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81. 发明授权

US07867379B2 Production of an upgraded stream from steam cracker tar by ultrafiltration 有权
标题翻译：通过超滤从蒸汽裂解焦油生产升级的流
公开(公告)号：US07867379B2
公开(公告)日：2011-01-11
申请号：US11980162
申请日：2007-10-30
申请人： Daniel P. Leta , Edward W. Corcoran , Eric B. Sirota , Stephen M. Cundy , Kirk C. Nadler , John Di-Yi Ou , Paul F. Keusenkothen
发明人： Daniel P. Leta , Edward W. Corcoran , Eric B. Sirota , Stephen M. Cundy , Kirk C. Nadler , John Di-Yi Ou , Paul F. Keusenkothen
IPC分类号： B01D61/16 , C10G9/36
CPC分类号： C10G55/04 , C10G31/11
摘要： This invention relates to a process of producing an upgraded product stream from steam cracker tar feedstream suitable for use in refinery or chemical plant processes or for utilization in fuel oil sales or blending. This process utilizes an ultrafiltration process for separating the steam cracker tar constituents resulting in a high recovery, low-energy process with improved separation and product properties.
摘要翻译：本发明涉及一种从适用于炼油厂或化工厂工艺的蒸汽裂解塔焦油原料生产升级产品流的方法或用于燃料油销售或混合的方法。该方法利用超滤方法分离蒸汽裂解焦油成分，导致高回收率，低能量的方法，具有改进的分离和产物性能。

82. 发明授权

US07815791B2 Process and apparatus for using steam cracked tar as steam cracker feed 有权
标题翻译：使用蒸汽裂解焦油作为蒸汽裂化器进料的方法和设备
公开(公告)号：US07815791B2
公开(公告)日：2010-10-19
申请号：US12112704
申请日：2008-04-30
申请人： Paul F. Keusenkothen
发明人： Paul F. Keusenkothen
IPC分类号： C10C1/20
CPC分类号： C10G69/06
摘要： A process and apparatus are provided for steam cracking heavy feeds, including steam cracked tars. The invention heats a steam cracked tar feed to provide a depolymerized steam cracked tar containing lower boiling molecules than the steam cracked tar feed, hydrogenates the depolymerized steam cracked tar using a hydrogenating catalyst, e.g., a downward flow fixed bed hydrotreater, to provide a hydrogenated steam cracked tar. At least a portion of the hydrogenated steam cracked tar is steam cracked in a steam cracking furnace comprising a convection zone and a radiant zone.
摘要翻译：提供了一种用于蒸汽破裂重料，包括蒸汽裂纹焦油的方法和装置。本发明加热蒸汽裂解的焦油进料，以提供含有比蒸汽裂解的焦油进料更低沸点分子的解聚的蒸汽裂解焦油，使用氢化催化剂（例如向下流动的固定床加氢处理器）氢化解聚的蒸汽裂化焦油，以提供氢化蒸汽裂解焦油。氢化蒸汽裂解焦油的至少一部分在包括对流区和辐射区的蒸汽裂解炉中蒸汽裂解。

