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    • 83. 发明申请
    • Nd-Fe-B Magnetic with Modified Grain Boundary and Process for Producing the Same
    • 具有改性晶粒边界的Nd-Fe-B磁性及其制备方法
    • US20080006345A1
    • 2008-01-10
    • US11793272
    • 2005-12-14
    • Kenichi MachidaShunji Suzuki
    • Kenichi MachidaShunji Suzuki
    • H01F1/01
    • H01F1/0577C22C29/14H01F41/0293
    • [Problem] In known methods, an improvement of the coercive force is realized by allowing the Dy metal or the like to present selectively in crystal grain boundary portions of a sintered magnet. However, since these are based on a physical film formation method, e.g., sputtering, through the use of a vacuum vessel, there is a mass productivity problem in the case where large amounts of magnet is treated. Furthermore, there is a magnet cost problem from the viewpoint that, for example, an expensive, high-purity Dy metal or the like must be used as a raw material for film formation. [Solving Means] A method for modifying grain boundaries of a Nd—Fe—B base magnet characterized by including the step of allowing an M metal component to diffuse and penetrate from a surface of a Nd—Fe—B base sintered magnet body having a Nd-rich crystal grain boundary phase surrounding principal Nd2Fe14B crystals to the grain boundary phase through a reduction treatment of a fluoride, an oxide, or a chloride of an M metal element (where M is Pr, Dy, Tb, or Ho).
    • [问题]在已知的方法中,通过使Dy金属等选择性地存在于烧结磁体的晶界部中,可以实现矫顽力的提高。 然而,由于这些基于物理成膜方法,例如溅射,通过使用真空容器,在处理大量磁体的情况下存在批量生产率问题。 此外,从例如必须使用昂贵,高纯度的Dy金属等作为成膜原料的观点出现磁铁成本问题。 [解决方案]一种用于改变Nd-Fe-B基础磁体的晶界的方法,其特征在于包括以下步骤:允许M金属组分从具有 通过氟化物,氧化物或氯化物的还原处理将包围主要Nd 2 Fe 14 B的富Nd晶界相结晶到晶界相 M金属元素(其中M为Pr,Dy,Tb或Ho)。