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    • 71. 发明申请
    • PROCESSES FOR CONJOINTLY PRODUCING BROMINE, CALCIUM CHLORIDE, AND CHLORINE
    • 连续生产溴化钙,氯化钙和氯仿的方法
    • US20100143238A1
    • 2010-06-10
    • US12594877
    • 2008-02-05
    • Joe D. SauerGeorge W. CookTyson J. HallGeorge A. Newbill
    • Joe D. SauerGeorge W. CookTyson J. HallGeorge A. Newbill
    • C01F11/24C01B7/01C01B7/09
    • C01B7/09C01B7/03C01B7/096C01F11/28C25B1/24
    • Processes are provided for conjointly producing Br2, a concentrated aqueous solution containing CaCI2, and Cl2 from an aqueous HBr-rich stream and a feed brine dilute in CaCI2 that comprises NaCI. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 from a Cl2 source, at least a portion of which is produced according to this invention, to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution, producing Cl2 and caustics from residual chlorides such as NaCI, and using at least a portion of the thus produced Cl2 in the Cl2 source.
    • 提供了从富含HBr水溶液的水中共同生成Br2,含有CaCl 2和Cl 2的浓缩水溶液和在包含NaCl的CaCl 2中稀释的进料盐水的方法。 这样的方法可以包括将富含HBr的水流和进料盐水加入到塔中,用来自Cl 2源的Cl 2氧化塔内的溴化物部分,其至少一部分根据本发明生产以产生Br2,回收 Br2,从塔中除去溴化物贫乏的塔底物,这样的含有HCl的塔底物,向溴化物贫乏的塔底物中加入Ca ++源,根据需要将底部的基本上所有的HCl转化为CaCl 2,从而从 处理的底部产物以产生浓缩的水溶液,从残余氯化物如NaCl中产生Cl 2和苛性碱,并使用Cl2源中由此产生的Cl 2的至少一部分。
    • 72. 发明申请
    • Inorganic hydrogen compounds
    • 无机氢化合物
    • US20090123360A1
    • 2009-05-14
    • US12213390
    • 2008-06-18
    • Randell L. Mills
    • Randell L. Mills
    • C01B33/04C01B6/04C01B7/13C01B6/06C01B7/19C01D7/00C01B7/09C01B7/01C01B5/00C01B31/24C01B21/38C01B17/69
    • C01B3/02C01B7/00C01B33/04C25B1/00H01M8/0606H01M12/06Y02P70/56
    • Compounds are provided comprising at least one neutral, positive, or negative hydrogen species having a binding energy greater than its corresponding ordinary hydrogen species, or greater than any hydrogen species for which the corresponding ordinary hydrogen species is unstable or is not observed. Compounds comprise at least one increased binding energy hydrogen species and at least one other atom, molecule, or ion other than an increased binding energy hydrogen species. One group of such compounds contains one or more increased binding energy hydrogen species selected from the group consisting of Hn, Hn−, and Hn+ where n is an integer from one to three. Applications of the compounds include use in batteries, fuel cells, cutting materials, light weight high strength structural materials and synthetic fibers, cathodes for thermionic generators, photoluminescent compounds, corrosion resistant coatings, heat resistant coatings, phosphors for lighting, optical coatings, optical filters, extreme ultraviolet laser media, fiber optic cables, magnets and magnetic computer storage media, and etching agents, masking agents, dopants in semiconductor fabrication, and fuels. Increased binding energy hydrogen compounds are useful in chemical synthetic processing methods and refining methods. The increased binding energy hydrogen ion has application as the negative ion of the electrolyte of a high voltage electrolytic cell.
    • 提供了包含至少一种具有大于其对应的常规氢物质的结合能的中性,正或或负的氢物质,或大于相应的普通氢物质不稳定或未观察到的氢物质的化合物。 化合物包含至少一种增加的结合能氢物种和至少一种其它原子,分子或离子,而不是增加的结合能氢物种。 一组这样的化合物包含一种或多种选自Hn,Hn-和Hn +的增加的结合能氢物质,其中n是1至3的整数。 化合物的应用包括用于电池,燃料电池,切割材料,轻质高强度结构材料和合成纤维,用于热电子发生器的阴极,光致发光化合物,耐腐蚀涂层,耐热涂层,用于照明的荧光体,光学涂层,光学滤光器 ,极紫外激光介质,光纤电缆,磁体和磁性计算机存储介质,以及蚀刻剂,掩蔽剂,半导体制造中的掺杂剂和燃料。 增加的结合能氢化合物在化学合成加工方法和精炼方法中是有用的。 增加的结合能氢离子作为高压电解槽的电解质的负离子被应用。
    • 80. 发明授权
    • Process and composition for drying of gaseous hydrogen halides
    • 用于干燥气态卤化氢的方法和组合物
    • US4853148A
    • 1989-08-01
    • US29631
    • 1987-03-24
    • Glenn M. TomDuncan W. Brown
    • Glenn M. TomDuncan W. Brown
    • B01D53/28B01J20/02B01J20/22C01B7/00C01B7/07C01B7/09C01B7/13C01B7/19C01G1/06
    • C01B7/197B01D53/28C01B7/0718C01B7/093C01B7/135C01G1/06Y10S34/01
    • A process for drying a gaseous hydrogen halide of the formula HX, wherein X is selected from the group consisting of bromine, chlorine, fluorine, and iodine, to remove water impurity therefrom, comprising:contacting the water impurity-containing gaseous hydrogen halide with a scavenger including a support having associated therewith one or more members of the group consisting of:(a) an active scavenging moiety selected from one or more members of the group consisting of:(i) metal halide compounds dispersed in the support, of the formula MX.sub.y ; and(ii) metal halide pendant functional groups of the formula -MX.sub.y-1 covalently bonded to the support, wherein M is a y-valent metal, and y is an integer whose value is from 1 to 3;(b) corresponding partially or fully alkylated compounds and/or pendant functional groups, of the metal halide compounds and/or pendant functional groups of (a);wherein the alkylated compounds and/or pendant functional groups, when present, are reactive with the gaseous hydrogen halide to form the corresponding halide compounds and/or pendant functional groups of (a); andM being selected such that the heat of formation, .DELTA.H.sub.f of its hydrated halide, MX.sub.y.(H.sub.2 O).sub.n, is governed by the relationship:.DELTA.H.sub.f .gtoreq.n.times.10.1 kilocalories/mole of such hydrated halide compoundwherein n is the number of water molecules bound to the metal halide in the metal halide hydrate.Also disclosed is an appertaining scavenger composition and a contacting apparatus wherein the scavenger is deployed in a bed for contacting with the water impurity-containing gaseous hydrogen halide.