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71. 发明授权

US08168822B2 Acetic acid production by way of carbonylation with enhanced reaction and flashing 有权
标题翻译：通过羰基化生产乙酸，增强反应和闪烁
公开(公告)号：US08168822B2
公开(公告)日：2012-05-01
申请号：US12459725
申请日：2009-07-07
申请人： Mark O. Scates
发明人： Mark O. Scates
IPC分类号： C07C51/12
CPC分类号： C07C51/12 , C07C51/44 , C07C53/08
摘要： A method of making acetic acid includes: (a) catalytically reacting methanol or a reactive derivative thereof with carbon monoxide in the presence of a homogeneous Group VIII metal catalyst and a methyl iodide promoter in a reactor vessel in a liquid reaction mixture including acetic acid, water, methyl acetate, methyl iodide and homogeneous catalyst, the reactor vessel being operated at a reactor pressure; (b) withdrawing reaction mixture from the reaction vessel and feeding the withdrawn reaction mixture along with additional carbon monoxide to a pre-flasher/post reactor vessel operated at a pressure below the reactor vessel pressure; (c) venting light ends in the pre-flasher vessel and concurrently consuming methyl acetate in the pre-flasher/post reactor vessel. Reaction conditions, residence time and composition are controlled in the pre-flasher/post reactor vessel such that a pre-flash mixture is enriched in acetic acid and diminished in methyl iodide and methyl acetate in the pre-flasher/post reactor vessel. From the pre-flasher/post reaction vessel the acetic acid enriched mixture is (d) withdrawn and fed to a flash vessel.
摘要翻译：制备乙酸的方法包括：（a）在反应器容器中，在均匀的第VIII族金属催化剂和甲基碘促进剂存在下，使甲醇或其活性衍生物与一氧化碳催化反应，所述液体反应混合物包括乙酸，水，乙酸甲酯，甲基碘和均相催化剂，反应器容器在反应器压力下操作; （b）从反应容器中取出反应混合物，并将抽出的反应混合物与另外的一氧化碳一起送入在低于反应器容器压力的压力下操作的预闪蒸器/反应器容器; （c）在预闪蒸器容器内排放轻馏分，同时在预闪蒸发器/后反应器容器中消耗乙酸甲酯。在闪蒸器/反应器前容器中控制反应条件，停留时间和组成，使得预闪蒸混合物富集在乙酸中，并且在闪蒸器/反应器内容器中的甲基碘和乙酸甲酯减少。从反闪蒸发器/反应容器之后，将富乙酸的混合物（d）取出并送入闪蒸容器。

72. 发明申请

US20120101298A1 CARBONYLATION PROCESS 有权
标题翻译：碳化过程
公开(公告)号：US20120101298A1
公开(公告)日：2012-04-26
申请号：US13138990
申请日：2010-05-06
申请人： Evert Jan Ditzel , Bogdan Costin Gagea
发明人： Evert Jan Ditzel , Bogdan Costin Gagea
IPC分类号： C07C67/37 , C07C51/12
CPC分类号： B01J35/10 , B01J29/18 , B01J2229/18 , B01J2229/38 , C07C51/12 , C07C67/37 , C07C53/08 , C07C69/14
摘要： A process for the production of acetic acid and/or methyl acetate by carbonylating methanol and/or reactive derivatives thereof with carbon monoxide in the presence of a catalyst which is a mordenite which has been treated with an aqueous basic solution containing at least one of aluminate ions and gallate ions and has a silica:X2O3 molar ratio (wherein X is A1 and/or Ga) of at least 12:1.
摘要翻译：在催化剂的存在下，使用甲醇和/或其反应性衍生物与一氧化碳羰化来制备乙酸和/或乙酸甲酯的方法，该催化剂是已经用含有至少一种铝酸盐的碱性水溶液处理过的丝光沸石离子和没食子酸酯离子，并且具有至少12:1的二氧化硅：X 2 O 3摩尔比（其中X是Al和/或Ga）。

