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81. 发明授权

US5902516A Five-coordinate phosphorous compound, process for producing the same and its use 失效
标题翻译：五配位磷化合物，其制备方法及其用途
公开(公告)号：US5902516A
公开(公告)日：1999-05-11
申请号：US908202
申请日：1997-08-07
申请人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
发明人： Naoki Inui , Taketoshi Kikuchi , Kanako Fukuda , Takashi Sanada
IPC分类号： C07F9/6571 , C07F9/6578 , C08K5/51 , C09K15/32 , C07D327/00 , C07F9/02
CPC分类号： C08K5/51 , C07F9/6571 , C07F9/6578 , C09K15/324
摘要： A five-coordinate phosphorous compound which is useful as an stabilizer for organic materials and represented by the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 represents hydrogen atom or an alkyl group; X represents a direct bond, a sulfur atom or a group represented by --CHR.sup.6 -- wherein R.sup.6 represents hydrogen atom, an alkyl group or a cycloalkyl group, and a process for producing the compound (I) are provided.
摘要翻译：可用作有机材料稳定剂并由式（I）表示的五配位磷化合物：其中R1，R2，R4和R5独立地表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基; R3表示氢原子或烷基; X表示直接键，硫原子或-CHR 6 - 表示的基团，其中R 6表示氢原子，烷基或环烷基，以及制备化合物（I）的方法。

82. 发明授权

US5847187A Organic phosphorous compound, a process for producing the same and a use thereof 失效
标题翻译：有机磷化合物，其制备方法及其用途
公开(公告)号：US5847187A
公开(公告)日：1998-12-08
申请号：US942792
申请日：1997-10-02
申请人： Taketoshi Kikuchi , Naoki Inui , Kanaku Fukuda , Takashi Sanada
发明人： Taketoshi Kikuchi , Naoki Inui , Kanaku Fukuda , Takashi Sanada
IPC分类号： C07F9/24 , C07F9/6574 , C07F9/6578 , C07F9/6584 , C08K5/5399 , C07F9/06
CPC分类号： C08K5/5399 , C07F9/2458 , C07F9/65744 , C07F9/6578 , C07F9/6584
摘要： An organic phosphorous compound represented by the following formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.5 and R.sup.6 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R.sup.3 represents a hydrogen atom or an alkyl group; R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or the two R.sup.4 may be combined with each other to form a direct bond, a sulfur bond (--S--), or aN optionally substituted methylene group; R.sup.7 and R.sup.8 represent a hydrogen atom or an alkyl group, or R.sup.7 and R.sup.8 may be combined with each other to form an alkylene group; A represents an alkylene group; B represents a direct bond or an alkylene group; and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other one represents a hydrogen atom or an alkyl group; and the organic phosphorous compound is useful as a stabilizer for an organic material.
摘要翻译：由下式（I）表示的有机磷化合物：其中R 1，R 2，R 5和R 6表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基组; R3表示氢原子或烷基; R4表示氢原子，烷基，环烷基，烷基环烷基，芳烷基或苯基，或者两个R 4可以相互结合形成直接键，硫键（-S-），或aN任选取代的亚甲基; R 7和R 8表示氢原子或烷基，或者R 7和R 8可以相互结合形成亚烷基; A表示亚烷基; B表示直接键或亚烷基; Y和Z中的一个表示羟基，烷氧基或芳烷氧基，另一个表示氢原子或烷基; 有机磷化合物可用作有机材料的稳定剂。

