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71. 发明授权

US5763725A Process for the production of ethylene by non-catalytic oxidative cracking of ethane or ethane rich C.sub.2 -C.sub.4 paraffins 失效
标题翻译：通过乙烷或富含乙烷的C2-C4链烷烃的非催化氧化裂化生产乙烯的方法
公开(公告)号：US5763725A
公开(公告)日：1998-06-09
申请号：US933109
申请日：1997-09-18
申请人： Vasant Ramchandra Choudhary , Amarjeet Munshiram Rajput , Shafeek Abdul Rashid Mulla
发明人： Vasant Ramchandra Choudhary , Amarjeet Munshiram Rajput , Shafeek Abdul Rashid Mulla
IPC分类号： C07C4/02 , C07C4/04
CPC分类号： C07C4/025 , Y02P20/52 , Y02P20/582 , Y10S585/91
摘要： An improved process for the production of ethylene by non-catalytic oxidative cracking of ethane or ethane rich C.sub.2 -C.sub.4 paraffins with high conversion, selectivity and productivity, operating in a most energy efficient and safe manner requiring little or no external energy, in an empty tubular reactor, wherein the exothermic oxidative conversion of ethane or ethane rich C.sub.2 -C.sub.4 paraffins is coupled with the endothermic hydrocarbon cracking reactions by carrying out both the exothermic and endothermic reactions simultaneously in the reactor so that the heat produced in the exothermic reactions is used instantly in the endothermic reactions and thereby making the overall process mildly exothermic, near thermo-neutral or mildly endothermic, which comprises passing a preheated gaseous feed comprising of ethane or ethane rich C.sub.2 -C.sub.4 paraffins, oxygen and steam through an empty tubular reactor operated at the effective temperature, pressure, space velocity and hydrocarbon/O.sub.2 and hydrocarbon/steam mole ratios in the feed, is provided.
摘要翻译：一种改进的乙烯生产工艺，通过非催化氧化裂解乙烷或富含乙烷的富C2-C4链烷烃，具有高转化率，选择性和生产率，以最节能和安全的方式运行，需要很少或没有外部能量，在空的其中乙烷或富含乙烷的C2-C4链烷烃的放热氧化转化通过在反应器中同时进行放热和吸热反应与吸热烃裂解反应相结合，使得在放热反应中产生的热量立即使用在吸热反应中，从而使整个过程温和地放热，接近热中性或温和吸热，其包括使包含乙烷或富乙烷的C2-C4链烷烃的氧气和蒸汽的预热气态进料通过在有效的温度，压力，空间速度和烃/ O 2和烃/蒸汽提供饲料中的摩尔比。

72. 发明授权

US5763724A Method of manufacturing chemical products 失效
标题翻译：制造化学产品的方法
公开(公告)号：US5763724A
公开(公告)日：1998-06-09
申请号：US463032
申请日：1995-06-05
申请人： Serge Bellet , Marc Loublier , Guy Margail
发明人： Serge Bellet , Marc Loublier , Guy Margail
IPC分类号： B01J19/00 , B01J19/28 , B08B7/02 , B08B9/02 , B08B17/02 , C07C4/04 , C10G9/18 , C10G9/20 , C10G15/00 , F23J3/00 , F28G7/00 , C07C4/02 , C07C5/327
CPC分类号： B01J19/0026 , B01J19/285 , B08B17/02 , B08B7/02 , B08B9/027 , B08B9/0327 , C07C4/04 , C10G15/00 , C10G9/18 , C10G9/20 , F23J3/00 , F28G7/00 , Y10S585/921 , Y10S585/922 , Y10S585/95
摘要： The present invention relates to a method of manufacturing one or more chemical products in which a chemical reaction is performed by causing one or more reagents to flow along the inside of a tube disposed in a radiation zone of a furnace. In the method, at least a portion of the tube is caused to vibrate so as to limit the deposition of reaction by-products on the inside wall of the tube. More particularly, the tube can be vibrated at a frequency lying in the range 50 Hz to 2000 Hz. The invention also provides apparatus for performing the method of the invention, which apparatus comprises a furnace including a radiation thermal enclosure through which at least one tube passes, which tube is provided with at least one excitation means suitable for generating tube vibration.
摘要翻译：本发明涉及一种制造一种或多种化学产物的方法，其中通过使一种或多种试剂沿着设置在炉的辐射区域中的管的内部流动来进行化学反应。在该方法中，使管的至少一部分振动，以限制反应副产物在管的内壁上的沉积。更具体地，管可以以50Hz至2000Hz的频率振动。本发明还提供了用于执行本发明的方法的装置，该装置包括一个包括辐射热封壳的炉子，至少一个管通过该炉子，该管道设有至少一个适于产生管道振动的激励装置。

