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81. 发明授权

US4444963A Polymerization process using catalysts comprising chromium on silica/phosphate support 失效
标题翻译：使用在二氧化硅/磷酸盐载体上包含铬的催化剂的聚合方法
公开(公告)号：US4444963A
公开(公告)日：1984-04-24
申请号：US423595
申请日：1982-09-27
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F10/00 , C08F4/02 , C08F4/24 , C08F4/62
CPC分类号： C08F10/00
摘要： In one embodiment of this invention, a chromium component is supported on a silica/aluminum orthophosphate combination and used with an organometal cocatalyst. In accordance with other embodiments of the invention, the silica/phosphate combination for a chromium catalyst support is produced by either impregnating a silica xerogel with aluminum phosphate or boron phosphate, precipitating aluminum phosphate in the presence of a silica hydrogel, or physically mixing silica and aluminum phosphate xerogels. The resulting catalysts are capable of producing high melt flow olefin polymers and exhibit high activity. The resulting polymers have many unusual and desirable characteristics, such as high density and good environmental stress crack resistance.
摘要翻译：在本发明的一个实施方案中，铬组分负载在二氧化硅/正磷酸铝组合上并与有机金属助催化剂一起使用。根据本发明的其它实施方案，用于铬催化剂载体的二氧化硅/磷酸盐组合是通过用磷酸铝或磷酸硼浸渍二氧化硅干凝胶，在二氧化硅水凝胶的存在下沉淀磷酸铝，或物理混合二氧化硅和磷酸铝干凝胶。所得催化剂能够生产高熔体流动的烯烃聚合物并表现出高的活性。所得到的聚合物具有许多不寻常和期望的特征，例如高密度和良好的耐环境应力开裂性。

82. 发明授权

US4421638A Demetallization of heavy oils 失效
标题翻译：重油脱金属
公开(公告)号：US4421638A
公开(公告)日：1983-12-20
申请号：US481085
申请日：1983-03-31
申请人： Simon G. Kukes , Marvin M. Johnson , Gerhard P. Nowack
发明人： Simon G. Kukes , Marvin M. Johnson , Gerhard P. Nowack
IPC分类号： C10G29/10 , C10G29/02
CPC分类号： C10G29/10
摘要： An improved process for removing metals from heavy oils and other hydrocarbon feed streams is disclosed. The process includes adding phosphorus sulfide to the hydrocarbon feed stream under suitable demetallizing conditions. It is believed that phosphorus sulfide reacts with the metals contained in the hydrocarbon containing feed stream to form oil insoluble compounds that can be removed from the hydrocarbon containing feed stream by any conventional method, such as filtration, centrifugation, or decantation.
摘要翻译：公开了一种用于从重油和其他烃进料流中除去金属的改进方法。该方法包括在合适的脱金属条件下向烃进料流中加入硫化磷。据信，硫化磷与含烃进料流中所含的金属反应形成油不溶性化合物，其可以通过任何常规方法如过滤，离心或倾析从含烃进料流中除去。

83. 发明授权

US4409418A Isomerization process 失效
标题翻译：异构化过程
公开(公告)号：US4409418A
公开(公告)日：1983-10-11
申请号：US395939
申请日：1982-07-07
申请人： Marvin M. Johnson , Gerhard P. Nowack , Semyon Kukes
发明人： Marvin M. Johnson , Gerhard P. Nowack , Semyon Kukes
IPC分类号： B01J27/18 , B01J27/188 , C07C5/25 , C07C45/50 , C07C5/24 , C07C5/30
CPC分类号： B01J27/1804 , B01J27/188 , C07C5/2537
摘要： An aliphatic mono-olefin e.g. butene-2, is isomerized in the presence of a catalyst comprising essentially zirconium phosphate and at least one of chromium and thorium to produce the corresponding terminal olefin selectively.
摘要翻译：脂族单烯烃丁烯-2在基本上包含磷酸锆和至少一种铬和钍的催化剂的存在下异构化，以选择性地产生相应的末端烯烃。

