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81. 发明申请

US20060093795A1 Polymeric substrate having a desiccant layer 审中-公开
标题翻译：具有干燥剂层的聚合物基材
公开(公告)号：US20060093795A1
公开(公告)日：2006-05-04
申请号：US10981167
申请日：2004-11-04
申请人： Jin-Shan Wang , Kathleen Vaeth , Terrence O'Toole
发明人： Jin-Shan Wang , Kathleen Vaeth , Terrence O'Toole
IPC分类号： B32B3/00
CPC分类号： B32B27/00 , B01D53/261 , B01D53/263 , B01D53/28 , B01J20/28033 , B01J20/28035 , H01L51/0097 , H01L51/52 , H01L51/5206 , H01L51/5253 , H01L51/5259 , H01L2251/5315 , H01L2251/5338 , Y02E10/549 , Y10T428/24802
摘要： A polymeric substrate for a moisture-sensitive electronic device includes a polymeric support having a top and bottom surface, and a desiccant layer disposed over at least a portion of the top or bottom surface of the polymeric support, or both.
摘要翻译：用于湿敏电子装置的聚合物基材包括具有顶表面和底表面的聚合物载体，以及设置在聚合物载体的顶表面或底表面的至少一部分上的干燥剂层，或两者。

82. 发明授权

US07034065B2 Ink jet ink composition 失效
标题翻译：喷墨油墨组合物
公开(公告)号：US07034065B2
公开(公告)日：2006-04-25
申请号：US09957558
申请日：2001-09-20
申请人： Jin-Shan Wang , Huijuan Chen
发明人： Jin-Shan Wang , Huijuan Chen
IPC分类号： C09D11/10 , C08L33/02 , C08L37/00 , C08L67/00 , C08L77/00
CPC分类号： C09D11/326 , C09D11/30
摘要： An ink jet ink composition comprising water, a pigment, a humectant and a hyperbranched polymer having end groups consisting essentially of hydrophilic moieties, said hyperbranched polymer having the following formula: HB—Xg wherein: HB is a hyperbranched polymer core; X is a hydrophilic end group; and g is an integer of at least 2.
摘要翻译：一种喷墨油墨组合物，其包含水，颜料，保湿剂和具有基本上由亲水部分组成的端基的超支化聚合物，所述超支化聚合物具有下式：<？在线配方描述=“在线配方”末端 =“lead”？> HB-X <？in-line-formula description =“In-line Formulas”end =“tail”？>其中：HB是超支化聚合物核心; X是亲水端基; g为至少2的整数。

83. 发明授权

US06887962B2 Processes based on atom (or group) transfer radical polymerization and novel (co)polymers having useful structures and properties 失效
公开(公告)号：US06887962B2
公开(公告)日：2005-05-03
申请号：US10289545
申请日：2002-11-07
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
IPC分类号： C08F4/00 , C08F4/06 , C08F4/40 , C08F4/44 , C08F4/50 , C08F12/08 , C08F16/18 , C08F20/00 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F271/02 , C08F291/00 , C08F293/00 , C08F297/00 , C08F210/10 , C08F212/08 , C08F220/12 , C08F220/44
CPC分类号： C08F271/02 , C08F4/00 , C08F4/40 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F2438/01
摘要： Improved processes for atom (or group) transfer radical polymerization (ATRP) and novel polymers have been developed and are described. In certain embodiments, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly alternating monomer sequence are described. Novel copolymers comprising a least one polymeric branch or polymeric block with a gradient monomer structure are described. Additionally, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly periodic monomer sequence are also described. Novel copolymers having a water soluble backbone and at least two hydrophobic polymeric branches grafted to the water soluble backbone are also described.