73. 发明授权

US5502263A Method of reclaiming styrene and other products from polystyrene based products 失效
公开(公告)号：US5502263A
公开(公告)日：1996-03-26
申请号：US370682
申请日：1995-01-10
申请人： Thomas E. Ponsford , Henry T. Ponsford
发明人： Thomas E. Ponsford , Henry T. Ponsford
IPC分类号： A62D3/00 , C07C4/22 , C09K5/10 , C10G1/10 , C10L1/04 , C10M105/06 , C10M127/04 , C23F15/00 , G21D5/08 , C07C4/04
CPC分类号： G21D5/08 , C07C4/22 , C09K5/10 , C10G1/10 , C10L1/04 , C10M105/06 , C10M127/04 , C23F15/00 , C10M2203/06 , C10N2240/06 , C10N2240/08
摘要： In the method for reclaiming styrene monomer from polystyrene, polystyrene is mixed with a solvent and heated to approximately 300.degree. C. to 400.degree. C. to depolymerize the polystyrene to produce a styrene monomer fraction and a heavier fraction of partial depolymerization products. The styrene fraction is separated from the heavier fraction to recover the styrene monomer and polystyrene partial depolymerization products. In a preferred embodiment, the solvent comprises a "styrene oil" which results from the incomplete depolymerization of polystyrene, at least a portion of which is recycled to mix with polystyrene. The method is useful in reclaiming styrene monomer from napalm, foamed polystyrene, and other polystyrene products. In the case of reclamation of napalm, the method also includes the steps of separating and recovering benzene and gasoline.

74. 发明授权

US5501878A Process for reducing the carbonization of heat exchange surfaces 失效
标题翻译：减少热交换表面碳化的方法
公开(公告)号：US5501878A
公开(公告)日：1996-03-26
申请号：US320875
申请日：1994-10-11
申请人： Simon Barendregt , Gerhard Zimmermann , Grete Bach
发明人： Simon Barendregt , Gerhard Zimmermann , Grete Bach
IPC分类号： C07C4/04 , C10G9/16 , B05D3/02 , B05D3/04
CPC分类号： C10G9/16 , C07C4/04
摘要： A process for reducing the carbonization of the heat exchange surfaces in a tubular heat exchanger of boiler steel which, in particular, within a unit for the thermal cracking of hydrocarbons to alkenes and while producing steam, carries out the rapid cooling of the cracking products after they leave the cracking furnace. After the tubular heat exchanger is cleaned and before it is returned to service, the sides of the heat exchange surfaces which come into contact with the cracking products are treated under reducing conditions until the greatest possible reduction of the Fe.sub.2 O.sub.3 on the surface to Fe.sub.3 O.sub.4 has taken place, without submicron Fe powder being formed.
摘要翻译：一种用于减少锅炉钢管式热交换器中的热交换表面的碳化的方法，特别是在用于将烃类热分解成烯烃并在产生蒸汽的单元内进行的裂化产物的快速冷却他们离开裂解炉。在管状热交换器被清洁并且在其恢复使用之前，与还原条件接触的热交换表面的侧面在还原条件下进行处理，直到Fe 3 O 4的表面上最大可能地还原Fe 3 O 4为止没有形成亚微米Fe粉末。

75. 发明授权

US5406010A Method of reclaiming styrene and other products from polystyrene based products 失效
标题翻译：从聚苯乙烯产品回收苯乙烯和其他产品的方法
公开(公告)号：US5406010A
公开(公告)日：1995-04-11
申请号：US10350
申请日：1993-01-28
申请人： Thomas E. Ponsford , Henry T. Ponsford
发明人： Thomas E. Ponsford , Henry T. Ponsford
IPC分类号： A62D3/00 , C07C4/22 , C09K5/10 , C10G1/10 , C10L1/04 , C10M105/06 , C10M127/04 , C23F15/00 , G21D5/08 , C07C4/04
CPC分类号： G21D5/08 , C07C4/22 , C09K5/10 , C10G1/10 , C10L1/04 , C10M105/06 , C10M127/04 , C23F15/00 , C10M2203/06 , C10N2240/06 , C10N2240/08
摘要： In the method for reclaiming styrene monomer from polystyrene, polystyrene is mixed with a solvent and heated to approximately 300.degree. C. to 400.degree. C. to depolymerize the polystyrene to produce a styrene monomer fraction and a heavier fraction of partial depolymerization products. The styrene fraction is separated from the heavier fraction to recover the styrene monomer and polystyrene partial depolymerization products. In a preferred embodiment, the solvent comprises a "styrene oil" which results from the incomplete depolymerization of polystyrene, at least a portion of which is recycled to mix with polystyrene. The method is useful in reclaiming styrene monomer from napalm, foamed polystyrene, and other polystyrene products. In the case of reclamation of napalm, the method also includes the steps of separating and recovering benzene and gasoline.
摘要翻译：在从聚苯乙烯中回收苯乙烯单体的方法中，将聚苯乙烯与溶剂混合并加热至约300℃至400℃以解聚聚苯乙烯以产生苯乙烯单体部分和部分解聚产物的较重部分。将苯乙烯部分与较重馏分分离，回收苯乙烯单体和聚苯乙烯部分解聚产物。在优选的实施方案中，溶剂包括由聚苯乙烯不完全解聚产生的“苯乙烯油”，其中至少一部分被再循环以与聚苯乙烯混合。该方法可用于从萘胺，发泡聚苯乙烯和其它聚苯乙烯产物回收苯乙烯单体。在回收浴室的情况下，该方法还包括分离和回收苯和汽油的步骤。

