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81. 发明授权

US4563447A Combating fungi with 4-piperidino methyl-1,3-dioxolanes 失效
标题翻译：用4-哌啶子基甲基-1,3-二氧戊环杀灭真菌
公开(公告)号：US4563447A
公开(公告)日：1986-01-07
申请号：US630487
申请日：1984-07-13
申请人： Wolfgang Kramer , Joachim Weissmuller , Dieter Berg , Paul Reinecke , Gerd Hanssler , Wilhelm Brandes
发明人： Wolfgang Kramer , Joachim Weissmuller , Dieter Berg , Paul Reinecke , Gerd Hanssler , Wilhelm Brandes
IPC分类号： A01N43/40 , C07D317/00 , C07D317/16 , C07D317/28 , C07D405/06 , C07D405/14
CPC分类号： C07D405/06 , A01N43/40 , C07D317/16 , C07D317/28 , C07D405/14
摘要： Substituted 4-piperidinomethyl-1,3-dioxolanes of the formula ##STR1## in which R.sup.1 is tetrahydronaphthyl, decahydronaphthyl, optionally substituted naphthyl, optionally substituted cycloalkyl or cycloalkenyl, optionally substituted phenyl, or alkyl which is substituted by in each case optionally substituted phenyl, phenoxy, phenylthio, cyclohexyl, cyclohexyloxy or cyclohexylthio,R.sup.2 is hydrogen or methyl,R.sup.3 is hydrogen or an acyl radicalor plant-tolerated addition products thereof with acids or metal salts, which possess fungicidal activity.
摘要翻译：取代的式“IMAGE”的4-哌啶甲基-1,3-二氧戊烷，其中R 1是四氢萘基，十氢萘基，任选取代的萘基，任选取代的环烷基或环烯基，任选取代的苯基或被各种情况下被取代的任选取代的苯基，苯氧基，苯硫基，环己基，环己氧基或环己基硫基，R2是氢或甲基，R3是氢或具有杀真菌活性的酸或其盐的酰基或植物耐受的加成产物。

82. 发明授权

US4562198A Combating fungi with substituted azolyl-tetrahydro-furan-2-ylidene-methane derivatives 失效
标题翻译：用真空灭菌与取代的吡唑并四氢呋喃-2-亚基甲烷衍生物
公开(公告)号：US4562198A
公开(公告)日：1985-12-31
申请号：US658344
申请日：1984-10-05
申请人： Hans-Ludwig Elbe , Manfred Jautelat , Karl H. Buchel , Wilhelm Brandes , Gerd Hanssler , Paul Reinecke
发明人： Hans-Ludwig Elbe , Manfred Jautelat , Karl H. Buchel , Wilhelm Brandes , Gerd Hanssler , Paul Reinecke
IPC分类号： A01N43/50 , A01N43/64 , A01N43/653 , C07C17/00 , C07C17/278 , C07C45/00 , C07C45/59 , C07C45/63 , C07C45/71 , C07C49/16 , C07C49/175 , C07C67/00 , C07C313/00 , C07C323/22 , C07D233/60 , C07D249/08 , C07D307/28 , C07D405/06 , C07D521/00 , C07F1/08 , C07F3/02 , C07F3/06 , C07F13/00 , C07F15/02 , C07F15/04
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C17/00 , C07C17/278 , C07C323/00 , C07C45/59 , C07C45/63 , C07C45/71 , C07C49/16 , C07D233/56 , C07D249/08 , C07D307/28
摘要： Azolyl-tetrahydrofuran-2-ylidene-methanes of the formula ##STR1## in which A represents a nitrogen atom or the CH group;X represents oxygen, sulphur or the SO or SO.sub.2 group;R represents optionally substituted aryl;R.sup.1 and R.sup.6 are identical or different and represent hydrogen, alkyl, halogenoalkyl or halogen, a maximum of up to 3 substituents representing halogen or halogenoalkyl, with the proviso that R.sup.1 and R.sup.2 are not at the same time methyl if X represents oxygen;R.sup.1 and R.sup.2, together with the carbon atom to which they are bonded, represent optionally substituted cycloalkyl orR.sup.2 and R.sup.3, together with the carbon atoms to which they are bonded, represent optionally substituted cycloalkyl,or addition products thereof with acids or metal salts. Some new intermediates are also shown. The end products are fungicides.
摘要翻译：其中A表示氮原子或CH基团的式（I）的唑基 - 四氢呋喃-2-亚基 - 甲烷; X表示氧，硫或SO或SO2基团; R代表任选取代的芳基; R1和R6相同或不同，代表氢，烷基，卤代烷基或卤素，最多可含3个代表卤素或卤代烷基的取代基，条件是如果X表示氧，则R1和R2不同时为甲基; R 1和R 2与它们所键合的碳原子一起代表任选取代的环烷基或R 2和R 3与它们所键合的碳原子一起代表任选取代的环烷基，或其与酸或金属盐的加成产物。还显示了一些新的中间体。最终产品是杀真菌剂。

