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    • 82. 发明授权
    • Shaped article of cellulose hydrate with a coating of plastic material
of chemically modified protein and process for the production thereof
    • 具有化学改性蛋白质的塑料材料的涂层的水合纤维素形成品及其生产方法
    • US4142013A
    • 1979-02-27
    • US869356
    • 1978-01-13
    • Klaus-Dieter HammerWolfgang KlendauerMartin Schroder
    • Klaus-Dieter HammerWolfgang KlendauerMartin Schroder
    • A22C13/00C08L1/06C09D189/00B32B23/08
    • C09D189/00A22C13/0013C08L1/06Y10T428/1324Y10T428/1393Y10T428/31703Y10T428/31884Y10T428/31891
    • This invention relates to a process for coating the surface of a shaped article of cellulose hydrate with a layer of polymer material which comprises applying to the surface of a shaped article in the gel state and based on cellulose hydrate, a liquid layer of an aqueous solution of a chemically modified protein obtained by mixing an aqueous alkaline protein solution with an aqueous solution of N-methylolacrylamide or N-methylol-methacrylamide or of the alkoxy derivatives thereof of aliphatic alcohols with 1 to 8 carbon atoms, particularly of organic, tetrafunctional, doubly unsaturated compounds of the general formula ##STR1## in which R.sub.1 and R.sub.2 are hydrogen or an alkyl group with 1 to 6 carbon atoms, andR.sub.3 is the group --(CH.sub.2).sub.n --, n being an integer from 1 to 8, or the group ##STR2## in which R.sub.4 is an alkyl group with 1 to 18 carbon atoms, subjecting the liquid mixture to a dwell time, heating the coated shaped article, and wetting the shaped article. The invention also relates to a shaped article of cellulose hydrate having a coating of protein thereon.
    • 本发明涉及一种用聚合物材料层涂覆纤维素水合物的成型制品的表面的方法,该方法包括以凝胶状态施加到成形制品的表面上,并且基于纤维素水合物,水溶液的液体层 通过将碱性水溶液与N-羟甲基丙烯酰胺或N-羟甲基 - 甲基丙烯酰胺的水溶液或其烷基衍生物混合而获得的化学修饰的蛋白质,其具有1至8个碳原子的脂族醇,特别是有机,四官能,双 其中R 1和R 2为氢或具有1至6个碳原子的烷基,通式为“IMAGE”的不饱和化合物,R 3为基团 - (CH 2)n - ,n为1至8的整数,或 基团,其中R 4是具有1至18个碳原子的烷基,使液体混合物进入停留时间,加热涂覆的成型制品并润湿成型制品。 本发明还涉及在其上具有蛋白质涂层的水合物的成形制品。