83. 发明授权

US07553460B2 Process and apparatus for cracking hydrocarbon feedstock containing resid to improve vapor yield from vapor/liquid separation 有权
标题翻译：用于裂化含有渣油的烃原料以提高蒸气/液体分离产物的方法和装置
公开(公告)号：US07553460B2
公开(公告)日：2009-06-30
申请号：US11713505
申请日：2007-03-02
申请人： Richard C. Stell , Jennifer L. Bancroft , Arthur R. Dinicolantonio , Subramanian Annamalai , James N. McCoy , Paul F. Keusenkothen , George Stephens , John R. Messinger , James Mitchell Frye , Nick G. Vidonic , George J. Balinsky
发明人： Richard C. Stell , Jennifer L. Bancroft , Arthur R. Dinicolantonio , Subramanian Annamalai , James N. McCoy , Paul F. Keusenkothen , George Stephens , John R. Messinger , James Mitchell Frye , Nick G. Vidonic , George J. Balinsky
IPC分类号： B01J10/00 , B01J23/90 , B01J19/00
CPC分类号： C10G9/00 , C10G2400/20
摘要： A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent. The process comprises at least two of the following conditions: (1) maintaining the bottoms under conditions to effect at least partial visbreaking; (2) reducing or eliminating partial vapor condensation during flashing by adding a heated vaporous diluent to dilute and superheat the vapor; (3) partially condensing the vapor within said flash/separation vessel by contacting with a condenser; (4) decoking internal surfaces and associated piping of the flash/separation vessel with air and steam; (5) utilizing a flash/separation vessel having an annular, inverted L-shaped baffle; and (6) regulating temperature in furnace tube banks used for heating by utilizing a desuperheater and/or an economizer. An apparatus for carrying out the process is also provided.
摘要翻译：一种用于裂化含有渣油的烃原料的方法，包括：加热原料，将加热的原料与流体和/或初级稀释蒸汽流混合以形成混合物，使混合物闪蒸形成气相和液相，并除去液相，分离和裂化气相，并冷却产物流出物。该方法包括以下条件中的至少两个：（1）在至少部分减粘裂化的条件下保持底部物质; （2）通过添加加热的蒸气稀释剂来稀释和过热蒸气来减少或消除闪蒸过程中的部分蒸气冷凝; （3）通过与冷凝器接触来部分冷凝所述闪蒸/分离容器内的蒸气; （4）用空气和蒸汽去除闪蒸/分离容器的内表面和相关管道; （5）利用具有环形的倒L形挡板的闪光/分离容器; 和（6）通过利用过热降温器和/或节能器来调节用于加热的炉管组中的温度。还提供了一种用于执行该过程的装置。

84. 发明申请

US20080116109A1 Disposition of steam cracked tar 有权
标题翻译：蒸汽裂解焦油的处理
公开(公告)号：US20080116109A1
公开(公告)日：2008-05-22
申请号：US11880925
申请日：2007-07-25
申请人： James N. McCoy , Paul F. Keusenkothen
发明人： James N. McCoy , Paul F. Keusenkothen
IPC分类号： C10C1/00 , B01J8/02
CPC分类号： C10G67/049
摘要： In the invention, tar is upgraded by deasphalting and then hydrocracking to produce valuable products such as low sulfur diesel fuel and mogas. The invention is also directed to a system integrating a pyrolysis furnace operation with refinery operations.
摘要翻译：在本发明中，通过脱沥青，然后加氢裂化来提炼焦油以产生有价值的产物，例如低硫柴油和莫斯汽。本发明还涉及将热解炉操作与精炼操作相结合的系统。

85. 发明授权

US07220887B2 Process and apparatus for cracking hydrocarbon feedstock containing resid 有权
公开(公告)号：US07220887B2
公开(公告)日：2007-05-22
申请号：US10851486
申请日：2004-05-21
申请人： Richard C. Stell , George J. Balinsky , James N. McCoy , Paul F. Keusenkothen
发明人： Richard C. Stell , George J. Balinsky , James N. McCoy , Paul F. Keusenkothen
IPC分类号： C07C4/04
CPC分类号： C10G51/06 , C10G9/00 , C10G9/007 , C10G9/36
摘要： A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent, wherein the bottoms are maintained under conditions to effect at least partial visbreaking. The visbroken bottoms may be steam stripped to recover the visbroken molecules while avoiding entrainment of the bottoms liquid. An apparatus for carrying out the process is also provided.

