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81. 发明授权

US4572779A Process for the dewaxing of hydrocarbon fractions 失效
$Process for the dewaxing of hydrocarbon fractions$
标题翻译：烃馏分脱蜡方法
公开(公告)号：US4572779A
公开(公告)日：1986-02-25
申请号：US579171
申请日：1984-02-10
申请人： Kazuyoshi Iwayama , Takehisa Inoue , Kimio Sato , Norio Hayakawa , Masaki Fujii
发明人： Kazuyoshi Iwayama , Takehisa Inoue , Kimio Sato , Norio Hayakawa , Masaki Fujii
IPC分类号： C10G73/02 , B01J29/40 , B01J29/70 , C01B39/38 , C10G45/64
CPC分类号： C10G45/64 , B01J29/40 , B01J29/70 , C01B39/38 , B01J2229/26 , B01J2229/42
摘要： A process for improving the fluidity of hydrocarbon fractions by dewaxing thereof. In the present process, hydrocarbon fractions are contacted with hydrogen in the presence of a specific type of catalyst, thereby lowering the pour point of the hydrocarbon fraction. The catalyst comprises a specific type of zeolite which is defined by a specific X-ray diffraction pattern and which has a predetermined range of mesitylene adsorption of not less than 1.6 wt %. The zeolite catalyst is obtained by providing an aqueous reaction mixture of SiO.sub.2, Al.sub.2 O.sub.3, an alkaline source as OH.sup.-, and a carboxyl group-containing organic compound having the following composition:______________________________________ SiO.sub.2 /Al.sub.2 O.sub.3 20-60 H.sub.2 O/SiO.sub.2 5-100 OH.sup.- /SiO.sub.2 0.1-0.35 ______________________________________ and reacting the mixture until crystals are produced. Advantageously, the ratio of the carboxyl group-containing organic compound to aluminum oxide is about 1.0 to 100.
摘要翻译：通过脱蜡改善烃馏分的流动性的方法。在本方法中，在特定催化剂存在下，使烃馏分与氢接触，从而降低烃馏分的倾点。该催化剂包括由特定的X射线衍射图定义并且具有不小于1.6重量％的均三甲苯吸附的预定范围的特定类型的沸石。沸石催化剂通过提供SiO 2，Al 2 O 3，碱性源作为OH-的含水反应混合物和具有以下组成的含羧基的有机化合物获得：-SiO 2 / Al 2 O 3 20-60 -H 2 O / SiO 2 5-100 -OH- / SiO 2 0.1-0.35 - 并使混合物反应直至产生晶体。有利地，含羧基的有机化合物与氧化铝的比例为约1.0至100。

82. 发明授权

US4334040A Propylene block copolymers 失效
标题翻译：丙烯嵌段共聚物
公开(公告)号：US4334040A
公开(公告)日：1982-06-08
申请号：US186578
申请日：1980-09-12
申请人： Masaki Fujii , Mitsutaka Miyabayashi
发明人： Masaki Fujii , Mitsutaka Miyabayashi
IPC分类号： C08F297/08 , C08F255/08
CPC分类号： C08F297/08
摘要： A propylene block copolymer comprising propylene, ethylene and a straight-chain .alpha.-olefin of 5 to 12 carbon atoms is characterized in that: its limiting viscosity is 0.3 to 15 dl/g (at 135.degree. C., in decalin); it comprises specified quantities of these monomers; and when it is subjected to successive extraction with o-dichlorobenzene at 40.degree. C. and 80.degree. C., the quantities, fusion peak temperatures, and content of the .alpha.-olefin of the resulting fractions are respectively within specific limits of values.
摘要翻译：包含丙烯，乙烯和5-12个碳原子的直链α-烯烃的丙烯嵌段共聚物的特征在于：其特性粘度为0.3至15dl / g（在135℃，在十氢化萘中）; 它含有规定量的这些单体; 当在40℃和80℃下用邻二氯苯进行连续萃取时，得到的馏分的数量，熔融峰温度和α-烯烃的含量分别在特定的值范围内。

83. 发明授权

US4308361A Propylene copolymers 失效
标题翻译：丙烯共聚物
公开(公告)号：US4308361A
公开(公告)日：1981-12-29
申请号：US152605
申请日：1980-05-23
申请人： Masaki Fujii , Mitsutaka Miyabayashi
发明人： Masaki Fujii , Mitsutaka Miyabayashi
IPC分类号： C08F210/06 , C08F297/08 , C08F210/14 , C08F293/00
CPC分类号： C08F210/06 , C08F297/08
摘要： A copolymer of propylene and a straight-chain .alpha.-olefin of 5 to 12 carbon atoms is characterized in that: its intrinsic viscosity is 0.3 to 15 dl./g. (at 135.degree. C., in decalin); it contains 3 to 30 percent by weight of the .alpha.-olefin; and when it is subjected to successive extraction with o-dichlorobenzene at 40.degree. C. and 80.degree. C., the quantities, fusion peak temperatures, and content of the .alpha.-olefin of the resulting fractions are respectively within specific limits of values. A preferred copolymer contains about 0.5 to 50 percent of a propylene homopolymer block and about 99.5 to 50 percent of a random copolymer block of propylene and a straight chain .alpha.-olefin having 5 to 12 carbon atoms.
摘要翻译：丙烯与5-12个碳原子的直链α-烯烃的共聚物的特征在于：其特性粘度为0.3-15dl / g。（在135℃，在十氢化萘中）; 它含有3-30重量％的α-烯烃; 当在40℃和80℃下用邻二氯苯进行连续萃取时，得到的馏分的数量，熔融峰温度和α-烯烃的含量分别在特定的值范围内。优选的共聚物包含约0.5至50％的丙烯均聚物嵌段和约99.5至50％的丙烯无规共聚物嵌段和具有5至12个碳原子的直链α-烯烃。

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