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    • 75. 发明授权
    • Conductive coatings and foams for anti-static protection, energy
absorption, and electromagnetic compatibility
    • 导电涂料和泡沫用于防静电保护,能量吸收和电磁兼容性
    • US4889750A
    • 1989-12-26
    • US312657
    • 1989-02-21
    • Robert E. Wiley
    • Robert E. Wiley
    • C08J9/00C08K3/04C09D5/24H01B1/24H05K9/00
    • H05K9/0079C08J9/0066C08K3/04C09D5/24H01B1/24Y10T428/1303Y10T428/1314Y10T428/1376Y10T428/25Y10T428/30
    • Improved compositions are disclosed which are useful in providing a conductive layer of coating on a surface to provide protection against harmful electrostatic discharges. Also disclosed are compositions useful in absorbing and dissipating mechanical and electromagnetic energy and preventing electrostatic build-up, these compositions also provide electromagnetic compatibility. The compositions contain elemental carbon and a polymeric matrix or binder. The improvement comprises employing a unique ground calcined, coal-based coke which approaches graphite in terms of its performance as a conductive additive or pigment but which does not possess the disadvantages associated with the use of graphite.The unique coke employed in the compositions and methods of the present invention has a level of graphitic structure which approaches that of a true graphite. This level of graphitization can be most easily recognized by utilizing x-ray powder diffraction. More specifically, when the value of E.sub.c or the inverse carbon peak width (the 002 peak) is measured for this material using Mo K.alpha. radiation (.lambda.=0.71.ANG.), the value is in the range of about 27 to about 80, and preferably about 28 to about 75.The final compositions employ a polymer resin or matrix system as a binder.The invention also relates to the method of applying the compositions to protect the article and reinforce the substrate, and the resulting coated articles, particularly containers for shipping and storage of electronic components and magnetic information-storage materials. The conductive coating may also add strength to the containers. The compositions may also be used to absorb both mechanical and electromagnetic energy thus providing EMC, and dissipate static electricity, thus preventing electrical static build-up.
    • 公开了改进的组合物,其可用于在表面上提供涂层的导电层以提供防止有害静电放电的保护。 还公开了可用于吸收和耗散机械和电磁能量并防止静电积聚的组合物,这些组合物还提供电磁兼容性。 组合物含有元素碳和聚合物基质或粘合剂。 该改进包括采用独特的研磨煅烧的煤基焦炭,就其作为导电添加剂或颜料的性能而言接近石墨,但不具有与使用石墨相关的缺点。 在本发明的组合物和方法中使用的独特的焦炭具有接近真实石墨的石墨结构的水平。 通过利用X射线粉末衍射可以最容易地识别该水平的石墨化。 更具体地说,当使用MoKα辐射(λ= 0.71 ANGSTROM)对该材料测量Ec值或反碳峰宽度(002峰)时,该值在约27至约80的范围内,并且 优选约28至约75.最终组合物采用聚合物树脂或基质体系作为粘合剂。 本发明还涉及施用组合物以保护制品并加强基材的方法,以及所得到的涂覆制品,特别是用于运输和储存电子部件和磁信息存储材料的容器。 导电涂层也可以增加容器的强度。 组合物也可用于吸收机械和电磁能量,从而提供EMC,并消散静电,从而防止电气静电积聚。