86. 发明授权

US07193123B2 Process and apparatus for cracking hydrocarbon feedstock containing resid to improve vapor yield from vapor/liquid separation 有权
标题翻译：用于裂化含有渣油的烃原料以提高蒸气/液体分离产物的方法和装置
公开(公告)号：US07193123B2
公开(公告)日：2007-03-20
申请号：US11134148
申请日：2005-05-20
申请人： Richard C. Stell , Jennifer L. Bancroft , Arthur R. DiNicolantonio , Subramanian Annamalai , James N. McCoy , Paul F. Keusenkothen , George Stephens , John R. Messinger , James Mitchell Frye , Nick G. Vidonic , George J. Balinsky
发明人： Richard C. Stell , Jennifer L. Bancroft , Arthur R. DiNicolantonio , Subramanian Annamalai , James N. McCoy , Paul F. Keusenkothen , George Stephens , John R. Messinger , James Mitchell Frye , Nick G. Vidonic , George J. Balinsky
IPC分类号： C07C4/04 , C07C4/02
CPC分类号： C10G9/00 , C10G2400/20
摘要： A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent. The process comprises at least two of the following conditions: (1) maintaining the bottoms under conditions to effect at least partial visbreaking; (2) reducing or eliminating partial vapor condensation during flashing by adding a heated vaporous diluent to dilute and superheat the vapor; (3) partially condensing the vapor within said flash/separation vessel by contacting with a condenser; (4) decoking internal surfaces and associated piping of the flash/separation vessel with air and steam; (5) utilizing a flash/separation vessel having an annular, inverted L-shaped baffle; and (6) regulating temperature in furnace tube banks used for heating by utilizing a desuperheater and/or an economizer. An apparatus for carrying out the process is also provided.
摘要翻译：一种用于裂化含有渣油的烃原料的方法，包括：加热原料，将加热的原料与流体和/或初级稀释蒸汽流混合以形成混合物，使混合物闪蒸形成气相和液相，并除去液相，分离和裂化气相，并冷却产物流出物。该方法包括以下条件中的至少两个：（1）在至少部分减粘裂化的条件下保持底部物质; （2）通过添加加热的蒸气稀释剂来稀释和过热蒸气来减少或消除闪蒸过程中的部分蒸气冷凝; （3）通过与冷凝器接触来部分冷凝所述闪蒸/分离容器内的蒸气; （4）用空气和蒸汽去除闪蒸/分离容器的内表面和相关管道; （5）利用具有环形的倒L形挡板的闪光/分离容器; 和（6）通过利用过热降温器和/或节能器来调节用于加热的炉管组中的温度。还提供了一种用于执行该过程的装置。

87. 发明授权

US09963641B2 Method of flushing pyrolysis reactor 有权
公开(公告)号：US09963641B2
公开(公告)日：2018-05-08
申请号：US14116366
申请日：2012-04-09
申请人： Paul F. Keusenkothen
发明人： Paul F. Keusenkothen
IPC分类号： B01J8/04 , C10B43/08 , B01J19/00 , B01J19/24 , C07C2/76
CPC分类号： C10B43/08 , B01J8/0492 , B01J19/0026 , B01J19/2485 , B01J2208/0053 , B01J2219/00159 , B01J2219/00247 , C07C2/76 , C10G2300/301 , C10G2300/708 , C07C11/24
摘要： The present techniques provide a pyrolysis process that is reduced in coke and/or tar formation relative to comparable processes. A flushing fluid is applied or injected directly into a pyrolysis reactor to reduce high levels of coke and tar that can accumulate within the pyrolysis reactor during pyrolysis of the feed.