83. 发明授权

US4940798A Substituted azolylvinyl ketones and carbinols as fungicides and plant growth regulators 失效
标题翻译：取代的唑基乙烯基酮和甲醇作为杀真菌剂和植物生长调节剂
公开(公告)号：US4940798A
公开(公告)日：1990-07-10
申请号：US100650
申请日：1987-09-24
申请人： Hans-Ludwig Elbe , Wolf Reiser , Erik Regel , Karl H. Buchel , Paul Reinecke , Wilhelm Brandes , Klaus Lurssen , Paul-Ernst Frohberger
发明人： Hans-Ludwig Elbe , Wolf Reiser , Erik Regel , Karl H. Buchel , Paul Reinecke , Wilhelm Brandes , Klaus Lurssen , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： A substituted azolylvinyl ketone or carbinol of the formula ##STR1## in which R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms, substituted cyclohexyl or the grouping ##STR2## wherein R.sup.3 represents optionally substituted phenyl, alkenyl, alkinyl, cyano or the grouping --Z--R.sup.4,whereinR.sup.4 represents alkyl, halogenoalkyl, optionally substituted phenyl or optionally substituted phenylalkyl andZ represents O, S, SO or SO.sub.2,n represents a number from 0 to 2,R.sup.2 represents alkyl, alkenyl, alkinyl, in each case optionally substituted phenyl or phenylalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, bicycloalkyl or bicycloalkenyl, but R.sup.2 does not represent optionally substituted phenyl at the same time as R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms or substituted cyclohexyl or R.sup.3 represents optionally substituted phenyl,X represents the CO or CH(OH) group andY represents a nitrogen atom or the CH group,or an addition product thereof with an acid or metal salt. The products are active in combating fungi and in regulating the growth of plants.

84. 发明授权

US4898875A Mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives 失效
标题翻译：巯基取代的羟乙基 - （三唑-1-基）衍生物
公开(公告)号：US4898875A
公开(公告)日：1990-02-06
申请号：US91557
申请日：1987-08-31
申请人： Karl H. Buchel , Graham Holmwood , Udo Kraatz , Wolfgang Kramer , Paul Reinecke , Wilhelm Brandes , Wilhelm Stendel
发明人： Karl H. Buchel , Graham Holmwood , Udo Kraatz , Wolfgang Kramer , Paul Reinecke , Wilhelm Brandes , Wilhelm Stendel
IPC分类号： A01N43/653 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Novel mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives of the formula ##STR1## in which Ar represents optionally substituted aryl,X represents oxygen, sulphur, a direct bond or the groupings --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --, --O--CH.sub.2 --, --SCH.sub.2 --, --O--CH.sub.2 --CH.sub.2 --, and --S--CH.sub.2 --CH.sub.2 --, the hetero atom being bonded to the aryl radical if X represents --OCH.sub.2 --, --SCH.sub.2 --, --O--CH.sub.2 --CH.sub.2 -- or --S--CH.sub.2 --CH.sub.2 -- andR represents hydrogen, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl or optionally substituted phenyl, and their acid addition salts and metal salt complexes are very effective as fungicides and parasiticides. Novel oxiranes of the formula ##STR2## in which Ar and X have the above-mentioned meaning, and their use as intermediates for the synthesis of the mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives.
摘要翻译：式（I）的新型巯基取代的羟乙基 - （三唑-1-基）衍生物，其中Ar表示任选取代的芳基，X表示氧，硫，直接键或-CH 2 - ， - CH2-，-O-CH2-，-SCH2-，-O-CH2-CH2-和-S-CH2-CH2-，如果X表示-OCH2-，-SCH2-，则杂原子键合到芳基上， -O-CH 2 -CH 2 - 或-S-CH 2 -CH 2 - ，R表示氢，任选取代的烷基，任选取代的烯基，任选取代的炔基，任选取代的环烷基，任选取代的环烷基烷基，任选取代的芳烷基或任选取代的苯基，酸加成盐和金属盐络合物作为杀真菌剂和杀寄生物剂是非常有效的。其中Ar和X具有上述含义的式“IMAGE”的新型环氧乙烷及其作为合成巯基取代的羟乙基 - （三唑-1-基）衍生物的中间体的用途。

