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81. 发明授权

US06482787B1 Laundry detergent and fabric conditioning compositions with oxidized cyclic amine based polymers 失效
标题翻译：具有氧化环胺基聚合物的洗衣洗涤剂和织物调理组合物
公开(公告)号：US06482787B1
公开(公告)日：2002-11-19
申请号：US09743236
申请日：2001-01-05
申请人： Rajan Keshav Panandiker , Sherri Lynn Randall , Eugene Paul Gosselink , William Conrad Wertz , Soren Hildebrandt , Elisabeth Kappes , Dieter Boeckh
发明人： Rajan Keshav Panandiker , Sherri Lynn Randall , Eugene Paul Gosselink , William Conrad Wertz , Soren Hildebrandt , Elisabeth Kappes , Dieter Boeckh
IPC分类号： C11D183
CPC分类号： C08G73/0273 , C08G73/02 , C08G73/022 , C08G73/0616 , C11D3/0015 , C11D3/225 , C11D3/227 , C11D3/3723 , C11D3/3776
摘要： Detergent compositions and fabric conditioning compositions which utilize certain oxidized cyclic amine based polymers, oligomers, or copolymers are disclosed. These oxidized cyclic amine based polymers, oligomers, or copolymer materials serve as fabric treatment agents that can impart fabric appearance and integrity benefits to fabrics and textiles laundered in washing solutions which contain such materials.
摘要翻译：公开了使用某些氧化的环胺基聚合物，低聚物或共聚物的洗涤剂组合物和织物调理组合物。这些氧化的环状胺基聚合物，低聚物或共聚物材料用作织物处理剂，其可赋予在含有这种材料的洗涤溶液中洗涤的织物和纺织物的织物外观和完整性益处。

82. 发明授权

US06410497B1 Activators for per compounds comprising oxime carbonates or oxime polymers 失效
标题翻译：包含肟碳酸酯或肟聚合物的每种化合物的活化剂
公开(公告)号：US06410497B1
公开(公告)日：2002-06-25
申请号：US09355335
申请日：1999-08-04
申请人： Elisabeth Kappes , Thomas Wehlage , Alfred Oftring , Dieter Boeckh
发明人： Elisabeth Kappes , Thomas Wehlage , Alfred Oftring , Dieter Boeckh
IPC分类号： C11D3395
CPC分类号： C11D3/3917
摘要： Inorganic per compounds may be activated with oxime carbonates of the formula (I), A—O—CO—OR3, a hydroximide ester of formula (II): or polymeric hydroximide esters.
摘要翻译：每种化合物的无机物可以用式（I）的肟碳酸酯，式（II）的氢化亚胺酯A-O-CO-OR 3或聚合的氢化肟酯活化。

83. 发明授权

US06300304B1 Propoxylated/ethoxylated polyalkyleneimine dispersants 有权
标题翻译：丙氧基化/乙氧基化聚亚烷基亚胺分散剂
公开(公告)号：US06300304B1
公开(公告)日：2001-10-09
申请号：US09549606
申请日：2000-04-14
申请人： Dieter Boeckh , Michael Ehle , Angelika Funhoff , Jürgen Mohr , James A. Cleary , Shulin Zhang , Eugene Paul Gosselink
发明人： Dieter Boeckh , Michael Ehle , Angelika Funhoff , Jürgen Mohr , James A. Cleary , Shulin Zhang , Eugene Paul Gosselink
IPC分类号： C11D337
CPC分类号： C11D3/0036 , C11D3/3723
摘要： The present invention relates to an alkoxylated polyalkyleneimine soil dispersant having the formula: wherein R is C2-C6 linear alkylene, C3-C6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula: —(R1O)m(R2O)nR3 wherein R1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R2 is ethylene; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x and y are each independently from about 4 to about 200; provided at least one —(R1O) unit is attached to the backbone prior to attachment of an —(R2O) unit and further provided m+n is at least 12.
摘要翻译：本发明涉及具有下式的烷氧基化聚亚烷基亚胺土壤分散剂：其中R是C 2 -C 6直链亚烷基，C 3 -C 6支链亚烷基及其混合物; B是分支的延续; E是具有下式的亚烷氧基单元：其中R1是1,2-亚丙基，1,2-亚丁基及其混合物; R2是乙烯; R3是氢，C1-C4烷基及其混合物; m为约1至约10; n为约10至约40; w，x和y各自独立地为约4至约200; 提供至少一个 - （R 1 O）单元在 - （R 20）单元的连接之前连接到骨架上，并进一步提供m + n至少为12。