88. 发明申请

US20170088484A1 Aromatization of Non-Aromatic Hydrocarbon 审中-公开
公开(公告)号：US20170088484A1
公开(公告)日：2017-03-30
申请号：US15240393
申请日：2016-08-18
申请人： David W. Maher , Robert D. Denton , Jaime A. Valencia , Paul F. Keusenkothen
发明人： David W. Maher , Robert D. Denton , Jaime A. Valencia , Paul F. Keusenkothen
IPC分类号： C07C2/76 , F02C3/22 , B01J19/24
CPC分类号： C07C2/76 , B01J19/24 , B01J29/064 , B01J29/40 , B01J29/405 , B01J37/28 , B01J2219/00103 , B01J2229/186 , C07C5/415 , C07C2529/40 , F02C3/22 , F05D2220/32 , F05D2220/76 , C07C15/00
摘要： The invention relates to producing aromatic hydrocarbon by aromatization of non-aromatic hydrocarbon, including feed pretreatment, aromatization of the aromatization feed's C2 hydrocarbon and C3+ non-aromatic hydrocarbon, and recovery of an aromatic product. The invention also relates to modules for carrying out the pretreatment, aromatization, and recovery, and also modules for auxiliary function such as power generation.

89. 发明申请

US20130204055A1 Selective Hydrogenation of Alkynyl-Containing Compounds and Polyunsaturated Compounds 有权
标题翻译：含炔基的化合物和多不饱和化合物的选择性氢化
公开(公告)号：US20130204055A1
公开(公告)日：2013-08-08
申请号：US13571120
申请日：2012-08-09
申请人： S. Mark Davis , Paul F. Keusenkothen , Charles J. Mart
发明人： S. Mark Davis , Paul F. Keusenkothen , Charles J. Mart
IPC分类号： C07C5/09
CPC分类号： C07C5/09 , C07C11/04
摘要： A selective hydrogenation process that is particularly effective in selectively hydrogenating alkynl compounds, such as acetylene or methyl acetylene, over alkenyl compounds, such as ethylene, is described. The process utilizes a slurry conversion unit for heat efficiency purposes during the conversion of acetylene into ethylene.
摘要翻译：描述了在链烯基化合物如乙烯上选择性氢化炔烃化合物如乙炔或甲基乙炔特别有效的选择性氢化方法。在乙炔转化为乙烯期间，该方法利用用于热效率目的的浆料转化单元。

90. 发明授权

US08399729B2 Integrated process for steam cracking 有权
标题翻译：蒸汽开裂综合工艺
公开(公告)号：US08399729B2
公开(公告)日：2013-03-19
申请号：US12833556
申请日：2010-07-09
申请人： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. DiNicolantonio , John J. Waldrop
发明人： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. DiNicolantonio , John J. Waldrop
IPC分类号： C07C4/04
CPC分类号： B01J10/005 , C10B55/00 , C10B55/10 , C10G9/005 , C10G9/007 , C10G9/36 , C10G51/023 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： This invention relates to a process and system for cracking hydrocarbon feedstock containing vacuum resid comprising: (a) subjecting a vacuum resid to a first thermal conversion in a thermal conversion reactor (such as delayed coker, fluid coker, Flexicoker™, visbreaker and catalytic hydrovisbreaker) where at least 30 wt % of the vacuum resid is converted to material boiling below 1050° F. (566° C.); (b) introducing said thermally converted resid to a vapor/liquid separator, said separator being integrated into a steam cracking furnace, to form a vapor phase and liquid phase; (c) passing said vapor phase to the radiant furnace in said steam cracking furnace; and (d) recovering at least 30 wt % olefins from the material exiting the radiant furnace (based upon the weight of the total hydrocarbon material exiting the radiant furnace).
摘要翻译：本发明涉及一种用于裂化含有真空渣油的烃原料的方法和系统，该方法和系统包括：（a）在热转化反应器（例如延迟焦化器，流体焦化器，Flexicoker TM，减粘裂化器和催化脱硫剂）中对真空渣油进行第一热转化），其中至少30重量％的真空渣油转化成沸点低于1050°F（566℃）的材料; （b）将所述热转化残渣引入蒸汽/液体分离器，所述分离器整合成蒸汽裂解炉，形成气相和液相; （c）将所述气相通过所述蒸汽裂解炉中的辐射炉; 和（d）从离开辐射炉的材料（基于离开辐射炉的总烃材料的重量）回收至少30重量％的烯烃。

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