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71. 发明授权

US4311847A Xanthene compounds 失效
标题翻译：呫吨化合物
公开(公告)号：US4311847A
公开(公告)日：1982-01-19
申请号：US194462
申请日：1980-10-06
申请人： Richard L. Cournoyer , James W. Foley
发明人： Richard L. Cournoyer , James W. Foley
IPC分类号： C07D513/10 , C09B11/24 , C09B11/28 , G03C1/83 , G03C8/48 , C07D275/04
CPC分类号： C07D513/10 , C09B11/24 , C09B11/28 , G03C1/83 , G03C8/48
摘要： The present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein R' is alkyl and n is 0 or 1, which compounds are useful in photographic products and processes.
摘要翻译：本发明涉及式“IMAGE”的新型呫吨化合物，其中R'为烷基，n为0或1，该化合物可用于照相产品和方法。

72. 发明授权

US4304833A Photographic products and processes employing triarylmethane compounds 失效
标题翻译：使用三芳基甲烷化合物的摄影产品和方法
公开(公告)号：US4304833A
公开(公告)日：1981-12-08
申请号：US152189
申请日：1980-05-22
申请人： James W. Foley
发明人： James W. Foley
IPC分类号： C09B11/06 , C09B11/10 , G03C1/83 , G03C8/48 , G03C1/40 , G03C1/10 , G03C1/84 , G03C5/54
CPC分类号： C09B11/06 , C09B11/10 , G03C1/83 , G03C8/48
摘要： The present invention is concerned with photographic products and processes, particularly diffusion transfer products and processes employing certain colored triarylmethane compounds possessing in their triaryl structure a 4'-oxo-1'-naphthylidene (or a 4'-oxo-1'-phenylidene) moiety, a naphthyl (or phenyl moiety) and a phenyl moiety substituted in the ortho-position to the central carbon atom with a non-nucleophilic group that cannot add to the central carbon atom but in alkaline solution undergoes an irreversible cleavage reaction with base that is complete within a predetermined time at a predetermined alkaline pH to provide a nucleophilic moiety that adds to the central carbon atom to form a ring-closed compound which is colorless.
摘要翻译：本发明涉及摄影产品和方法，特别是使用具有三芳基结构的具有4'-氧代-1'-亚萘基（或4'-氧代-1'-亚苯基）亚甲基的某些有色三芳基甲烷化合物的扩散转移产物和方法，部分，萘基（或苯基部分）和在与中心碳原子的邻位取代的苯基部分与不能添加到中心碳原子但在碱性溶液中的非亲核基团发生与碱的不可逆裂解反应，在预定的碱性pH下在预定时间内完成，以提供添加到中心碳原子以形成无色的闭环化合物的亲核部分。

73. 发明授权

US4298676A Optical filter agents and photographic products and processes containing same 失效
标题翻译：光学过滤剂和含有它们的摄影产品和方法
公开(公告)号：US4298676A
公开(公告)日：1981-11-03
申请号：US89559
申请日：1979-10-29
申请人： Derek H. R. Barton , Irena Y. Bronstein-Bonte , Lloyd D. Taylor
发明人： Derek H. R. Barton , Irena Y. Bronstein-Bonte , Lloyd D. Taylor
IPC分类号： G03C8/48 , G03C1/40 , G03C1/10 , G03C1/84 , G03C5/54
CPC分类号： G03C8/48
摘要： Optical filter agents and photographic products and processes using same are disclosed. The optical filter agents are pH-sensitive hydrazone compounds conforming to the following structural formula: ##STR1## where R is any group which can provide a double bond for conjugation with the ##STR2## portion of the compound to provide light-absorbing capability or color for the agent at a pH above its pKa, X is a substituent of R providing at least one electron-withdrawing group and each R' can be defined as any substituent that does not impair the light-absorbing capacity of the compound at a pH above the pKa thereof. The pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The pH-sensitive optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurence of fogging during in-light development.
摘要翻译：公开了使用其的光学过滤剂和照相产品和方法。光学过滤剂是符合以下结构式的pH敏感腙化合物：其中R是可以提供双键与化合物的部分缀合以提供光吸收能力或颜色的任何基团对于高于其pKa的pH的试剂，X是提供至少一个吸电子基团的R的取代基，并且每个R'可以被定义为在上述pH以上不会损害化合物的光吸收能力的任何取代基其pKa。 pH敏感的光学过滤剂在高于pKa的pH下具有高度着色的光吸收形式，并且在低于pKa的pH下基本上不吸收。 pH敏感的光学滤光剂可用于照相胶片单元和用于保护光敏元件的过程，以防止在光照显影过程中发生起雾。