85. 发明授权

US4870092A 1,3-Diazolyl-2-propanols as fungicidal agents 失效
标题翻译： 1,3-二唑基-2-丙醇作为杀真菌剂
公开(公告)号：US4870092A
公开(公告)日：1989-09-26
申请号：US578246
申请日：1984-02-08
申请人： Hans-Ludwig Elbe , Graham Holmwood , Erick Regel , Karl H. Buchel , Paul Reinecke , Wilhelm Brandes
发明人： Hans-Ludwig Elbe , Graham Holmwood , Erick Regel , Karl H. Buchel , Paul Reinecke , Wilhelm Brandes
IPC分类号： A01N43/50 , A01N43/653 , C07C49/223 , C07D233/60 , C07D249/08 , C07D403/06 , C07D405/06 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C49/223 , C07D233/56 , C07D249/08
摘要： A fungicidal composition comprising a fungicidally effective amount of a 1,3-diazolyl-2-propanol of the formula ##STR1## in which Alk.sup.1 is alkyl, andAlk.sup.2 is alkyl, orAlk.sup.1 and Alk.sup.2 together complete a cycloaliphatic ring,X is a nitrogen atom or the CH group,Y is a nitrogen atom or the CH group, andR is optionally substituted phenyl, phenylalkyl, phenoxy, phenylthio, phenoxyalkyl, phenylthioalkyl, benzyloxy or benzylthio,or a physiologically acceptable product thereof with an acid or metal salt in admixture with a diluent.
摘要翻译：一种杀真菌组合物，其包含杀真菌有效量的式“IMAGE”的1,3-二唑基-2-丙醇，其中Alk1是烷基，Alk2是烷基，或Alk1和Alk2一起完成脂环族环，X是氮 Y为氮原子或CH基团，R为任选取代的苯基，苯基烷基，苯氧基，苯硫基，苯氧基烷基，苯硫基烷基，苄氧基或苄硫基，或其生理学上可接受的产物与酸或金属盐反应与稀释剂混合。

86. 发明授权

US4798899A Combating fungi with novel azolyl-tetrahydrofuran-2-ylidene-methanes 失效
标题翻译：用新的唑基 - 四氢呋喃-2-亚基 - 甲烷灭菌真菌
公开(公告)号：US4798899A
公开(公告)日：1989-01-17
申请号：US879662
申请日：1986-06-27
申请人： Hans-Ludwig Elbe , Manfred Jautelat , Karl H. Buchel , Wilhelm Brandes , Gerd Hanssler , Paul Reinecke
发明人： Hans-Ludwig Elbe , Manfred Jautelat , Karl H. Buchel , Wilhelm Brandes , Gerd Hanssler , Paul Reinecke
IPC分类号： A01N43/50 , A01N43/653 , C07C45/00 , C07C45/59 , C07C45/63 , C07C49/16 , C07C67/00 , C07D233/60 , C07D249/08 , C07D307/28 , C07D307/30 , C07D307/38 , C07D405/06 , C07D521/00 , C07D233/56
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C45/59 , C07C45/63 , C07C49/16 , C07D233/56 , C07D249/08 , C07D307/28
摘要： Azolyl-tetrahydrofuran-2-ylidene-methanes of the formula ##STR1## in which A represents a nitrogen atom or the CH group,R represents alkyl, alkenyl, alkinyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl, halogenalkoxyalkyl, halogenoalkylthioalkyl, halogenoalkenyl, optionally substituted aralkyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted cycloalkyl or optionally substituted cycloalkylalkyl,R.sup.1 to R.sup.6 are identical or different and represent hydrogen, alkyl, halogenoalkyl or halogen, up to at most 3 of the substituents representing halogen or halogenoalkyl, orR.sup.1 and R.sup.2, together with the carbon atom to which they are bonded, represent optionally substituted cycloalkyl, orR.sup.2 and R.sup.3, together with the carbon atoms to which they are bonded, represent optionally substituted cycloalkyl,or addition products thereof with acids or metal salts. Some new intermediates are also shown.
摘要翻译：芳基 - 四氢呋喃-2-亚基 - 甲烷，其中A表示氮原子或CH基团，R表示烷基，烯基，炔基，烷氧基烷基，烷硫基烷基，卤代烷基，卤代烷氧基烷基，卤代烷硫基烷基，卤代烯基，任选取代的芳烷基，任选取代的芳氧基烷基，任选取代的芳硫基烷基，任选取代的环烷基或任选取代的环烷基烷基，R 1至R 6相同或不同，代表氢，烷基，卤代烷基或卤素，最多至多3个表示卤素或卤代烷基的取代基，或R 1和 R2与它们所键合的碳原子一起代表任选取代的环烷基，或者R 2和R 3与它们所键合的碳原子一起表示任选取代的环烷基，或其与酸或金属盐的加成产物。还显示了一些新的中间体。