84. 发明授权

US6147183A Amphoteric amine based polymers having a net cationic charge and process for their production 有权
标题翻译：具有净阳离子电荷的两性胺基聚合物及其制备方法
公开(公告)号：US6147183A
公开(公告)日：2000-11-14
申请号：US153084
申请日：1998-09-15
申请人： Soren Hildebrandt , Elisabeth Kappes , Dieter Boeckh , Rajan Panandiker , Sherri Randall , Eugene Paul Gosselink , William Conrad Wertz
发明人： Soren Hildebrandt , Elisabeth Kappes , Dieter Boeckh , Rajan Panandiker , Sherri Randall , Eugene Paul Gosselink , William Conrad Wertz
IPC分类号： C08G73/02 , C08G73/06 , C11D3/37 , C08G69/00 , C08G63/00 , C08G73/00
CPC分类号： C08G73/022 , C08G73/02 , C08G73/0273 , C08G73/0616 , C11D3/37 , C11D3/3723 , C11D3/3776
摘要： Amphoteric amine based polymers having a net cationic charge, wherein the polymers are obtained by reacting (a) at least one amine with (b) at least one crosslinking agent, in a molar ratio of (a):(b) of from 2:1 to 1:1.5 and (c) reacting the condensation products of (a) and (b), which are free of anionic groups, with an anionic group containing an alkylating agent or oxidizing their tertiary nitrogen atoms to N-oxides in such an amount that the resulting polymers still have a net cationic charge, and a process for the production of amphoteric amine based polymers having anet cationic charge by reacting the compounds of (a), (b) and (c) the amphoteric amine based polymers may be used as additives in detergents.
摘要翻译：具有净阳离子电荷的两性胺基聚合物，其中所述聚合物通过（a）至少一种胺与（b）至少一种交联剂以（a）：（b）的摩尔比为2： 1和1：1.5和（c）使不含阴离子基团的（a）和（b）的缩合产物与含有烷基化剂的阴离子基团反应或将其叔氮原子氧化成N-氧化物所得聚合物仍然具有净阳离子电荷的量，以及通过使（a），（b）和（c）化合物与两性胺基聚合物反应制备具有anet阳离子电荷的两性胺基聚合物的方法可以是用作洗涤剂中的添加剂。

85. 发明授权

US5104951A Water-soluble copolymers and their preparation 失效
标题翻译：水溶性共聚物及其制备
公开(公告)号：US5104951A
公开(公告)日：1992-04-14
申请号：US707305
申请日：1991-05-29
申请人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt , Richard Baur
发明人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt , Richard Baur
IPC分类号： C07C233/38 , C08F2/10 , C08F20/10 , C08F220/04 , C08F222/10 , C11D3/37
CPC分类号： C11D3/3773 , C08F220/04 , C11D3/3757 , C11D3/3769
摘要： Water-soluble polymers having K values of from 5 to 100 (determined on the Na salt of the polymers according to H. Fikentscher in aqueous solution at 25.degree. C., a pH of 7 and a concentration of 1% by weight of the Na salt of the polymer) are prepared by polymerizing a monomer mixture of(a) monethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acids and(b) more than 20-100 mol % of monomers which have two or more ethylenically unsaturated double bonds linked via one or more ester or amide functions and which contain one or more --CO--OX groups, where X is one hydrogen equivalent, one alkali metal equivalent or one alkaline earth metal equivalent or an ammonium group,in aqueous solution in the presence of a polymerization initiator, and the polymers are used in amounts of from 0.5 to 25% by weight in detergents and cleaners.
摘要翻译： K值为5至100的水溶性聚合物（根据H.Fikentscher的聚合物的钠盐在25℃的水溶液中测定，pH为7，浓度为Na的1重量％聚合物的盐）通过聚合（a）单烯属不饱和C3-C8-单羧酸和（b）大于20-100摩尔％的具有两个或更多个烯属不饱和双键的单体的单体混合物来制备，所述双键通过一个或多个在聚合引发剂存在下，在水溶液中含有一个或多个-CO-OX基团，其中X是一个氢当量，一个碱金属当量或一个碱土金属当量或铵基团，并且在洗涤剂和清洁剂中聚合物的用量为0.5至25重量％。