76. 发明授权

US5395405A Method for producing hydrocarbon gas from waste 失效
标题翻译：从废物生产烃类气体的方法
公开(公告)号：US5395405A
公开(公告)日：1995-03-07
申请号：US046693
申请日：1993-04-12
申请人： Christopher J. Nagel , Thomas P. Griffin
发明人： Christopher J. Nagel , Thomas P. Griffin
IPC分类号： A62D3/00 , A62D3/32 , A62D101/20 , A62D101/22 , A62D101/26 , A62D101/28 , B01J10/00 , C07C1/00 , C10B49/14 , C10B53/00 , C10J3/57 , F27B3/04 , F27B3/08 , F27D3/15 , F27D3/16 , F27D3/18 , C10J3/00 , C07C4/04
CPC分类号： F27D3/18 , A62D3/32 , B01J10/005 , C07C1/00 , C10B49/14 , C10B53/00 , C10J3/57 , F27B3/04 , F27B3/08 , F27D3/16 , A62D2101/20 , A62D2203/10 , B01J2219/0004 , B01J2219/0009 , B01J2219/00155 , C10J2300/0946 , F27D2003/162 , F27D2003/164 , F27D3/1518 , F27M2001/05 , F27M2003/11
摘要： A method for dissociating organic waste to produce a gasified hydrocarbon. The method of the invention includes directing an organic waste, into a reaction zone containing a molten metal bath in a reactor maintained under conditions sufficient to dissociate the organic waste and to form a gasified hydrocarbon component. Wherein the organic waste includes an inorganic component, the an inorganic component is retained in a vitreous and/or molten metal phase or is removed form the gaseous phase by physical or chemical separation.
摘要翻译：一种将有机废物解离以产生气化烃的方法。本发明的方法包括将有机废物引入含有熔融金属浴的反应区，反应器保持在足以解离有机废物并形成气化烃组分的条件下。其中有机废物包括无机组分，无机组分保留在玻璃状和/或熔融金属相中，或者通过物理或化学分离从气相中除去。

77. 发明授权

US5371308A Process for the preparation of lower olefins 失效
标题翻译：低级烯烃的制备方法
公开(公告)号：US5371308A
公开(公告)日：1994-12-06
申请号：US111797
申请日：1993-08-25
申请人： John W. Gosselink , Jacobus Eilers
发明人： John W. Gosselink , Jacobus Eilers
IPC分类号： B01J23/74 , C07B61/00 , C07C1/04 , C07C4/04 , C07C11/02 , C10G2/00 , C10G9/36 , C10G69/06
CPC分类号： C07C1/0485 , C10G2400/20 , Y10S208/95 , Y10S585/93
摘要： A process for preparing lower olefins from a hydrocarbon feed having at least a fraction boiling above the boiling point range of the lower olefins, which process includes thermal cracking of the hydrocarbon feed, wherein at least part of the hydrocarbon feed is a hydroprocessed synthetic oil fraction. The hydroprocessed synthetic oil fraction may be prepared by hydrogenation and/or hydroconversion and/or hydrocracking of a synthetic oil fraction.
摘要翻译：从具有至少沸点高于低级烯烃的沸点范围的馏分的烃原料制备低级烯烃的方法，该方法包括烃进料的热裂解，其中至少部分烃进料是加氢合成油馏分。加氢合成油馏分可以通过合成油馏分的氢化和/或加氢转化和/或加氢裂化来制备。