74. 发明授权

US4277406A Novel triarylmethane compounds 失效
标题翻译：新型三芳基甲烷化合物
公开(公告)号：US4277406A
公开(公告)日：1981-07-07
申请号：US106899
申请日：1979-12-26
申请人： James W. Foley
发明人： James W. Foley
IPC分类号： C09B11/06 , C09B11/10 , G03C1/83 , G03C8/48
CPC分类号： G03C1/83 , C09B11/06 , C09B11/10 , G03C8/48
摘要： The present invention is concerned with novel triarylmethane dyes possessing in their triaryl structure a 4'-oxo-1'-naphthylidene (or a 4'-oxo-1'-phenylidene) moiety and a phenyl moiety substituted in the ortho-position to the central carbon atom with the group ##STR1## wherein R is alkyl, unsubstituted or substituted with a solubilizing group, and Y is an electron-withdrawing group, which compounds find utility in photographic products and processes.
摘要翻译：本发明涉及在三芳基结构中具有4'-氧代-1'-亚萘基（或4'-氧代-1'-亚苯基）部分的新型三芳基甲烷染料和在与邻位具有基团的中心碳原子，其中R是未取代的或被增溶基团取代的烷基，Y是吸电子基团，该化合物可用于照相产品和方法。

75. 发明授权

US4269925A Polymeric optical filter agents and photographic products and processes containing same 失效
标题翻译：聚合物光学滤光剂和含有它们的摄影产品和方法
公开(公告)号：US4269925A
公开(公告)日：1981-05-26
申请号：US089558
申请日：1979-10-29
申请人： Derek H. R. Barton , Irena Y. Bronstein-Bonte , Lloyd D. Taylor
发明人： Derek H. R. Barton , Irena Y. Bronstein-Bonte , Lloyd D. Taylor
IPC分类号： G03C8/48 , G03C1/40 , G03C1/10 , G03C1/84 , G03C5/54
CPC分类号： G03C8/48
摘要： Polymeric optical filter agents and photographic products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive optical filter agents comprising polymeric backbone units having the following hydrazone moiety: ##STR1## where R is a group which can provide a double bond for conjugation with the ##STR2## portion of the moiety to provide light-absorbing capability for the agent at a pH above its pKa, and X represents a substituent of R providing at least one electron-withdrawing group. The polymeric pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The polymeric optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurence of fogging during in-light development.
摘要翻译：公开了聚合物光学滤光剂和使用它们的照相产品和方法。聚合物光学过滤剂是pH敏感的光学过滤剂，其包含具有以下腙部分的聚合物主链单元：其中R是能够提供双键以与该部分的“IMAGE”部分缀合以提供光的基团 - 在高于其pKa的pH下的试剂的吸收能力，X表示提供至少一个吸电子基团的R的取代基。聚合物pH敏感光学过滤剂在高于pKa的pH下具有高度着色的光吸收形式，并且在低于pKa的pH下基本上不吸收。聚合物光学滤光剂可用于照相胶片单元和用于保护光敏元件免于在光照显影过程中发生起雾的过程。

76. 发明授权

US4258119A Novel xanthene compounds and photographic products and processes employing the same 失效
标题翻译：新型呫吨化合物和摄影产品及其采用的方法
公开(公告)号：US4258119A
公开(公告)日：1981-03-24
申请号：US106938
申请日：1979-12-26
申请人： Richard L. Cournoyer , James W. Foley
发明人： Richard L. Cournoyer , James W. Foley
IPC分类号： C09B11/00 , C09B11/24 , C09B11/28 , G03C1/825 , G03C1/83 , G03C8/08 , G03C8/48 , G03C1/40 , G03C1/48 , G03C1/84 , G03C5/54
CPC分类号： G03C8/48 , C09B11/24 , C09B11/28 , G03C1/83
摘要： In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein X is ##STR2## wherein R' is alkyl, Y is an electron-withdrawing group and n is 0 or 1. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds.
摘要翻译：在一个实施方案中，本发明涉及下式的新的呫吨化合物，其中X是其中R'是烷基，Y是吸电子基团，n是0或1.在另一个实施方案中，本发明涉及采用这些呫吨化合物的摄影产品和方法。

77. 发明授权

US4258118A Novel xanthene compounds and photographic products and processes employing the same 失效
标题翻译：新型呫吨化合物和摄影产品及其采用的方法
公开(公告)号：US4258118A
公开(公告)日：1981-03-24
申请号：US106905
申请日：1979-12-26
申请人： James W. Foley , Louis Locatell, Jr. , Charles M. Zepp
发明人： James W. Foley , Louis Locatell, Jr. , Charles M. Zepp
IPC分类号： C09B11/00 , C09B11/24 , C09B11/28 , G03C1/83 , G03C8/48 , G03C1/84 , G03C1/40 , G03C1/48 , G03C5/54
CPC分类号： G03C1/83 , C09B11/24 , C09B11/28 , G03C8/48
摘要： In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein R' is alkyl; Y is an electron-withdrawing group and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds.
摘要翻译：在一个实施方案中，本发明涉及新的呫吨化合物，其中R'是烷基; Y是吸电子基团，A是阴离子。在另一个实施方案中，本发明涉及采用这些呫吨化合物的照相产品和方法。