86. 发明授权

US5049302A Stable liquid detergent compositions with enchanced clay soil detergency and anti-redeposition properties 失效
标题翻译：稳定的液体洗涤剂组合物具有增强的粘土污垢去污力和抗再沉积性能
公开(公告)号：US5049302A
公开(公告)日：1991-09-17
申请号：US254467
申请日：1988-10-06
申请人： Richard J. Holland , Ornie K. Bullard , Alicia V. York , Dieter Boeckh , Wolfgang Trieselt , Paul Diessel , Hans-Ulrich Jaeger
发明人： Richard J. Holland , Ornie K. Bullard , Alicia V. York , Dieter Boeckh , Wolfgang Trieselt , Paul Diessel , Hans-Ulrich Jaeger
IPC分类号： C11D1/83 , C11D3/00 , C11D3/22 , C11D3/37
CPC分类号： C11D1/83 , C11D3/0036 , C11D3/225 , C11D3/3788
摘要： A stable liquid detergent composition having improved clay soil detergency, clay soil anti-redeposition, oily soil anti-redeposition and soil release properties is disclosed. The detergent composition is comprised of an anionic surfactant, a nonionic surfactant, a hydrotrope, a graft copolymer of polyalkylene oxide and an ester monomer, and a nonionic cellulosic anti-redeposition agent. The graft copolymer is comprised of (a) a polyalkylene oxide based upon an alkylene oxide having from 2 to 4 carbon atoms having a molecular weight of 300 to 100,000 and, (b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 1 to 6 carbon atoms, and/or methyl or ethyl ester of acrylic or meth-acrylic acid in a weight ratio of (a):(b) of from 1:0.2 to 1:10. The nonionic cellulosic anti-redeposition agent is preferably hydroxypropyl methylcellulose. There is a synergism between the nonionic anti-redeposition agent and the graft polyol which imparts improved clay soil detergency, clay anti-deposition and oily soil anti-redeposition properties to the detergent composition.
摘要翻译：公开了一种稳定的液体洗涤剂组合物，其具有改进的粘土污垢去污力，粘土污垢抗再沉积，油性土壤抗再沉积和脱土性质。洗涤剂组合物由阴离子表面活性剂，非离子表面活性剂，水溶助长剂，聚环氧烷和酯单体的接枝共聚物和非离子纤维素抗再沉积剂组成。接枝共聚物包含（a）基于分子量为300至100,000的具有2至4个碳原子的烯化氧的聚亚烷基氧化物，和（b）至少一种衍生自饱和一元羧酸的乙烯基酯，其含有1 至（6）个碳原子，和/或丙烯酸或甲基丙烯酸的甲酯或乙酯，重量比（a）：（b）为1:0.2至1:10。非离子纤维素抗再沉积剂优选为羟丙基甲基纤维素。非离子抗再沉积剂和接枝多元醇之间存在协同作用，其赋予洗涤剂组合物改进的粘土污垢去污力，粘土抗沉积和油性土壤抗再沉积性能。