73. 发明申请

US20120022289A1 Controlling decanter phase separation of acetic acid production process 有权
标题翻译：控制滗析相分离乙酸生产过程
公开(公告)号：US20120022289A1
公开(公告)日：2012-01-26
申请号：US12804424
申请日：2010-07-21
申请人： Noel Hallinan , Michael E. Fitzpatrick , John D. Hearn , Miraj S. Patel
发明人： Noel Hallinan , Michael E. Fitzpatrick , John D. Hearn , Miraj S. Patel
IPC分类号： C07C51/12
CPC分类号： C07C51/12 , C07C51/44 , C07C53/08
摘要： Disclosed is a method for controlling the decanter phase separation of an acetic acid production by methanol carbonylation. The method comprises measuring the methyl acetate concentration of the reactor mixture, calculating the density of the decanter heavy, organic phase according to the measured methyl acetate concentration, and adjusting the conditions in the reactor or in the decanter to ensure phase separation of the decanter.
摘要翻译：公开了通过甲醇羰基化控制乙酸生产的滗析器相分离的方法。该方法包括测量反应器混合物的乙酸甲酯浓度，根据测量的乙酸甲酯浓度计算滗析器重质有机相的密度，并调节反应器或滗析器中的条件以确保滗析器的相分离。

74. 发明申请

US20120010371A1 METHOD OF ACCELERATING METHANOL CARBONYLATION 有权
标题翻译：加速甲醇碳化的方法
公开(公告)号：US20120010371A1
公开(公告)日：2012-01-12
申请号：US13257379
申请日：2011-02-08
申请人： Zhixiong You , Takeshi Minami , Chunji Yin , Yoichi Umehara , Tetsuro Matsumura , Chikako Hashimoto , Yasuo Hosono
发明人： Zhixiong You , Takeshi Minami , Chunji Yin , Yoichi Umehara , Tetsuro Matsumura , Chikako Hashimoto , Yasuo Hosono
IPC分类号： C07C51/12 , C08F226/06
CPC分类号： C08F226/06 , C07C51/12 , C08F212/36 , C07C53/08
摘要： According to a method for producing acetic acid by carbonylation of methanol characterized in that an acid having an acid dissociation constant (pKa) smaller than the constant of acetic acid is allowed to be present in the reaction system, acetic acid can be produced by the reaction of methanol and carbon monoxide in a reaction liquid in the presence of a solid catalyst containing rhodium and alkyl iodide, to achieve an enhanced reaction rate of carbonylation of methanol in producing acetic acid in the region at a high carbonylation degree (Ca>0.8 mol/mol) for more efficient production of acetic acid.
摘要翻译：根据通过羰基化甲醇生产乙酸的方法，其特征在于在反应体系中存在酸解离常数（pKa）小于乙酸常数的酸，可以通过反应生成乙酸的甲醇和一氧化碳在含有铑和烷基碘的固体催化剂存在下的反应液中，以在羰基化程度高（Ca> 0.8mol / L）的区域中提高甲醇生产乙酸的羰基化反应速率， mol）以更有效地生产乙酸。

75. 发明授权

US08076508B2 Preparation of acetic acid 有权
标题翻译：乙酸的制备
公开(公告)号：US08076508B2
公开(公告)日：2011-12-13
申请号：US12315887
申请日：2008-12-08
申请人： Wayne J. Brtko , Michael E. Fitzpatrick
发明人： Wayne J. Brtko , Michael E. Fitzpatrick
IPC分类号： C07C51/12
CPC分类号： B01D3/143 , C07C51/12 , C07C51/44 , C07C53/08
摘要： A process for producing acetic acid is disclosed. The process comprises carbonylating methanol to form a reaction mixture and flashing the reaction mixture to form a vapor stream and a liquid stream. The flash tank is equipped with a distillation column. The vapor stream comprises acetic acid and other volatile components but essentially no catalyst. The liquid stream comprises the catalyst and sufficient amounts of water and acetic acid to carry and stabilize the catalyst. The liquid stream is recycled to the carbonylation and the vapor stream is subjected to further separation to produce essentially pure acetic acid.
摘要翻译：公开了一种生产乙酸的方法。该方法包括羰基化甲醇以形成反应混合物并使反应混合物闪蒸以形成蒸气流和液体流。闪蒸罐配有蒸馏塔。蒸汽流包括乙酸和其它挥发性组分，但基本上不含催化剂。液体流包含催化剂和足够量的水和乙酸以携带和稳定催化剂。将液体物流再循环到羰基化反应中，蒸气流进一步分离以产生基本上纯的乙酸。