87. 发明授权

US4758582A Novel azolyl-aroxymethyl-dimethylpentynol fungicides 失效
标题翻译：新型唑基 - 甲氧基甲基 - 二甲基戊炔类杀真菌剂
公开(公告)号：US4758582A
公开(公告)日：1988-07-19
申请号：US816540
申请日：1986-01-06
申请人： Gerhard Jager , Manfred Jautelat , Dieter Arlt , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler
发明人： Gerhard Jager , Manfred Jautelat , Dieter Arlt , Paul Reinecke , Wilhelm Brandes , Gerd Hanssler
IPC分类号： A01N43/50 , A01N43/64 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Novel fungicidally active compounds of the formula ##STR1## in which X is nitrogen or the CH group,Y is hydrogen, bromine or iodine,Z is oxygen, sulphur, the --SO-- group or the --SO.sub.2 -- group, andAR is optionally substituted aryl,or physiologically tolerated additon products thereof with acids or metal salts.
摘要翻译：新颖的杀真菌活性化合物，其中X是氮或CH基，Y是氢，溴或碘，Z是氧，硫，-SO-基或-SO 2 - 基，AR是任选的取代的芳基或其生理上耐受的添加剂与酸或金属盐。

88. 发明授权

US4755521A Fungicidal agents 失效
标题翻译：杀真菌剂
公开(公告)号：US4755521A
公开(公告)日：1988-07-05
申请号：US55487
申请日：1987-05-28
申请人： Wolfgang Kramer , Joachim Weissmuller , Wolf Reiser , Dieter Berg , Wilhelm Brandes , Paul Reinecke
发明人： Wolfgang Kramer , Joachim Weissmuller , Wolf Reiser , Dieter Berg , Wilhelm Brandes , Paul Reinecke
IPC分类号： A01N43/36 , A01N43/40 , A01N43/46 , A01N43/50 , A01N43/54 , A01N43/60 , A01N43/653 , A01N43/84 , A01N47/38 , A01N47/42 , A01N43/64
CPC分类号： A01N43/84 , A01N43/36 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/60 , A01N43/653 , A01N47/38 , A01N47/42
摘要： A synergistic fungicidal composition comprising a fungicidally effective amount of at least one amino compound of the formula ##STR1## in which R represents optionally substituted cycloalkyl or optionally substituted aryl,R.sup.1 represents hydrogen or alkyl,R.sup.2 represents alkyl,R.sup.3 represents alkyl andR.sup.4 represents alkyl, alkenyl or alkinyl, orR.sup.3 and R.sup.4, together with the nitrogen atom to which they are bonded, represent an optionally substituted saturated heterocyclic radical, which can contain further hetero-atoms,X represents oxygen or sulphur,Y represents oxygen, sulphur or the methylene group,m represents 0 or 1 andn represents 0 or 1,or an addition product thereof with an acid, metal salt or quaternizing agent, and at least one member selected from the group consisting of several individually known fungicides.
摘要翻译：一种协同杀真菌组合物，其包含杀真菌有效量的至少一种下式的氨基化合物，其中R表示任选取代的环烷基或任选取代的芳基，R 1表示氢或烷基，R 2表示烷基，R 3表示烷基，R 4表示烷基，链烯基或炔基，或者R 3和R 4与它们所键合的氮原子一起代表任选取代的饱和杂环基，其可含有其它杂原子，X表示氧或硫，Y表示氧，硫或亚甲基，m表示0或1，n表示0或1，或其与酸，金属盐或季铵化剂的加成产物，以及选自几种单独已知的杀真菌剂中的至少一种。