84. 发明申请

US20050090632A1 Noel (co) polymers and a novel polymerization process based on atom (or group) transfer radical polymerization 审中-公开
标题翻译： Noel（共）聚合物和基于原子（或基团）转移自由基聚合的新型聚合方法
公开(公告)号：US20050090632A1
公开(公告)日：2005-04-28
申请号：US10992249
申请日：2004-11-18
申请人： Krzysztof Matyjaszewski , Jin-Shan Wang
发明人： Krzysztof Matyjaszewski , Jin-Shan Wang
IPC分类号： C08F4/00 , C08F136/08 , C08F293/00 , C08L51/00 , C08L53/00 , C09D151/00 , C09D153/00 , C09J151/00 , C09J153/00
CPC分类号： C09J153/00 , C08F4/00 , C08F136/08 , C08F293/005 , C08F2438/01 , C08L51/003 , C08L53/00 , C09D151/003 , C09D153/00 , C09J151/003 , C08F4/10
摘要： A new polymerization process (atom transfer radical polymerization, or ATRP) based on a redox reaction between a transition metal (e.g., Cu(I)/Cu(II), provides “living” or controlled radical polymerization of styrene, (meth)acrylates, and other radically polymerizable monomers. Using various simple organic halides as model halogen atom transfer precursors (initiators) and transition metal complexes as a model halogen atom transfer promoters (catalysts), a “living” radical polymerization affords (co)polymers having the predetermined number average molecular weight by Δ[M]/[I]0 (up to Mn>105) and a surprisingly narrow molecular weight distribution (Mw/Mn), as low as 1.15. The participation of free radical intermediates in ATRP is supported by end-group analysis and stereochemistry of the polymerization. In addition, polymers with various topologies (e.g., block, random, star, end-functional and in-chain functional copolymers [for example, of styrene and methyl (meth)acrylate]) have been synthesized using the present process. The polymeric products encompassed by the present invention can be widely used as plastics, elastomers, adhesives, emulsifiers, thermoplastic elastomers, etc.
摘要翻译：基于过渡金属（例如Cu（I）/ Cu（II））之间的氧化还原反应的新的聚合方法（原子转移自由基聚合或ATRP）提供苯乙烯，（甲基）丙烯酸酯的“活性”或受控自由基聚合使用各种简单的有机卤化物作为模型卤素原子转移前体（引发剂）和过渡金属络合物作为模型卤素原子转移促进剂（催化剂），“活性”自由基聚合提供具有预定的数均分子量为Δ[M] / [I] <0>（至多为M <10> 5），令人惊奇的分子量自由基中间体在ATRP中的参与由聚合的端基分析和立体化学支持而得到支持，其中，分子量分布（M> / M>>）低至1.15。此外，具有各种拓扑结构的聚合物（例如嵌段，无规，星形，末端官能和链内官能团共聚物[ 或者例如苯乙烯和（甲基）丙烯酸甲酯]）。本发明包括的聚合物可广泛用作塑料，弹性体，粘合剂，乳化剂，热塑性弹性体等。

85. 发明授权

US06756457B2 Polymerization process 失效
标题翻译：聚合过程
公开(公告)号：US06756457B2
公开(公告)日：2004-06-29
申请号：US10196102
申请日：2002-07-16
申请人： Jin-Shan Wang
发明人： Jin-Shan Wang
IPC分类号： C08F204
CPC分类号： C08F290/06 , C08F2/38 , C08F4/00 , C08F293/005
摘要： A process for polymerization of vinyl monomers is described comprising polymerizing vinyl monomers in the presence of of an initiating system comprising (i) an organic sulfur compound and (ii) an onium salt catalyst. The present invention provides a novel method for living polymerization of vinyl monomers, which provides a high level of macromolecular control over the polymerization process and which leads to uniform and controllable polymeric products.
摘要翻译：描述了乙烯基单体的聚合方法，其包括在包含（i）有机硫化合物和（ii）鎓盐催化剂的引发体系的存在下聚合乙烯基单体。本发明提供了乙烯基单体的活性聚合的新方法，其提供了聚合过程中高水平的大分子控制，并且导致均匀和可控的聚合物产物。

