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    • 88. 发明授权
    • Production of pervious low density carbon fiber reinforced composite articles
    • 生产低密度碳纤维增强复合材料
    • US3859158A
    • 1975-01-07
    • US34759473
    • 1973-04-03
    • CELANESE CORP
    • PARK IM KEUM
    • D01F11/14C09J5/02D03D11/00
    • D01F11/14B29K2307/00D03D2700/0148Y10S273/23Y10T442/134
    • The efficient production of pervious low density carbon fiber reinforced composite articles is made possible through the use of the present invention. A fibrous open weave tape (as described) which is capable of undergoing conversion to a carbonaceous fibrous material is continuously passed in the direction of its length through a series of heating zones to form a fibrous carbon tape (preferably of graphitic carbon) wherein an open weave construction is maintained. A plurality of layers of the resulting fibrous open weave carbon tape may be impregnated with a thermosetting resinous material, and a plurality of previously superimposed layers of the impregnated tape subsequently cured to form a pervious composite article. The composite articles of the present invention exhibit a high specific modulus and strength, and are extremely lightweight. The lightweight composite articles may be utilized as structural elements, and are particularly suited for use as a facing sheet of an acoustic sandwich liner which serves as a noise suppression function in jet engines.
    • 通过使用本发明可以有效地生产渗透低密度碳纤维增强复合材料制品。 能够转化为碳质纤维材料的纤维状开口编织带(如上所述)在其长度方向上连续通过一系列加热区,以形成纤维碳带(优选石墨碳),其中开口 维修编织。 所得到的纤维状开口编织碳带的多层可以用热固性树脂材料浸渍,并且多个先前叠加的浸渍带的层随后固化以形成透过性复合制品。
    • 90. 发明授权
    • Production of hydroxy compounds by hydrogenolysis of buffered carboxylate salts
    • 通过缓冲性羧酸盐水解氢化生成羟基化合物
    • US3855319A
    • 1974-12-17
    • US31538572
    • 1972-12-15
    • CELANESE CORP
    • HOBBS CBEDFORD J
    • C07C29/149C07C29/00
    • C07C29/149C07C31/207C07C31/20
    • Carboxylic acids are converted to the corresponding hydroxymethylsubstituted compounds by preparing an aqueous solution of their alkali metal salts buffered to a pH between about 6.0 and 7.0 and then reacting the buffered salt solution with hydrogen in the presence of a hydrogenolysis catalyst such as active metallic cobalt. In a particularly useful embodiment the potassium salts of carboxylic acids, dicarboxylic acids, and hydroxycarboxylic acids having at least about four carbon atoms are hydrogenolyzed in a reactor within which the desired buffering is accomplished with potassium bicarbonate in the presence of a finite concentration of free carbon dioxide. After the reaction step the liquid product is degassed at a temperature high enough to decompose potassium bicarbonate to potassium carbonate; the reaction product separates into two phases because of the salting-out action of the resulting potassium carbonate, and the organic products can be recovered by decantation while the aqueous phase, containing reuseable potassium carbonate, is recycled to the acid-neutralization step which precedes the hydrogenolysis.