87. 发明授权

US4925905A Preparation of water-soluble copolymers based on monoethylenically unsaturated carboxylic acids 失效
标题翻译：基于单烯属不饱和羧酸的水溶性共聚物的制备
公开(公告)号：US4925905A
公开(公告)日：1990-05-15
申请号：US330759
申请日：1989-03-30
申请人： Dieter Boeckh , Hans-Peter Seelmann-Eggebert , Heinrich Hartmann , Wolfgang Trieselt , Richard Baur
发明人： Dieter Boeckh , Hans-Peter Seelmann-Eggebert , Heinrich Hartmann , Wolfgang Trieselt , Richard Baur
IPC分类号： C08F2/06 , C08F2/14 , C08F2/38 , C08F20/02 , C08F20/10 , C08F218/02 , C08F218/08 , C08F220/04 , C08F220/20 , C08F222/04 , C11D3/37
CPC分类号： C08F220/04 , C11D3/3757
摘要： Water-soluble copolymers having a K value of from 8 to 100 (determined on the Na salt of the copolymers according to H. Fikentscher in aqueous solution at 25.degree. C., at a pH of 7 and at a concentration of the Na salt of the polymer of 1% by weight) are prepared by copolymerization of monomer mixtures of(a) from 98.5 to 18.5 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids,(b) from 1.5 to 20 mol % of one or more comonomers which contain two or more ethylenically unsaturated, nonconjugated double bonds which are separated from one another by one or more ester bonds,(c) from 0 to 80 mol % of one or more monoethylenically unsaturated C.sub.4 -C.sub.6 -dicarboxylic acids or their anhydrides and(d) from 0 to 20 mol % of other monoethylenically unsaturated comonomers which are copolymerizable with the monomers (a), (b) and (c),the sum of the molar percentages (a) to (d) always being 100, in the presence of a polymerization initiator and a polymerization regulator at not more than 200.degree. C. in one or more inert organic solvents.
摘要翻译： K值为8至100的水溶性共聚物（根据H.Fikentscher的共聚物的Na盐在25℃的水溶液中，pH为7，Na盐浓度为 1重量％的聚合物）是通过（a）98.5-18.5摩尔％的一种或多种单烯键式不饱和C 3 -C 6 - 单羧酸的单体混合物的共聚制备的，（b）1.5-20摩尔％含有两个或更多个烯属不饱和的非共轭双键的更多共聚单体，它们通过一个或多个酯键彼此分离，（c）0至80mol％的一种或多种单烯属不饱和C4-C6-二羧酸或其酸酐和（d）可与单体（a），（b）和（c）共聚的0至20摩尔％的其它单烯属不饱和共聚单体，摩尔百分数（a）至（d）的总和始终为100，在不存在聚合引发剂和聚合调节剂的情况下在一种或多种惰性有机溶剂中超过200℃。

88. 发明授权

US4897215A Detergents containing water-soluble copolymers containing as copolymerized units monomers having two or more ethylenically unsaturated double bonds 失效
标题翻译：含有含有共聚单元的含有两个或更多个烯属不饱和双键的单体的水溶性共聚物的洗涤剂
公开(公告)号：US4897215A
公开(公告)日：1990-01-30
申请号：US191898
申请日：1988-05-10
申请人： Wolfgang Trieselt , Richard Baur , Ekhard Winkler , Paul Diessel , Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann
发明人： Wolfgang Trieselt , Richard Baur , Ekhard Winkler , Paul Diessel , Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann
IPC分类号： C08F220/04 , C08F290/00 , C08F299/00 , C08L101/16 , C11D3/37
CPC分类号： C11D3/3757 , C08F220/04 , C11D3/3761
摘要： A surfactant-based detergent contains water-soluble copolymers which contain(a) from 99.5 to 15 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.6 -monocarboxylic acids,(b) from 0.5 to 20 mol % or one or more comonomers which have two or more ethylenically unsaturated nonconjugated double bonds and are derived from esters,(c) from 0 to 84.5 mol % of one or more monoethylenically unsaturated C.sub.4 - to C.sub.6 -dicarboxylic acids,(d) from 0 to 20 mol % of one or more hydroxyalkyl esters of monoethlenically unsaturated C.sub.3 - to C.sub.6 -carboxlic acids and(e) from 0 to 30 mol % of other water-soluble monoethylenically unsaturated monomers copolymerizable with (a) to (d)as copolymerized units, with the proviso that the sum of the mol % ages (a) to (e) is always 100 and which have a Fikentscher K value of from 8 to 120.
摘要翻译：基于表面活性剂的洗涤剂含有水溶性共聚物，其含有（a）99.5〜15摩尔％的一种或多种单烯属不饱和C3〜C6-一元羧酸，（b）0.5〜20摩尔％或一种或多种共聚单体，具有两个或更多个烯键式不饱和非共轭双键并衍生自酯，（c）0至84.5摩尔％的一种或多种单烯键式不饱和C4至C6-二羧酸，（d）0至20摩尔％的一种或多种更多的单烯属不饱和C3〜C6-羧酸的羟烷基酯和（e）0〜30摩尔％的可与（a）〜（d）共聚的单体共聚的其他水溶性单烯属不饱和单体，条件是总和 mol％的年龄（a）至（e）的总和为100，并且具有8至120的Fikentscher K值。