86. 发明授权

US06639032B2 Highly branched polymer from telomerization 失效
标题翻译：来自调聚的高支化聚合物
公开(公告)号：US06639032B2
公开(公告)日：2003-10-28
申请号：US09995948
申请日：2001-11-28
申请人： Jin-Shan Wang
发明人： Jin-Shan Wang
IPC分类号： C08F406
CPC分类号： C08F2/38
摘要： A process for making hyperbranched polymers from An—Lz(XY)m type monomers wherein A is a polymerizable group moiety, XY is a telogen group moiety in which Y is a transferable atom or group which can participate in a transfer reaction with the formation of reactive X*, L is a linkage between A and XY, z is 0 or 1, and n and m are integers of at least 1, comprising: (a) initiating reaction by forming activated species from reaction between either an A or an XY group of the An—Lz(XY)m type monomer and an external stimulus to form activated monomer species with an activated polymerizable group moiety A* or an activated moiety X* derived from the telogen group moiety XY; and (b) polymer segment chain growth by (i) propagation reaction between the polymerizable group A moieties of the An—Lz(XY)m type monomers with the activated moieties A* and X* of activated species, and further reaction between the polymerizable group moieties with the activated moieties of the reaction products thereof, and (ii) chain transfer reaction between the activated A* polymerizable group moieties of activated species or of polymer segments formed in (b)(i) with XY telogen group moieties of the An—Lz(XY)m type monomers or of polymer segments formed in (b)(i), whereby activated X* moieties and inactive A—Y moieties are formed by transfer of transferable atom or group Y of the telogen group moiety XY to the activated A* moiety.
摘要翻译：制备An-Lz（XY）m型单体的超支化聚合物的方法，其中A是可聚合基团部分，XY是其中Y是可转移的原子或基团的前体基团部分，其中可以参与转移反应，形成反应性X *，L是A和XY之间的键，z是0或1，n和m是至少为1的整数，包括：（a）通过从A或XY之间的反应形成活化物质来引发反应一组An-Lz（XY）m型单体和外部刺激，以形成活化的单体物质与活化的可聚合基团部分A *或衍生自前体基团部分XY的活化部分X *; 和（b）通过（i）An-Lz（XY）m型单体的可聚合基团A部分与活化部分的活化部分A *和X *之间的扩散反应以及可聚合链段链（ii）活化物质的活化的A *可聚合基团部分或（b）（i）中形成的聚合物链段之间的链转移反应与An -L-（XY）m型单体或在（b）（i）中形成的聚合物链段，由此通过将前体基团部分XY的可转移原子或Y基团转移到活化的A形成活化的X *部分和无活性的AY部分 *部分。

87. 发明授权

US06525170B1 Highly branched polyesters through one-step polymerization process 失效
标题翻译：高分支聚酯通过一步聚合过程
公开(公告)号：US06525170B1
公开(公告)日：2003-02-25
申请号：US09919096
申请日：2001-07-31
申请人： Jin-Shan Wang
发明人： Jin-Shan Wang
IPC分类号： C08G6504
CPC分类号： C08G63/914
摘要： A polymerization process for producing highly branched polyesters is disclosed comprising reacting functional groups A and B of multi-functional branching monomer reactants of the formula A—L—Bn, where one of A and B represents an epoxide group, the other of A and B represents an acid chloride group, L represents a linking group between A and B, and n is at least 2. In accordance with a specific embodiment of the invention, branched polyesters are obtained which have a number average molecular weight of at least 1000 and a ratio of weight average molecular weight to number average molecular weight of less than 2. The invention provides a process for producing highly branched polyesters in one reaction step. The invention has the capability of making highly branched structures of high molecular weight and low polydispersity and has the advantages of not requiring multi-step reactions and purification. The invention yields highly branched polyesters having a multiplicity of very reactive epoxy or acid chloride or both on the outside surface which can be further converted to other functional groups, including polymerizable groups and initiating groups, which can undergo further chain extensions.
摘要翻译：公开了用于生产高支化聚酯的聚合方法，其包括使式AL-Bn的多官能支化单体反应物的官能团A和B反应，其中A和B之一表示环氧基，A和B中的另一个表示酰氯基团，L表示A和B之间的连接基团，n至少为2.根据本发明的具体实施方案，获得了数均分子量为至少1000的支链聚酯，重均分子量与数均分子量小于2.本发明提供了在一个反应步骤中生产高支化聚酯的方法。本发明具有制备高分子量，低分散性的高支化结构的能力，具有不需要多步反应和纯化的优点。本发明产生具有多重极性反应性环氧树脂或酰氯或两者的高度支化的聚酯，可以进一步转化成其它官能团，包括可以进一步延伸的可聚合基团和引发基团。

