发明申请

US20120149953A1 PROCESS FOR MAKING A HIGH VISCOSITY BASE OIL WITH AN IMPROVED VISCOSITY INDEX 有权
标题翻译：具有改进粘度指数的高粘度基油的制备方法
公开(公告)号：US20120149953A1
公开(公告)日：2012-06-14
申请号：US12966738
申请日：2010-12-13
申请人： Saleh A. Elomari , Stephen J. Miller , Sven Ivar Hommeltoft , Hye-Kyung C. Timken
发明人： Saleh A. Elomari , Stephen J. Miller , Sven Ivar Hommeltoft , Hye-Kyung C. Timken
IPC分类号： C07C11/00 , C07C2/08
CPC分类号： C10G50/00 , B01J31/0284 , B01J31/40 , B01J2231/20 , C10G1/002 , C10G3/00 , C10G57/02 , C10G2300/1022 , C10G2300/1088 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/4025 , C10G2400/10 , Y02P30/20
摘要： We provide a process, comprising oligomerizing one or more olefins having a boiling point less than 82° C. in a presence of an ionic liquid catalyst and one or more C5+ alpha olefins in a reactor to produce a base oil having a kinematic viscosity at 100° C. of 36 mm2/s or higher and a VI greater than 55; and wherein the one or more olefins having the boiling point less than 82° C. comprise greater than 50 wt % of a total mixture of olefins fed to the reactor. We provide a process, comprising oligomerizing olefins having a low boiling point in a presence of an ionic liquid catalyst and a mixture of C5+ alpha olefins derived from waste plastic to produce a base oil having a kinematic viscosity at 40° C. greater than 1100 mm2/s and a VI greater than 55. We also provide a base oil made by the process.
摘要翻译：我们提供了一种方法，其包括在反应器中在离子液体催化剂和一种或多种C 5+α-烯烃的存在下使沸点低于82℃的一种或多种烯烃低聚以产生运动粘度为100的基础油 ℃，36mm 2 / s以上，VI大于55; 并且其中沸点小于82℃的一种或多种烯烃占供给反应器的烯烃的总混合物的大于50重量％。我们提供一种方法，其包括在离子液体催化剂存在下使具有低沸点的烯烃和衍生自废塑料的C5 +α烯烃的混合物低聚以产生在40℃下具有大于1100mm 2的运动粘度的基础油 / s，VI大于55.我们还提供了一个由该过程制成的基础油。

90. 发明授权

US08178739B2 Tuning an oligomerizing step to produce a base oil with selected properties 有权
标题翻译：调整低聚步骤以产生具有选定性能的基础油
公开(公告)号：US08178739B2
公开(公告)日：2012-05-15
申请号：US12538746
申请日：2009-08-10
申请人： Saleh Elomari , Stephen J. Miller
发明人： Saleh Elomari , Stephen J. Miller
IPC分类号： C07C2/02 , C07C2/08
CPC分类号： C10G50/02 , C10G2300/1088 , C10G2300/1092 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/80 , C10G2400/10
摘要： A process, comprising: a. selecting a kinematic viscosity; b. feeding an olefin feed comprising a propylene to an oligomerization zone; c. tuning an oligomerizing step to produce a base oil having the kinematic viscosity and a viscosity index from 20 to 90. A process, comprising: a. selecting a kinematic viscosity that is greater than 20 mm2/s; b. feeding a feed comprising propylene to an oligomerization zone; and c. adding a Brönsted acid to produce a base oil. A process, comprising tuning a step in an oligomerization zone comprising a propylene and an ionic liquid catalyst to produce a base oil having: a. a high kinematic viscosity; b. a viscosity index from 25 to 90; and c. a low pour point. A base oil, comprising oligomerized olefins, wherein the base oil has: a. a high kinematic viscosity; b. a viscosity index from 25 to 90; and c. a low pour point.
摘要翻译：一个过程，包括：a。选择运动粘度; b。将包含丙烯的烯烃进料进料到低聚区; C。调节低聚步骤以产生具有20至90的运动粘度和粘度指数的基础油。一种方法，包括：a。选择大于20 mm2 / s的运动粘度; b。将含有丙烯的进料进料到低聚区; 和c。加入布朗斯台德酸生产基础油。一种方法，包括调整包含丙烯和离子液体催化剂的低聚区中的步骤以产生具有以下成分的基础油：a。高运动粘度; b。粘度指数为25〜90; 和c。低倾点。一种基础油，其包含低聚烯烃，其中所述基础油具有：a。高运动粘度; b。粘度指数为25〜90; 和c。低倾点。

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