84. 发明授权

US4400564A Separation of monoolefins from diolefins 失效
标题翻译：单烯烃与二烯烃的分离
公开(公告)号：US4400564A
公开(公告)日：1983-08-23
申请号：US140283
申请日：1980-04-14
申请人： Marvin M. Johnson , Donald C. Tabler
发明人： Marvin M. Johnson , Donald C. Tabler
IPC分类号： C07C7/156 , C07C7/148
CPC分类号： C07C7/156 , Y02P20/582
摘要： A process and apparatus for separating monoolefins from diolefins comprising contacting a mixture of monoolefins and diolefins with a complexing agent selected from the group consisting of copper(I) salts of sulfonic acids and copper(I) salts of dialkylphosphates and a suitable hydrocarbon solvent for the complexing agent under such conditions that the monoolefins and diolefins form complexes with the complexing agent. The monoolefin complex can be separated from the diolefin complex based either on the relative solubilities of the two complexes in the hydrocarbon solvent for the complexing agent or based on the relative strengths of the two complexes.
摘要翻译：一种用于从二烯烃分离单烯烃的方法和装置，包括使单烯烃和二烯烃的混合物与选自以下的络合剂接触：选自由磺酸的铜（I）盐和磷酸二烷基酯的铜（I）盐和适用的烃溶剂，络合剂在单烯烃和二烯烃与络合剂形成络合物的条件下。可以基于两种络合物在用于络合剂的烃溶剂中的相对溶解度或基于两种络合物的相对强度，将二烯烃络合物与二烯烃络合物分离。

85. 发明授权

US4364841A Phosphate containing support with zerovalent chromium 失效
标题翻译：含有含铬的载体的磷酸盐
公开(公告)号：US4364841A
公开(公告)日：1982-12-21
申请号：US221759
申请日：1980-12-31
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F4/00 , C08F4/24 , C08F4/60 , C08F10/00 , C08F4/02 , C08F4/62
CPC分类号： C08F10/00
摘要： In accordance with one embodiment of this invention, a zerovalent chromium compound is introduced onto an activated phosphate-containing support and utilized in conjunction with an organometal cocatalyst, such as a trialkylborane. In accordance with another embodiment of this invention, a phosphate-containing xerogel is formed by removing water from an aluminum phosphate-containing hydrogel by means of azeotropic distillation or washing with a volatile, water miscible organic compound, activated and thereafter zerovalent chromium is incorporated therewith. In other embodiments of this invention, a phosphate-containing support is formed by forming aluminum phosphate from an aluminum alkoxide or from a melt, or by phosphating silica or alumina, or by forming an aluminum phosphate/silica combination. A support thus formed is activated and a zerovalent chromium compound added. The resulting catalysts are capable of giving high melt index, broad molecular weight distribution polymer, which polymer also exhibits other deviations from typical olefin polymers including lower flexural modulus. The catalyst is ideally suited for forming olefin polymers such as ethylene and ethylene copolymers in a slurry system.
摘要翻译：根据本发明的一个实施方案，将零价铬化合物引入到活化的含磷酸盐载体上并与有机金属助催化剂如三烷基硼烷结合使用。根据本发明的另一个实施方案，通过共沸蒸馏或用挥发性水混溶性有机化合物洗涤从含磷酸铝的水凝胶中除去水而形成含磷酸盐的干凝胶，然后活化其中的零价铬。在本发明的其它实施方案中，通过由烷氧基铝或熔体形成磷酸铝，或通过磷酸二氧化硅或氧化铝，或通过形成磷酸铝/二氧化硅组合形成含磷酸盐的载体。如此形成的载体被活化并加入零价铬化合物。所得到的催化剂能够提供高熔体指数，宽分子量分布的聚合物，该聚合物还表现出与典型烯烃聚合物的其它偏差，包括较低的弯曲模量。该催化剂理想地适用于在淤浆体系中形成烯烃聚合物如乙烯和乙烯共聚物。

86. 发明授权

US4327234A Hydrogenation process using supported nickel catalyst 失效
标题翻译：使用负载镍催化剂的氢化方法
公开(公告)号：US4327234A
公开(公告)日：1982-04-27
申请号：US213424
申请日：1980-12-05
申请人： Gerhard P. Nowack , Marvin M. Johnson
发明人： Gerhard P. Nowack , Marvin M. Johnson
IPC分类号： B01J23/755 , B01J23/78 , B01J23/83 , B01J27/185 , C07C5/10 , C08L7/00
CPC分类号： B01J27/1853 , B01J23/755 , B01J23/78 , B01J23/83 , C07C5/10 , C07C2101/12 , C07C2523/755 , C07C2527/167
摘要： Unsaturated hydrocarbons are hydrogenated using a catalyst comprising nickel on a calcium phosphate support. The catalyst can be used in combination with a promoter selected from at least one of barium and uranium. Aromatic compounds such as benzene can be hydrogenated in this process. The catalytic activity of the described catalyst is sufficiently great as to permit hydrogenation under relatively mild conditions, including liquid phase hydrogenation of aromatics, thus prolonging the active life of the catalyst.
摘要翻译：使用在磷酸钙载体上包含镍的催化剂氢化不饱和烃。催化剂可以与选自钡和铀中的至少一种的助催化剂组合使用。芳族化合物如苯可以在该方法中氢化。所述催化剂的催化活性足够大，以允许在相对温和的条件下进行氢化，包括芳族化合物的液相氢化，从而延长催化剂的活性寿命。