83. 发明授权

US5635570A Resin composition and process for producing the same 失效
标题翻译：树脂组合物及其制造方法
公开(公告)号：US5635570A
公开(公告)日：1997-06-03
申请号：US290517
申请日：1994-08-15
申请人： Hiroomi Abe , Kenji Nagaoka , Takashi Sanada
发明人： Hiroomi Abe , Kenji Nagaoka , Takashi Sanada
IPC分类号： C08L35/06 , C08L71/12 , C08L81/02 , C08F283/08 , C08L81/04
CPC分类号： C08L81/02 , C08L35/06 , C08L71/12
摘要： A resin composition prepared by simultaneously melting and kneading (A) a polyphenylene ether resin, (B) a polyarylene sulfide resin and (C) a functional compound having a bond or a functional group selected from the group consisting of non-aromatic carbon-carbon multiple bond, oxirane group and derived-carboxyl group and subsequently mixing thereinto (D) a polar compound having, in on molecule, at least two polar groups selected from the group consisting of derived-carboxyl group, derived-hydroxyl group, derived-amino group, derived-mercapto group, derived-sulfonic acid group, oxazoline group, cyanamide group, isocyanate group and oxirane group, provided that at least one of the polar groups is different from at least one of the functional groups which the functional compound (C) has.
摘要翻译：通过同时熔融和捏合（A）聚苯醚树脂，（B）聚芳硫醚树脂和（C）具有键或官能团的官能化合物制备的树脂组合物，所述键或官能团选自非芳族碳 - 碳多键，环氧乙烷基和衍生的羧基，并随后混合（D）在分子中具有至少两个极性基团的极性化合物，所述极性基团选自衍生的羧基，衍生的羟基，衍生的氨基基团，衍生 - 巯基，衍生 - 磺酸基，恶唑啉基，氨基氰基，异氰酸酯基和环氧乙烷基，条件是极性基团中的至少一个不同于至少一个官能化合物（C ）具有。

84. 发明授权

US5478873A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5478873A
公开(公告)日：1995-12-26
申请号：US297920
申请日：1994-08-31
申请人： Takashi Sanada , Hiroshi Hagimori , Tetsuo Yamaguchi , Motohiko Samizo
发明人： Takashi Sanada , Hiroshi Hagimori , Tetsuo Yamaguchi , Motohiko Samizo
IPC分类号： C08K5/3435 , C08K5/3492 , C08K5/54
CPC分类号： C08K5/3435 , C08K5/3492
摘要： The present invention provides a thermoplastic resin composition improved in stability at the time of processing which comprises (a) 100 parts by weight of a polyphenylene ether resin and (b) 0.001-15 parts by weight of at least one 4-amino-2,2,6,6-tetramethylpiperidyl compound represented by the following formula (I) or (II): ##STR1## wherein R.sub.1 represents a hydrogen atom, an oxygen atom (oxy radical), a hydroxyl group, an alkyl group, a cycloalkyl group, an allyl group, a benzyl group, an aryl group, an alkanoyl group, an alkenoyl group, an alkyloxy group or a cycloalkyloxy group;R.sub.2 represents a hydrogen atom, an alkyl group or ##STR2## where X represents a direct bond, --O-- or --NH--, R.sub.4 represents a direct bond, a straight or branched alkylene group, an alkylidene group or an arylene group, R.sub.5 represents a hydrogen atom, an alkyl group, an aryl group, ##STR3## n represents an integer of 1 to 4, p represents an integer of 2 to 6, andR.sub.3 represents a hydrogen atom or an n valent organic group.
摘要翻译：本发明提供了加工时稳定性提高的热塑性树脂组合物，其包含（a）100重量份的聚苯醚树脂和（b）0.001-15重量份的至少一种4-氨基-2，由下式（I）或（II）表示的2,6-六甲基哌啶化合物：其中R 1表示氢原子，氧原子（氧基），羟基烷基，环烷基，烯丙基，苄基，芳基，烷酰基，烯酰基，烷氧基或环烷氧基; R 2表示氢原子，烷基或X，其中X表示直接键，-O-或-NH-，R 4表示直接键，直链或支链亚烷基，亚烷基或亚芳基，R 5 表示氢原子，烷基，芳基，n表示1〜4的整数，p表示2〜6的整数，R 3表示氢原子或n价的有机基团。

85. 发明授权

US5237002A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5237002A
公开(公告)日：1993-08-17
申请号：US836382
申请日：1992-02-18
申请人： Taichi Nishio , Hideyuki Kuribayashi , Takashi Sanada
发明人： Taichi Nishio , Hideyuki Kuribayashi , Takashi Sanada
IPC分类号： C08L51/04 , C08L63/00 , C08L71/12 , C08L77/00
CPC分类号： C08L77/00 , C08L51/04 , C08L71/123 , C08L63/00 , Y10S525/905
摘要： A novel thermoplastic resin composition excellent in heat resistance, impact resistance, hardness is provided which comprises 100 parts by weight of a composition comprising (A) 5-95% by weight of a polyphenylene ether prepared by oxidation polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 which may be identical or different and represent a hydrogen atom, a halogen atom, a substituted or unsubstituted hydrocarbon residue, with a proviso that at least one of them is a hydrogen atom and (B) 95-5% by weight of a polyamide and 5-100 parts by weight of (C) a copolymer of an ethylene-.alpha.-olefin copolymer rubber with an alkenyl aromatic compound and an unsaturated carboxylic acid or its anhydride. This composition may further contain 0.01-30 parts by weight of an epoxy compound (D) for 100 parts by weight of the composition of (A) and (B).
摘要翻译：提供了耐热性，耐冲击性，硬度优异的新型热塑性树脂组合物，其包含100重量份的组合物，其包含（A）5-95重量％的由至少一种表示的酚化合物的氧化聚合制备的聚苯醚其中R1，R2，R3，R4和R5可以相同或不同，代表氢原子，卤素原子，取代或未取代的烃基，条件是它们中至少有一个是氢原子和（B）95-5重量％的聚酰胺和5-100重量份的（C）乙烯-α-烯烃共聚物橡胶与链烯基芳族化合物和不饱和羧酸或其不饱和羧酸的共聚物酐。对于100重量份的组合物（A）和（B），该组合物还可以含有0.01-30重量份的环氧化合物（D）。