76. 发明授权

US07902398B2 Method and apparatus for carbonylation with reduced catalyst loss 有权
标题翻译：减少催化剂损失的羰基化方法和装置
公开(公告)号：US07902398B2
公开(公告)日：2011-03-08
申请号：US11789768
申请日：2007-04-25
申请人： Mark O. Scates , Joshua Gregory Wagner
发明人： Mark O. Scates , Joshua Gregory Wagner
IPC分类号： C07C51/12
CPC分类号： C07C51/12 , C07C51/47 , C07C53/08
摘要： An apparatus and method for carbonylating a reactant, including sequestering Group VIII catalyst metal from a process stream which generally has a ppb concentration of the catalyst metal. The process stream is treated with a polymer having nitrogen-containing heterocyclic repeat units to sequester the catalyst from the stream, thus allowing valuable catalyst to be recovered and returned to the reaction mixture. An apparatus provides a resin bed downstream of the light ends column in a carbonylation process. Preferably, spent resin is regenerated with a regenerant composition compatible with the carbonylation reaction mixture so that catalyst metal can be directly recycled and the resin re-used.
摘要翻译：用于羰基化反应物的装置和方法，包括从通常具有催化剂金属的ppb浓度的工艺流中螯合第VIII族催化剂金属。用具有含氮杂环重复单元的聚合物处理工艺流以从流中隔离催化剂，从而允许有价值的催化剂回收并返回到反应混合物中。一种装置在羰基化方法中提供在轻馏分塔下游的树脂床。优选地，用与羰基化反应混合物相容的再生剂组合物再生废树脂，使得可以直接再循环催化剂金属并重新使用树脂。

77. 发明申请

US20110021817A1 Method and apparatus for carbonylating methanol with acetic acid enriched flash stream 有权
标题翻译：用富含乙酸的闪蒸液羰基化甲醇的方法和装置
公开(公告)号：US20110021817A1
公开(公告)日：2011-01-27
申请号：US12924234
申请日：2010-09-23
申请人： Jeremy J. Patt
发明人： Jeremy J. Patt
IPC分类号： C07C51/12 , B01J19/00
CPC分类号： C07C51/12 , B01D3/06 , B01J14/005 , B01J19/0013 , B01J31/0231 , B01J31/20 , B01J2219/00006 , B01J2219/00164 , B01J2219/00202 , B01J2219/00213 , B01J2219/0024 , B01J2531/822 , B01J2531/827 , C07C51/445 , C07C53/08
摘要： A carbonylation process for producing acetic acid including: (a) carbonylating methanol or its reactive derivatives in the presence of a Group VIII metal catalyst and methyl iodide promoter to produce a liquid reaction mixture including acetic acid, water, methyl acetate and methyl iodide; (b) feeding the liquid reaction mixture at a feed temperature to a flash vessel which is maintained at a reduced pressure; (c) heating the flash vessel while concurrently flashing the reaction mixture to produce a crude product vapor stream, wherein the reaction mixture is selected and the flow rate of the reaction mixture fed to the flash vessel as well as the amount of heat supplied to the flash vessel is controlled such that the temperature of the crude product vapor stream is maintained at a temperature less than 90° F. cooler than the feed temperature of the liquid reaction mixture to the flasher and the concentration of acetic acid in the crude product vapor stream is greater than 70% by weight of the crude product vapor stream.
摘要翻译：一种用于生产乙酸的羰基化方法，包括：（a）在第VIII族金属催化剂和甲基碘助催化剂存在下羰基化甲醇或其活性衍生物以产生包括乙酸，水，乙酸甲酯和甲基碘的液体反应混合物; （b）将进料温度下的液体反应混合物送入保持在减压状态的闪蒸容器; （c）加热闪蒸器，同时使反应混合物闪烁以产生粗产物蒸汽流，其中选择反应混合物，并将反应混合物的流速加入闪蒸容器以及供应至闪蒸器的热量控制闪蒸容器，使得粗产物蒸汽流的温度保持在比液体反应混合物进入闪蒸器的进料温度低于90°F的温度和粗产物蒸气流中乙酸的浓度大于70重量％的粗产物蒸气流。