88. 发明授权

US06426167B2 Water-resistant protective overcoat for image recording materials 失效
标题翻译：用于图像记录材料的防水保护罩
公开(公告)号：US06426167B2
公开(公告)日：2002-07-30
申请号：US09353939
申请日：1999-07-15
申请人： Hwei-Ling Yau , Lan B. Thai , Jin-Shan Wang , Tienteh Chen
发明人： Hwei-Ling Yau , Lan B. Thai , Jin-Shan Wang , Tienteh Chen
IPC分类号： G03C1108
CPC分类号： G03C1/7614 , B41M7/0027 , G03C1/047 , G03C1/95 , G03C11/08 , G03C2001/03594 , G03C2001/7635 , G03C2200/36 , Y10S430/162
摘要： An overcoat composition for imaging products containing: 30-95 weight %, based on the dry laydown of the overcoat, of a hydrophobic polymer, said hydrophobic polymer being homopolymers or copolymers containing at least 30% by weight, based on the total weight of monomers, of the monomer described in structurel; and 5 to 70 weight %, based on the dry laydown of the overcoat, of gelatin: wherein: R is H, CH3, C2H5, and C3H7; and X1, X2, X3, X4 and X5 are H, F, Cl, Br, I, CN, CH3O, C2H5O, C3H7O, C4H9O, CH3, C2H5, C3H7, n-C4H9, sec-C4H9, tert-C4H9, CF3, C2F5, C3F7, iso-C3F7, n-C4F9, sec-C4F9, tert-C4F9, CH3NH, (CH3)2N, n-C5H11, C4H9, n-C6H13, n-C7H15, n-C8H17, n-C9H19, n-C10H21, or n-C12H25.
摘要翻译：用于成像产品的外涂层组合物，其基于外涂层的干沉积，疏水性聚合物为30-95重量％，所述疏水性聚合物为基于单体总重量的至少30重量％的均聚物或共聚物，结构1中描述的单体; 和5至70重量％，基于外涂层的干沉积;明胶：其中：R是H，CH 3，C 2 H 5和C 3 H 7; 并且X 1，X 2，X 3，X 4和X 5分别是H，F，Cl，Br，I，CN，CH 3 O，C 2 H 5 O，C 3 H 7 O，C 4 H 9 O，CH 3，C 2 H 5，C 3 H 7，n-C 4 H 9，仲-C 4 H 9，C 4 H 9，CF 3， C2F5，C3F7，iso-C3F7，n-C4F9，sec-C4F9，叔-C4F9，CH3NH，（CH3）2N，n-C5H11，C4H9，n-C6H13，n-C7H15，n-C8H17，n-C9H19，n -C 10 H 21或n-C 12 H 25。