86. 发明授权

US5189108A Modified polymer rubber and process for preparing the same 失效
标题翻译：改性聚合物橡胶及其制备方法
公开(公告)号：US5189108A
公开(公告)日：1993-02-23
申请号：US625924
申请日：1990-12-14
申请人： Akio Imai , Mitsuji Tsuji , Takashi Sanada , Keisaku Yamamoto
发明人： Akio Imai , Mitsuji Tsuji , Takashi Sanada , Keisaku Yamamoto
IPC分类号： C08F255/04 , C08F255/06 , C08F279/02 , C08F291/00 , C08F291/02
CPC分类号： C08F255/04 , C08F255/06 , C08F279/02
摘要： A modified polymer rubber is obtained by(1) graft-polymerizing at least one grafting monomer to a shreaded rubbery polymer (A) in an aqueous suspension at a temperature of 30.degree.-130.degree. C. to obtain a graft polymer, and(2) kneading the graft polymer with at least one polymerizable monomer in the presence of a free radical initiator at a temperature of 180.degree.-280.degree. C. This process does not cause gel formation and is advantageous in manufacturing cost.The modified polymer rubber thus obtained is excellent in processability and storage stability, and highly useful as a compatibilizer for various resins.

87. 发明授权

US5166237A Thermoplastic resin composition 失效
公开(公告)号：US5166237A
公开(公告)日：1992-11-24
申请号：US482629
申请日：1990-02-20
申请人： Hiroomi Abe , Taichi Nishio , Takashi Sanada , Noriyasu Kagawa
发明人： Hiroomi Abe , Taichi Nishio , Takashi Sanada , Noriyasu Kagawa
IPC分类号： C08L33/08 , C08L33/04 , C08L33/10 , C08L33/18 , C08L63/00 , C08L71/12 , C08L77/00 , C08L77/06 , C09D133/08 , C09D133/10 , C09D133/18 , C09D177/06
CPC分类号： C08L71/123 , C08L77/00 , C08L63/00
摘要： A novel thermoplastic composition having improved paint adhesion strength comprising,A) from about 5 to 95 weight % of a6t least one polyphenylene ether.B) from about 95 to 5 weight % of at least one polyamide,C) paint adhesion improving amount of at least one paint adhesion improver selected from the class consisting of(1) homopolymers or copolymers of unsaturated nitrile compounds and(2) homopolymers or copolymers of alkyl (meth)acrylate, excluding an ethylene alkylacrylate copolymer having about 50 weight % or higher of ethylene,D) from about 0.01 to 30 parts by weight of at least one compatibilizer, based on 100 by weight of the total of the polyphenylene either and polyamide.