78. 发明申请

US20100234628A1 Process for the Preparation of Iridium Acetate 有权
标题翻译：制备铱铱的方法
公开(公告)号：US20100234628A1
公开(公告)日：2010-09-16
申请号：US11915084
申请日：2006-05-24
申请人： Ralf Karch , Bernd Kayser , Andreas Rivas-Nass , Jurgen Bodo Widmer , Roland Winde , Eileen Worner
发明人： Ralf Karch , Bernd Kayser , Andreas Rivas-Nass , Jurgen Bodo Widmer , Roland Winde , Eileen Worner
IPC分类号： C07F15/00 , C07C51/12 , C07C45/69 , C07F7/08 , C01B7/00
CPC分类号： C07C51/412 , C07C53/10
摘要： The present invention relates to a process for the preparation of indium acetate comprising the steps: (a) reacting an indium compound with an alkaline compound in a protic solvent to obtain an iridium containing precipitate, where the reaction is conducted in the presence of at least one component (i) selected from oxalic acid, a salt of oxalic acid, formic acid and a salt of formic acid, (b) reacting the precipitate in the presence of at least (i) one compound selected from oxalic acid, a salt of oxalic acid, formic acid and a salt of formic acid, and (ii) CH3CO2H and/or CH3(CO)O(CO)CH3 to give an iridium acetate containing solution. The invention also relates to indium acetate having a low halide content, to an indium containing precipitate and to uses of the iridium containing precipitate of the present invention and the iridium acetate of the present invention.
摘要翻译：本发明涉及一种制备醋酸铟的方法，包括以下步骤：（a）在质子溶剂中使铟化合物与碱性化合物反应，得到含铱的沉淀物，其中反应在至少存在下进行一种选自草酸，草酸盐，甲酸和甲酸盐的组分（i），（b）在至少（i）一种选自草酸，草酸，草酸，甲酸和甲酸盐，和（ii）CH 3 CO 2 H和/或CH 3（CO）O（CO）CH 3，得到含铱铱的溶液。本发明还涉及具有低卤化物含量的醋酸铟，含铟沉淀物以及本发明的含铱沉淀物和本发明的乙酸铱的用途。

79. 发明申请

US20100158804A1 METHOD FOR THE USE OF [11C] CARBON MONOXIDE IN LABELING SYNTHESIS OF 11C-LABELLED ESTERS AND ACIDS BY SENSITIZED PHOTO-INDUCED FREE RADICAL CARBONYLATION 审中-公开
标题翻译：使用[11C]一氧化碳在11C标记的酯和酸的合成中的方法通过敏感的光诱导的自由基碳酸化
公开(公告)号：US20100158804A1
公开(公告)日：2010-06-24
申请号：US12715657
申请日：2010-03-02
申请人： BENGT LANGSTROM , OLEKSIY ITSENKO
发明人： BENGT LANGSTROM , OLEKSIY ITSENKO
IPC分类号： A61K49/10 , C07C51/12 , C07C57/30 , C07C69/612 , C07C68/00 , C07C55/02 , C07C69/608
CPC分类号： C07B59/001 , C07B2200/05 , C07C51/10 , C07C67/36 , C07C69/612 , C07C69/75 , C07C2601/14 , C07C57/30 , C07C55/21
摘要： Methods and reagents for photo-initiated carbonylation with carbon-isotope labeled carbon monoxide using alkyl/aryl iodides with alcohols or water treated by photosensitizers are provided. The resultant carbon-isotope labeled esters and acids, and pharmaceutical acceptable salts and solvates are useful as radiopharmaceuticals, especially for use in Positron Emission Tomography (PET). Associated kits and method for PET studies are also provided.
摘要翻译：提供了用碳同位素标记的一氧化碳使用烷基/芳基碘化物与醇或通过光敏剂处理的水进行光引发羰基化的方法和试剂。所得的碳同位素标记的酯和酸以及药学上可接受的盐和溶剂合物可用作放射性药物，尤其用于正电子发射断层扫描（PET）。还提供了关于PET研究的试剂盒和方法。

80. 发明授权

US07741512B2 Process for the preparation of carbonylation products 失效
标题翻译：制备羰基化产物的方法
公开(公告)号：US07741512B2
公开(公告)日：2010-06-22
申请号：US12226150
申请日：2007-03-27
申请人： Harry Kaiser , David John Law , Stephan Andreas Schunk , John Glenn Sunley
发明人： Harry Kaiser , David John Law , Stephan Andreas Schunk , John Glenn Sunley
IPC分类号： C07C51/12 , C07C51/14 , C07C67/36
CPC分类号： B01J29/22 , B01J2229/186 , C07C51/12 , C07C53/08
摘要： Process for preparing an aliphatic carboxylic acid having (n+1) carbon atoms, where n is an integer up to 6, and/or the ester derivative thereof by contacting an aliphatic alcohol having n carbon atoms and/or a reactive derivative thereof selected from dialkyl ether, ester of the alcohol and an alkyl halide with carbon monoxide in the presence of a catalyst. The catalyst consists of mordenite which has been ion- exchanged or otherwise loaded with silver.
摘要翻译：具有（n + 1）（n + 1）个碳原子的脂肪族羧酸，其中n为6以下的整数的方法，和/或其具有n个碳原子的脂族醇和/或其反应性衍生物的酯衍生物选自二烷基醚，醇的酯和烷基卤与一氧化碳在催化剂存在下反应。催化剂由离子交换或以其他方式负载银的丝光沸石组成。

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