78. 发明授权

US5369215A Depolymerization method for resource recovery from polymeric wastes 失效
标题翻译：聚合废物资源回收解聚方法
公开(公告)号：US5369215A
公开(公告)日：1994-11-29
申请号：US107281
申请日：1993-08-16
申请人： Gerald A. Platz
发明人： Gerald A. Platz
IPC分类号： C07B63/02 , C07C4/22 , C07C4/04 , C07C4/06
CPC分类号： C07B63/02 , C07C4/22 , B29B17/02 , B29L2030/00 , C07C2527/232 , Y02W30/622 , Y02W30/68 , Y10S241/37 , Y10S264/912 , Y10S425/044
摘要： Polymeric feedstocks, such as scrap or waste tires, rubber, and plastics, in a size range of -6 to +25 mesh are washed with an organic solvent to remove stabilizing additives which have migrated to the surface of the polymer particles, thus eliminating the stabilizers from participation in subsequent reactions and allowing the final production of more pure monomeric products. The polymer particles are exposed to ozone under conditions to cause stress cracking, fissuring and cleavage of the polymer feedstock particles. The ozonated polymer particles are depolymerized to produce one or more monomeric compounds, with the reaction taking place rapidly and occurring in the presence of a system of one or more catalysts which may be metallic salts. The depolymerization is accomplished under conditions of elevated temperatures and reduced pressure, the conditions being less severe than those conditions associated with thermal pyrolysis. The monomeric compounds are recovered by conventional means from otherwise waste polymers and are recycled. Other products of this invention may be collected and recycled or disposed of with no adverse impact on the environment.
摘要翻译：用有机溶剂洗涤尺寸范围为-6至+25目的聚合物原料，例如废料或废轮胎，橡胶和塑料，以除去迁移到聚合物颗粒表面的稳定添加剂，从而消除稳定剂参与后续反应并允许最终生产更纯的单体产品。聚合物颗粒在引起应力开裂，裂缝和聚合物原料颗粒裂开的条件下暴露于臭氧。臭氧化的聚合物颗粒被解聚以产生一种或多种单体化合物，反应发生迅速并且在一种或多种可以是金属盐的催化剂的体系存在下发生。解聚在升高的温度和降低的压力条件下完成，条件不如热分解条件那么苛刻。通过常规方法从另外的废聚合物中回收单体化合物并且被再循环。本发明的其它产品可以被收集和再循环或处理，对环境没有不利的影响。

79. 发明授权

US5321191A Process for the thermal pyrolysis of hydrocarbons using an electric furnace 失效
标题翻译：使用电炉对烃进行热解的方法
公开(公告)号：US5321191A
公开(公告)日：1994-06-14
申请号：US972782
申请日：1992-11-09
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： C10G9/24 , C07C4/04
CPC分类号： C10G9/24 , Y10S585/921 , Y10S585/926
摘要： A process for the thermal pyrolysis of hydrocarbons in a reactor (1) of elongate shape comprising at a first end supply means (5) for a gaseous mixture containing at least one hydrocarbon, at the opposite end discharge means (10) for the effluents produced and between these two ends supply means (9) for effluent cooling fluid, the reactor comprising in a first part (first end side) a plurality of electric heating means (3) enclosed by casings (4) disposed in substantially mutually parallel layers perpendicular to the axis of the reactor, in such a way as to define between the casings and/or the casings and the walls (22), spaces or passages for circulation of the gaseous mixtures and/or effluents. The heating means heat the passages in successive, individual, transverse sections which are substantially perpendicular to the axis of the reactor. The reactor comprises means for introducing into the casings (4) a gas G known as a casing gas which preferably contains water vapour and/or hydrogen. The permeability of the casings is sufficient to permit diffusion, at least at certain points, of at least a part of the gas G from inside the casings to the outside of the casings, the gas G then being diluted in the gaseous mixture.
摘要翻译：一种用于在细长形状的反应器（1）中热解烃的方法，该方法包括在第一端供应装置（5），用于含有至少一种烃的气态混合物，在相对的端部排出装置（10）用于所产生的流出物并且在这两个端部之间，用于流出物冷却流体的供应装置（9），所述反应器包括在第一部分（第一端侧）中的多个电加热装置（3），所述多个电加热装置（3）由壳体（4）包围，反应器的轴线以限定壳体和/或壳体和壁（22）之间的方式，用于气态混合物和/或流出物循环的空间或通道。加热装置加热基本上垂直于反应器轴线的连续的，单独的横向部分中的通道。反应器包括用于将优选含有水蒸气和/或氢气的称为外壳气体的气体G引入壳体（4）的装置。壳体的渗透性足以允许至少在某些点处将气体G的至少一部分从壳体内部扩散到壳体的外部，然后将气体G稀释在气体混合物中。

80. 发明授权

US5147511A Apparatus for pyrolysis of hydrocarbons 失效
标题翻译：油料分解装置
公开(公告)号：US5147511A
公开(公告)日：1992-09-15
申请号：US619740
申请日：1990-11-29
申请人： Herman N. Woebcke
发明人： Herman N. Woebcke
IPC分类号： C07C4/04 , C07C11/02 , C10G9/00 , C10G9/20 , C10G9/42 , F28D7/12
CPC分类号： C10G9/002 , C10G9/20 , F28D7/12 , F28D2021/0075
摘要： An improved hydrocarbon pyrolysis process and apparatus for the production of ethylene comprising a novel furnace comprised of an unfired superheater radiant section and a fired radiant section, adiabatic tube reactor and quench boiler is provided.

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