87. 发明授权

US4140493A Hydrocarbon steam reforming process 失效
标题翻译：烃蒸汽重整过程
公开(公告)号：US4140493A
公开(公告)日：1979-02-20
申请号：US844411
申请日：1977-10-21
申请人： Marvin M. Johnson , Gerhard P. Nowack
发明人： Marvin M. Johnson , Gerhard P. Nowack
IPC分类号： B01J27/185 , C01B3/40 , C07C4/00 , C10G11/02 , C10G11/04 , C01B2/16 , C07C3/34 , C10G11/28
CPC分类号： C01B3/40 , B01J27/1853 , C07C4/00 , C01B2203/1052 , C07C2523/02 , C07C2523/12 , C07C2523/755 , C07C2523/78 , C07C2523/83 , C07C2527/167 , Y02P20/52
摘要： A catalyst consisting essentially of nickel, a promoter selected from the group consisting of barium and uranium and a calcium phosphate support having a Ca:P atomic ratio in the range of 1.4:1 to 2.3:1, is formed by impregnating a calcium phosphate gel with suitable compounds of nickel and either barium or uranium. The resulting catalysts are useful for reacting carbon monoxide and steam and in steam reforming processes for producing methane.
摘要翻译：通过浸渍磷酸钙凝胶形成基本上由镍组成的催化剂，选自钡和铀的助催化剂和Ca:P原子比在1.4:1至2.3:1范围内的磷酸钙载体使用合适的镍和钡或铀化合物。所得催化剂可用于使一氧化碳和蒸汽反应，并用于生产甲烷的蒸汽重整过程。

88. 发明授权

US4082815A Acyclic monoolefin double-bond isomerization using a nonacidic supported nickel, iron or cobalt catalyst with either antimony or arsenic 失效
标题翻译： ACYCLIC MONOOLEFIN双键异构化使用非杀伤性支持的镍，铁或钴催化剂与抗体或抗原
公开(公告)号：US4082815A
公开(公告)日：1978-04-04
申请号：US739157
申请日：1976-11-05
申请人： Marvin M. Johnson , Donald C. Tabler , Gerhard P. Nowack
发明人： Marvin M. Johnson , Donald C. Tabler , Gerhard P. Nowack
IPC分类号： B01J23/843 , C07C5/25 , C07C5/24
CPC分类号： C07C5/2525 , B01J23/843 , C07C5/2556
摘要： A method and catalysts for isomerization which involves contacting a feedstream with hydrogen and with various supported catalysts of metallic arsenides and antimonides, with carbon monoxide being optionally introduced into the reaction as a modifier.

89. 发明授权

US4080312A Solid catalysts for oxidative dehydrogenation of alkenes or alkadienes to furan compounds 失效
标题翻译：烯烃或链烯二烯与呋喃化合物氧化脱氢的固体催化剂
公开(公告)号：US4080312A
公开(公告)日：1978-03-21
申请号：US612513
申请日：1975-09-11
申请人： Floyd E. Farha, Jr. , Marvin M. Johnson , Donald C. Tabler
发明人： Floyd E. Farha, Jr. , Marvin M. Johnson , Donald C. Tabler
IPC分类号： B01J23/28 , B01J23/847 , B01J27/198 , C07D307/36 , B01J27/28 , B01J23/92
CPC分类号： B01J23/8472 , B01J23/28 , B01J27/198 , C07D307/36
摘要： Alkenes and/or alkadienes are contacted with molecular oxygen and an oxidative dehydrogenation catalyst consisting essentially of phosphorus, vanadium, oxygen, and at least one promoter selected from the group consisting of iron, cobalt, nickel, and molybdenum to produce furan compounds.
摘要翻译：烯烃和/或链烯二醇与分子氧和主要由磷，钒，氧和至少一种选自铁，钴，镍和钼的促进剂组成的氧化脱氢催化剂接触，以产生呋喃化合物。

90. 发明授权

US4053524A Hydrogenation process and catalyst 失效
标题翻译：氢化过程和催化剂
公开(公告)号：US4053524A
公开(公告)日：1977-10-11
申请号：US608599
申请日：1975-08-28
申请人： Paul R. Stapp , Marvin M. Johnson
发明人： Paul R. Stapp , Marvin M. Johnson
IPC分类号： B01J23/652 , C07C29/20 , C07C27/04
CPC分类号： B01J23/6522
摘要： Aromatic compounds that are hydroxy-substituted on the aromatic nucleus can effectively be hydrogenated by contacting those compounds simultaneously with hydrogen and a catalyst comprising ruthenium supported by Cr.sub.2 O.sub.3 under alkaline conditions.

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