89. 发明授权

US6069205A Block copolymers 失效
标题翻译：嵌段共聚物
公开(公告)号：US6069205A
公开(公告)日：2000-05-30
申请号：US943925
申请日：1997-10-03
申请人： Jin-Shan Wang
发明人： Jin-Shan Wang
IPC分类号： C08F293/00 , C08F297/00
CPC分类号： C08F297/00 , C08F293/005 , C08F2438/01
摘要： The present invention is block copolymer of the formulas I and II(PA).sub.x (PB).sub.y X (I)X(PB).sub.y (PA).sub.x (PB).sub.y X (II)wherein PA is an ethylenically unsaturated monomer, and PB is a cationically polymerizable monomer that can be initiated with an alkyl halide or without catalysts, x is 4 to 500,000 and y is from 2 to 500,000 and X is a halogen atom. The present invention also provides a method for making a block copolymer of the formulas I and II(PA).sub.x (PB).sub.y X (I)X(PB).sub.y (PA).sub.x (PB).sub.y X (II)wherein PA is an ethylenically unsaturated monomer, and PB is a cationically polymerizable monomer that can be initiated with an alkyl halide, x is 4 to 500,000 and y is from 2 to 500,000 and X is a halogen atom. The reaction is initiated by an atom transfer radical polymerization of the PA monomer with an initiator to produce a polymer of the formulas (III) or (IV)(PA).sub.x X (III)X(PA).sub.x X (IV)wherein X is a halogen atom. The reaction proceeds by adding the polymer of the formulas (II) or (IV) to monomer (PB) to initiate a cationic polymerization reaction to produce a polymer shown in formulas (I) and (II) above.
摘要翻译：本发明是式I和II（PA）x（PB）yX（I）X（PB）y（PA）x（PB）yX（II）的嵌段共聚物，其中PA是烯属不饱和单体，PB是可以用烷基卤或无催化剂引发的阳离子聚合性单体，x为4〜500,000，y为2〜500,000，X为卤素原子。本发明还提供了制备式I和II（PA）x（PB）y X（I）X（PB）y（PA）x（PB）yX（II）的嵌段共聚物的方法，其中PA是烯属不饱和单体，PB是可以用烷基卤引发的阳离子聚合性单体，x为4〜500,000，y为2〜500,000，X为卤素原子。反应通过PA单体与引发剂的原子转移自由基聚合引发，以产生式（III）或（IV）（PA）x X（III）X（PA）x X（IV）的聚合物，其中X为卤素原子。通过将式（II）或（IV）的聚合物加入到单体（PB）中来引发阳离子聚合反应以产生上述式（I）和（II）所示的聚合物，进行反应。

90. 发明授权

US5977261A Anionically copolymerized living random (meth)acrylic copolymers and copolymers prepared therefrom 失效
标题翻译：阴离子共聚的活性无规（甲基）丙烯酸共聚物和由其制备的共聚物
公开(公告)号：US5977261A
公开(公告)日：1999-11-02
申请号：US98981
申请日：1998-06-17
申请人： Jin-shan Wang , Philippe Bayard , Philippe Teyssie , Bruno Vuillemin , Philippe Heim
发明人： Jin-shan Wang , Philippe Bayard , Philippe Teyssie , Bruno Vuillemin , Philippe Heim
IPC分类号： C08F20/12 , C08F220/12 , C08F297/02
CPC分类号： C08F20/12 , C08F220/12
摘要： Living random (meth)acrylic copolymers, facilely converted into random co(meth)acrylates and block copolymers thereof, comprise the anionic copolymerizates of at least one comonomer A with at least one comonomer B selected from among the (meth)acrylates and maleimides, at least one of the comonomers A and B comprising a (meth)acrylate, in the presence of (i) at least one alkali or alkaline earth metal, mono- or difunctional initiator and (ii) at least one ligand, for example a nonnitrogenous macrocyclic complexant, e.g., a crown ether, or an alkali metal alcoholate.
摘要翻译：活性无规（甲基）丙烯酸共聚物易于转化为无规共聚（甲基）丙烯酸酯及其嵌段共聚物，包含至少一种共聚单体A与至少一种选自（甲基）丙烯酸酯和马来酰亚胺的共聚单体B的阴离子共聚物，在（i）至少一种碱金属或碱土金属，单 - 或双官能引发剂存在下，包含（甲基）丙烯酸酯的至少一种共聚单体A和B，和（ii）至少一种配体，例如非氮大环络合剂，例如冠醚或碱金属醇化物。

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