88. 发明授权

US5073590A Themoplastic resin composition and process for producing the same 失效
标题翻译：本发明的树脂组合物及其制造方法
公开(公告)号：US5073590A
公开(公告)日：1991-12-17
申请号：US698337
申请日：1991-05-07
申请人： Hiroomi Abe , Taichi Nishio , Kiyoshi Mitsui , Satoru Sogabe , Takashi Sanada
发明人： Hiroomi Abe , Taichi Nishio , Kiyoshi Mitsui , Satoru Sogabe , Takashi Sanada
IPC分类号： C08K3/34 , C08J3/20 , C08K3/00 , C08L1/00 , C08L23/08 , C08L23/10 , C08L23/26 , C08L33/04 , C08L35/00 , C08L51/06 , C08L53/00 , C08L57/00 , C08L57/10 , C08L77/00
CPC分类号： C08L77/00 , C08L23/10 , C08L2205/035 , C08L23/0869 , C08L51/06
摘要： A thermoplastic resin composition is obtained by blending 100 parts by weight of a resin blend consisting of 10 to 90% by weight of at least one polypropylene type resin (A) selected from the group consisting of modified polypropylenes and compounds composed of modified polypropylenes and polypropylenes, and 90 to 10% by weight of a polyamide resin (B); 2 to 30 parts by weight of an epoxy group containing copolymer (C) and 2 to 100 parts by weight of an ethylene-.alpha..beta.-unsaturated carboxylic acid alkyl estermaleic anhydride terpolymer (D).The composition can easily be processed into a molded product, a film, a sheet or the like by a conventional processing method such as injection molding and extrusion molding. The resulting product has a very good balance in physical properties such as heat resistance, coating properties, impact strength and flexural modulus. The composition of this invention is useful in the fields of automobiles, electric industry and electronic industry.

89. 发明授权

US5017652A Process for making a thermoplastic resin composition 失效
标题翻译：制造热塑性树脂组合物的方法
公开(公告)号：US5017652A
公开(公告)日：1991-05-21
申请号：US243715
申请日：1988-09-13
申请人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Takashi Sanada
发明人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Takashi Sanada
IPC分类号： C08F283/08 , C08G65/48 , C08L71/12 , C08L77/00
CPC分类号： C08G65/485 , C08F283/08 , C08L71/126 , C08L77/00 , Y10S525/905
摘要： A process for making a thermoplastic resin composition which comprises melting and mixing 100 parts by weight of polyphenylene ether (A) and 0.01-5.0 parts by weight of at least one compound (B) which contains in its molecule both (a) carbon-carbon double bond or carbon-carbon triple bond and (b) carboxyl group, acid anhydride group, acid amide group, imide group, carboxylic acid ester group, epoxy group, amino group or hydroxyl group in the presence of 0.01% or more and less than 0.1% by weight of radical initiator based on the polyphenylene ether (A),said polyphenylene ether (A) being obtained by oxidation-polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent a hydrogen atom, a halogen atom, a hydrocarbon or a substituted hydrocarbon group, with a proviso that at least one of them is a hydrogen atom, and said polyphenylene ether (A) having a reduced viscosity .eta..sub.sp/c of 0.40-0.58 deciliter/gram.

90. 发明授权

US4957966A Thermoplastic resin composition 失效
公开(公告)号：US4957966A
公开(公告)日：1990-09-18
申请号：US203187
申请日：1988-06-07
申请人： Taichi Nishio , Hiroomi Abe , Yasurou Suzuki , Takashi Sanada , Satoru Hosoda , Takayuki Okada
发明人： Taichi Nishio , Hiroomi Abe , Yasurou Suzuki , Takashi Sanada , Satoru Hosoda , Takayuki Okada
IPC分类号： C08K5/00 , C08K5/09 , C08L71/00 , C08L71/12 , C08L75/00 , C08L77/00 , C08L81/00
CPC分类号： C08K5/0008 , C08L71/123 , C08L77/00 , C08L71/00 , C08L75/00 , C08L81/00 , Y10S525/905
摘要： A novel thermoplastic resin composition comprising a matrix of polyamide resin (E) and a disperse phase of a composition (D), said composition (D) comprising a polyphenylene ether (A), a rubber-like materail (B) and a mutual compatibilizer (C), said polyphenylene ether (A) being obtained from at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represents a hydrogen atom, a halogen atom or a substituted or unsubstituted hydrocarbon residue, with a proviso that at least one of them is a hydrogen atom, and said polyphenylene ether (A) having a reduced viscosity .eta..sub.sp/c of 0.40-0.58 deciliter/gram, said mutual compatibilizer (C) being compatible or reactive with said polyphenylene ether and reactive with said polyamide resin, and said polyamide resin (E) having a number average molecular weight of 14,000-40,000 and an end amino group content of 50-95 mmole/kg, wherein the thermoplastic resin composition constitutes 1-65 wt. % of said polyphenylene ether (A), 1-20 wt. % of said rubber-like material (B), 0.01-5 wt. % of said mutual compatibilizer (C) and 35-97.99 wt. % of said polyamide resin (E), based on the total weight of said thermoplastic resin composition, and the weight average particle size of said disperse phase is 2 micron or less.

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