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    • 86. 发明授权
    • Aqueous solution of cationic organosilicon compounds and process for the
production of the solutions
    • 阳离子有机硅化合物的水溶液及其制备方法
    • US4390712A
    • 1983-06-28
    • US298251
    • 1981-08-31
    • Alfons KarlWolfgang BuderPeter Kleinschmit
    • Alfons KarlWolfgang BuderPeter Kleinschmit
    • B03D1/01C07F7/18C07F7/10
    • C07F7/1892B03D1/0046B03D1/01
    • There are prepared aqueous solutions of cationic organosilicon compounds which are produced by reacting an alkoxysilylalkyl halide of the formula (RO).sub.3-n R.sub.n.sup.1 --Si--R.sup.2 --X (I) where R is C.sub.1 to C.sub.5 alkyl, methoxy, ethoxy, phenyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.1 is C.sub.1 to C.sub.5 alkyl, phenyl, tolyl, benzyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.2 is a divalent ethylenic double bond free hydrocarbon group having 3 to 8 carbon atoms, n is zero, 1 or 2 and X is chlorine, bromine, or iodine with a tertiary amine of the formula R.sup.3 NR.sup.4 R.sup.5 (II) where R.sup.3, R.sup.4, and R.sup.5 are the same or different and each is an alkyl group or benzyl in which the number of carbon atoms of the alkyl group or the alkyl groups together is up to 30 or R.sup.4 and .sup.5 together with the nitrogen atom, as well as in a given case a further hetero atom selected from the group consisting of oxygen, nitrogen, and sulfur is a univalent five to eight membered heterocyclic ring having three to seven --CH.sub.2 -- groups in the heterocyclic ring, or R.sup.5 is a C.sub.3 to C.sub.12 cycloalkyl group in aqueous medium at a temperature from room temperature (e.g. about 20.degree. C.) to 300.degree. C. at a mole ratio of (I) to (II) between 1:0.8 to 1:1,2 and in a given case under pressure.
    • 制备阳离子有机硅化合物的水溶液,其通过使式(RO)3-nRn1-Si-R2-X(I)的烷氧基​​甲硅烷基烷基卤化物反应制备,其中R是C1至C5烷基,甲氧基,乙氧基,苯基或 C5至C8环烷基; R 1是C 1至C 5烷基,苯基,甲苯基,苄基或C 5至C 8环烷基; R2是具有3-8个碳原子的二价烯键式双键无键烃基,n为0,1或2,X为氯,溴或碘,与式R3NR4R5(Ⅱ)的叔胺反应,其中R3,R4和 R5相同或不同,并且各自为烷基或苄基,其中烷基或烷基的碳原子数一起为至多30或R4和5以及氮原子以及在给定的 在另一个选自氧,氮和硫的杂原子的情况下,杂环中具有三至七个-CH 2 - 基的一价五元至八元杂环,或者R5是水性中的C3至C12环烷基 介质在室温(例如约20℃)至300℃的温度下以(I)至(II)的摩尔比为1:0.8至1:1.2,在给定情况下在压力下。
    • 88. 发明授权
    • Zirconium dioxide powder, method of its production and use
    • 二氧化锆粉末,其生产和使用方法
    • US06524548B1
    • 2003-02-25
    • US09067915
    • 1998-04-29
    • Helmut MangoldWerner HartmannDieter KernerPeter Kleinschmit
    • Helmut MangoldWerner HartmannDieter KernerPeter Kleinschmit
    • C01G2500
    • B82Y30/00C01G25/02C01P2002/54C01P2002/60C01P2004/51C01P2004/64C01P2006/11C01P2006/12C01P2006/80C01P2006/90
    • Pyrogenically, especially flame-hydrolytically produced zirconium dioxide powder with a specific surface area between 20 and 200 m2/g, a primary particle size between 7 and 100 nm, a tamped density of the deacidified and non-deacidified zirconium dioxide between 40 and 150 g/l with Sears numbers of the deacidified and non-deacidified zirconium dioxide between 1 and 20 ml/2 g and with a chlorine content of the deacidified zirconium dioxide less than 0.6% by weight. These are produced by evaporating zirconium halides, mixing the vapors alone or together with a carrier gas in a burner with air, oxygen, nitrogen and hydrogen, causing the gases to react with each other in a flame in a closed burner chamber, cooling off the waste gases and the zirconium dioxide in a heat exchanger unit, separating the waste gases from the zirconium dioxide and removing any halide remnants adhering to the zirconium dioxide by a heat treatment with moistened air.
    • 热原性地,特别是火焰水解生产的二氧化锆粉末,比表面积为20至200m2 / g,一次粒径在7至100nm之间,脱酸和非脱酸二氧化锆的密度为40-150g / S,数量为1至20ml / 2g之间的脱酸和非脱酸二氧化锆,并且脱酸二氧化锆的氯含量小于0.6重量%。 这些是通过蒸发卤化锆,将蒸气单独或与气体一起携带在具有空气,氧气,氮气和氢气的燃烧器中的气体混合而产生的,导致气体在封闭的燃烧器室中的火焰中彼此反应,冷却 废气和二氧化锆在热交换器单元中分离废气和二氧化锆,并通过用湿润的空气进行热处理除去附着在二氧化锆上的任何卤化物残余物。