78. 发明授权

US4204061A Sulfam(na)phthaleins 失效
标题翻译： Sulfam（na）phthaleins
公开(公告)号：US4204061A
公开(公告)日：1980-05-20
申请号：US836021
申请日：1977-09-23
申请人： Stanley M. Bloom , Alan L. Borror , James W. Foley
发明人： Stanley M. Bloom , Alan L. Borror , James W. Foley
IPC分类号： C07D275/06 , C07D455/04 , G03C1/83 , G03C8/48 , C07D279/02 , C07D417/10
CPC分类号： C07D275/06 , C07D455/04 , G03C1/83 , G03C8/48
摘要： This invention relates to phenol sulfam(na)phthaleins possessing a ##STR1## wherein R is selected from methyl, unsubstituted or substituted with one or two halo groups and phenyl, unsubstituted or substituted with alkyl, dimethylamino or nitro substituted on the N atom of the sulfam(na)phthalein ring, which compounds find utility as photographic optical filter agents and filter agent precursors.
摘要翻译：本发明涉及具有“IMAGE”的苯酚磺胺（na）酞，其中R选自未被取代或被一个或两个卤素取代的甲基，未被取代或被烷基取代的苯基，二甲基氨基或硝基取代在磺胺（na）酞菁环，这些化合物可用作照相光学过滤剂和过滤剂前体。

79. 发明授权

US4139381A Photographic products and processes employing pH sensitive filter dyes 失效
标题翻译：使用pH敏感的过滤染料的摄影产品和工艺
公开(公告)号：US4139381A
公开(公告)日：1979-02-13
申请号：US836006
申请日：1977-09-23
申请人： Stanley M. Bloom , Alan L. Borror , James W. Foley
发明人： Stanley M. Bloom , Alan L. Borror , James W. Foley
IPC分类号： C07C43/225 , C07D275/06 , C07D279/02 , C07D417/10 , G03C8/48 , G03C8/54 , G03C7/00 , G03C1/40 , G03C1/84 , G03C5/54
CPC分类号： C07D275/06 , C07C43/225 , G03C8/48
摘要： This invention is concerned with photographic products, particularly diffusion transfer photographic film units, useful in photographic processes conducted outside of a camera wherein post-exposure fogging by ambient light is prevented by a compound initially present as a substantially colorless compound which is activated by base to provide a light-absorbing reagent or colored optical filter agent which is capable of being irreversibly discharged without a change in pH. The colorless compound or filter agent precursor is initially disposed in a layer of the film unit, for example, in a layer coated over the photosensitive element. Subsequent to imagewise exposure of the photosensitive element, the colored optical filter agent is generated by contacting the colorless precursor with a basic processing composition. After remaining in contact with said basic composition for a given time, the colored optical filter agent is discharged by forming a new compound which is substantially colorless and which is different from and non-reversible to said precursor and different from and non-reversible to said optical filter agent.
摘要翻译：本发明涉及照相产品，特别是扩散转印照相胶片单元，其可用于在照相机外部进行的摄影过程中，其中通过环境光的曝光后雾化被最初作为基本上无色的化合物的化合物预防，所述化合物被碱活化，提供能够在不改变pH的情况下不可逆地排出的吸光剂或有色光学过滤剂。无色化合物或过滤剂前体最初设置在膜单元的层中，例如在涂覆在感光元件上的层中。在感光元件成像曝光之后，通过使无色前体与基本处理组合物接触来产生着色光学滤光片。在与所述碱性组合物保持接触一定时间后，通过形成基本无色的新化合物排出有色光学过滤剂，该化合物与所述前体不同且不可逆，并且不同于并且不可逆地转化为所述光学过滤剂。

80. 发明授权

US4001275A Indole dehydro phthalides and naphthalides 失效
标题翻译：内含去离子水杨酸酯和萘二甲酸酯
公开(公告)号：US4001275A
公开(公告)日：1977-01-04
申请号：US617271
申请日：1975-09-29
申请人： Alan L. Borror
发明人： Alan L. Borror
IPC分类号： C07D307/885 , C07D311/92 , G03C8/48 , C07D209/10 , C07D209/12 , C07D209/14 , C07D209/18
CPC分类号： C07D307/885 , C07D311/92 , G03C8/48
摘要： This invention relates to a process of preparing phthalein indicator dyes including phthalides and naphthalides derived from certain hydroxy-substituted carbocyclic aryl compounds, such as phenols, and from certain N-heterocyclic aryl compounds, such as indoles, and to a process of preparing novel intermediates useful therein. According to the present invention, the selected carbocyclic compound or the selected N-heterocyclic compound is reacted with phthalaldehydic or naphthalaldehydic acid to form the corresponding (na)phthalidyl adduct which is treated with an oxidizing agent to yield the subject intermediates. To prepare the indicator dye, the intermediate, i.e., the oxidation product thus obtained is then reacted with a carbocyclic or heterocyclic aryl compound to yield the corresponding indicator dye. The oxidation products comprising the novel intermediates of the present invention may be dehydro or hydrated (na)phthalidyl adducts.

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