89. 发明授权

US08536108B2 Care polymers 有权
标题翻译：护理聚合物
公开(公告)号：US08536108B2
公开(公告)日：2013-09-17
申请号：US13105201
申请日：2011-05-11
申请人： Rajan Keshav Panandiker , Julie Ann Menkhaus , Dieter Boeckh , Rainer Dobrawa , Frank Huelskoetter , Valentin Cepus , Jack Tinsley , Klaus Muehlbach , Markus Brym , Sophia Ebert , Ivette Garcia Castro
发明人： Rajan Keshav Panandiker , Julie Ann Menkhaus , Dieter Boeckh , Rainer Dobrawa , Frank Huelskoetter , Valentin Cepus , Jack Tinsley , Klaus Muehlbach , Markus Brym , Sophia Ebert , Ivette Garcia Castro
IPC分类号： B08B3/04 , C11D1/00 , C11D3/18
CPC分类号： C11D3/373 , C11D3/001 , C11D3/3749 , D06M15/227 , D06M15/643 , D06M2200/50
摘要： The present application relates to care polymers and fabric and home care compositions comprising such care polymers, as well as processes for making and using such care polymers and such compositions. The performance of the care polymers that Applicants teach, can be further increased by following the emulsification teaching of the present specification and/or combining such care polymers with silicone materials.
摘要翻译：本申请涉及包含这种护理聚合物的护理聚合物和织物和家庭护理组合物，以及制备和使用这种护理聚合物和这种组合物的方法。申请人教导的护理聚合物的性能可以通过遵循本说明书的乳化教导和/或将这些护理聚合物与硅氧烷材料组合来进一步提高。

90. 发明授权

US08318653B2 Amphiphilic water-soluble alkoxylated polyalkyleneimines having an inner polyethylene oxide block and an outer polypropylene oxide block 有权
标题翻译：具有内部聚环氧乙烷嵌段和外部聚环氧丙烷嵌段的两亲性水溶性烷氧基化聚亚烷基亚胺
公开(公告)号：US08318653B2
公开(公告)日：2012-11-27
申请号：US12739747
申请日：2008-11-07
申请人： Andrea Misske , Sophia Ebert , Stefan Frenzel , Dieter Boeckh , Frank Huelskoetter , James Danziger
发明人： Andrea Misske , Sophia Ebert , Stefan Frenzel , Dieter Boeckh , Frank Huelskoetter , James Danziger
IPC分类号： C11D3/37 , C11D1/722 , C11D3/30 , C08G73/02
CPC分类号： C08L79/02 , C08G73/0206 , C08G73/024
摘要： The present invention relates to amphiphilic water-soluble alkoxylated polyalkyleneimines having an inner polyethylene oxide block comprising 20 to 50 polyethylene oxide units and an outer polypropylene oxide block comprising 10 to 50 polyethylene oxide units and especially to such alkoxylated polyalkyleneimines wherein the ratio of polyethylene oxide units and polypropylene oxide units is proportionally related to the square root of the number of polyalkyleneimine units present in the backbone. The present invention further relates to the use of these alkoxylated polyalkyleneimines as a soil detachment promoting additive to laundry detergents and cleaning compositions and to laundry detergents and cleaning compositions which comprise these alkoxylated mono- or polyalkyleneimines.
摘要翻译：本发明涉及具有包含20-50个聚环氧乙烷单元的内部聚环氧乙烷嵌段的两亲性水溶性烷氧基化聚亚烷基亚胺和包含10-50个聚环氧乙烷单元的外部聚环氧丙烷嵌段，特别涉及这样的烷氧基化聚亚烷基亚胺，其中聚环氧乙烷单元和聚丙烯氧化物单元与存在于主链中的聚亚烷基亚胺单元的数量的平方根成比例地相关。本发明还涉及这些烷氧基化聚亚烷基亚胺作为洗涤剂和清洁组合物的促进添加剂的土壤剥离剂以及包含这些烷氧基化单 - 或聚亚烷基亚胺的衣物洗涤剂和清洁组合物的用途。

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