89. 发明授权

US4740515A 3-(1,2,4-triazol-1-yl)-prop-1-ene fungicides 失效
标题翻译： 3-（1,2,4-三唑-1-基） - 丙-1-烯类杀真菌剂
公开(公告)号：US4740515A
公开(公告)日：1988-04-26
申请号：US632138
申请日：1984-07-18
申请人： Joachim Weissmuller , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul Reinecke
发明人： Joachim Weissmuller , Wolfgang Kramer , Karl H. Buchel , Wilhelm Brandes , Paul Reinecke
IPC分类号： A01N43/653 , C07C17/14 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07C17/14 , C07D233/56 , C07D249/08
摘要： 3-(1,2,4-Triazol-1-yl)-prop-1-enes of the general formula (I) ##STR1## in which X.sup.1 and X.sup.2 independently of one another represent hydrogen or methyl,R.sup.1 represents alkyl, alkenyl, in each case optionally substituted cycloalkyl or cycloalkenyl or in each case optionally substituted phenyl or benzyl andR.sup.2 represents alkyl, alkenyl, in each case optionally substituted cycloalkyl or cycloalkenyl, halogenoalkyl, in each case optionally substituted phenyl or phenylalkyl, phenoxyalkyl or phenylthioalkyl, in each case optionally substituted in the phenyl part,but whereinR.sup.1 and R.sup.2 may not simultaneously represent optionally substituted phenyl if X.sup.1 and/or X.sup.2 represent hydrogen,and acid addition salts and metal salt complexes thereof which are tolerated by plants, exhibit fungicidal activity.
摘要翻译：其中X 1和X 2彼此独立地表示氢或甲基的通式（I）的（I）的3-（1,2,4-三唑-1-基） - 丙-1-烯，R 1表示烷基，烯基，在每种情况下均为任选取代的环烷基或环烯基，或在每种情况下为任选取代的苯基或苄基，并且R 2表示烷基，烯基，在每种情况下为任选取代的环烷基或环烯基，卤代烷基，在每种情况下为任选取代的苯基或苯基烷基，苯氧基烷基或苯硫基烷基，在每种情况下都可以在苯基部分被取代，但如果X1和/或X2代表氢，其中R1和R2不能同时代表任选取代的苯基，并且其被植物耐受的酸加成盐和金属盐络合物显示为杀真菌剂活动。

90. 发明授权

US4734427A Fungicidal phenylsulphonyl imidazoles 失效
标题翻译：杀真菌苯磺酰咪唑
公开(公告)号：US4734427A
公开(公告)日：1988-03-29
申请号：US12988
申请日：1987-02-10
申请人： Hans-Jochem Riebel , Akihiko Yanagi , Akinori Hirashima , Wilhelm Brandes , Paul Reinecke
发明人： Hans-Jochem Riebel , Akihiko Yanagi , Akinori Hirashima , Wilhelm Brandes , Paul Reinecke
IPC分类号： A01N43/50 , A01N43/647 , C07D233/56 , C07D249/18 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/647 , C07D233/56 , C07D249/08 , C07D249/18
摘要： The phenylsulphonylazoles of the formula ##STR1## in which R.sup.1 represents alkyl,m represents the number 1 or 2,n represents the number 0 or 1, andR.sup.2 represents a radical of the formula ##STR2## wherein R.sup.3 represents alkyl, andR.sup.4 represents hydrogen, halogen, nitro or alkyl.are particularly suitable for combating undesirable microorganisms.
摘要翻译：式（I）的苯基磺酰基唑其中R 1表示烷基，m表示数字1或2，n表示数字0或1，并且R 2表示下式的基团其中R 3表示烷基，和 R4代表氢，卤素，硝基或烷基。特别适用于对抗不良微生物。

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